Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O

Autores
Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Arrambide, Gabriel; Gambino, Dinorah; Barán, Enrique José
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The crystal and molecular structure of the [VO(DLmeth)(NH 2O)2]?H2O complex has been determined by X-ray diffraction methods (monoclinic, P21/c with a = 5.8138(2),b = 27.3496(8), c = 7.5663(2) Å , β = 103.059(3)°, and Z =4). The vanadium(V) cation is in a pentagonal bipyramidal environment axially coordinated to the oxo group and equatorially to two hydroxylamido groups in a side-on fashion. The fifth equatorial binding site and the other apical position are occupied by an N and an O atom, respectively, from the methioninate anion acting as a bidentate ligand.
Instituto de Física La Plata
Centro de Química Inorgánica
Materia
Química
Amino Acid Complex
Crystal Structure
Hydroxylamido Complex
Oxovanadium(V)Complex
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/84269
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/84269
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>OPiro, Oscar EnriqueEcheverría, Gustavo AlbertoArrambide, GabrielGambino, DinorahBarán, Enrique JoséQuímicaAmino Acid ComplexCrystal StructureHydroxylamido ComplexOxovanadium(V)ComplexThe crystal and molecular structure of the [VO(DLmeth)(NH 2O)2]?H2O complex has been determined by X-ray diffraction methods (monoclinic, P21/c with a = 5.8138(2),b = 27.3496(8), c = 7.5663(2) Å , β = 103.059(3)°, and Z =4). The vanadium(V) cation is in a pentagonal bipyramidal environment axially coordinated to the oxo group and equatorially to two hydroxylamido groups in a side-on fashion. The fifth equatorial binding site and the other apical position are occupied by an N and an O atom, respectively, from the methioninate anion acting as a bidentate ligand.Instituto de Física La PlataCentro de Química Inorgánica2011info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf752-754http://sedici.unlp.edu.ar/handle/10915/84269enginfo:eu-repo/semantics/altIdentifier/issn/0932-0776info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2011-0719info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-03T10:48:26Zoai:sedici.unlp.edu.ar:10915/84269Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-03 10:48:27.198SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
title Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
spellingShingle Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
Piro, Oscar Enrique
Química
Amino Acid Complex
Crystal Structure
Hydroxylamido Complex
Oxovanadium(V)Complex
title_short Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
title_full Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
title_fullStr Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
title_full_unstemmed Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
title_sort Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
dc.creator.none.fl_str_mv Piro, Oscar Enrique
Echeverría, Gustavo Alberto
Arrambide, Gabriel
Gambino, Dinorah
Barán, Enrique José
author Piro, Oscar Enrique
author_facet Piro, Oscar Enrique
Echeverría, Gustavo Alberto
Arrambide, Gabriel
Gambino, Dinorah
Barán, Enrique José
author_role author
author2 Echeverría, Gustavo Alberto
Arrambide, Gabriel
Gambino, Dinorah
Barán, Enrique José
author2_role author
author
author
author
dc.subject.none.fl_str_mv Química
Amino Acid Complex
Crystal Structure
Hydroxylamido Complex
Oxovanadium(V)Complex
topic Química
Amino Acid Complex
Crystal Structure
Hydroxylamido Complex
Oxovanadium(V)Complex
dc.description.none.fl_txt_mv The crystal and molecular structure of the [VO(DLmeth)(NH 2O)2]?H2O complex has been determined by X-ray diffraction methods (monoclinic, P21/c with a = 5.8138(2),b = 27.3496(8), c = 7.5663(2) Å , β = 103.059(3)°, and Z =4). The vanadium(V) cation is in a pentagonal bipyramidal environment axially coordinated to the oxo group and equatorially to two hydroxylamido groups in a side-on fashion. The fifth equatorial binding site and the other apical position are occupied by an N and an O atom, respectively, from the methioninate anion acting as a bidentate ligand.
Instituto de Física La Plata
Centro de Química Inorgánica
description The crystal and molecular structure of the [VO(DLmeth)(NH 2O)2]?H2O complex has been determined by X-ray diffraction methods (monoclinic, P21/c with a = 5.8138(2),b = 27.3496(8), c = 7.5663(2) Å , β = 103.059(3)°, and Z =4). The vanadium(V) cation is in a pentagonal bipyramidal environment axially coordinated to the oxo group and equatorially to two hydroxylamido groups in a side-on fashion. The fifth equatorial binding site and the other apical position are occupied by an N and an O atom, respectively, from the methioninate anion acting as a bidentate ligand.
publishDate 2011
dc.date.none.fl_str_mv 2011
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/84269
url http://sedici.unlp.edu.ar/handle/10915/84269
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0932-0776
info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2011-0719
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
752-754
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.13397

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