Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate
- Autores
- Baran, Enrique José; Parajón Costa, Beatriz Susana; Echeverría, Gustavo Alberto; Piro, Oscar Enrique
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The new acesulfamate salt, TlC4H4NO4S, was prepared by reaction of acesulfamic acid and thallium(I) carbonate in aqueous solution. Its crystal and molecular structure was determined by single crystal X-ray diffraction methods. The substance crystallizes in the monoclinic space group P21/a, with unit cell parameters a = 7.5844(4) Å, b = 9.7268(5) Å, c = 10.8105(5) Å, β = 105.174(6)°, and Z = 4 molecules per unit cell, and is isostructural with the corresponding sodium, potassium, rubidium and cesium salts. The FTIR and Raman spectra of the compound are also recorded and briefly discussed.
Centro de Química Inorgánica
Instituto de Física La Plata - Materia
-
Química
Thallium(I) acesulfamate
Synthesis
Crystal structure
IR spectra
Raman spectra - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc/4.0/
- Repositorio
.jpg)
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/128456
Ver los metadatos del registro completo
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Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamateBaran, Enrique JoséParajón Costa, Beatriz SusanaEcheverría, Gustavo AlbertoPiro, Oscar EnriqueQuímicaThallium(I) acesulfamateSynthesisCrystal structureIR spectraRaman spectraThe new acesulfamate salt, TlC4H4NO4S, was prepared by reaction of acesulfamic acid and thallium(I) carbonate in aqueous solution. Its crystal and molecular structure was determined by single crystal X-ray diffraction methods. The substance crystallizes in the monoclinic space group P21/a, with unit cell parameters a = 7.5844(4) Å, b = 9.7268(5) Å, c = 10.8105(5) Å, β = 105.174(6)°, and Z = 4 molecules per unit cell, and is isostructural with the corresponding sodium, potassium, rubidium and cesium salts. The FTIR and Raman spectra of the compound are also recorded and briefly discussed.Centro de Química InorgánicaInstituto de Física La Plata2015info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf95-100http://sedici.unlp.edu.ar/handle/10915/128456enginfo:eu-repo/semantics/altIdentifier/issn/1857-5552info:eu-repo/semantics/altIdentifier/issn/1857-5625info:eu-repo/semantics/altIdentifier/doi/10.20450/mjcce.2015.630info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc/4.0/Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-03T11:03:09Zoai:sedici.unlp.edu.ar:10915/128456Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-03 11:03:09.458SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate |
| title |
Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate |
| spellingShingle |
Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate Baran, Enrique José Química Thallium(I) acesulfamate Synthesis Crystal structure IR spectra Raman spectra |
| title_short |
Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate |
| title_full |
Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate |
| title_fullStr |
Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate |
| title_full_unstemmed |
Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate |
| title_sort |
Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate |
| dc.creator.none.fl_str_mv |
Baran, Enrique José Parajón Costa, Beatriz Susana Echeverría, Gustavo Alberto Piro, Oscar Enrique |
| author |
Baran, Enrique José |
| author_facet |
Baran, Enrique José Parajón Costa, Beatriz Susana Echeverría, Gustavo Alberto Piro, Oscar Enrique |
| author_role |
author |
| author2 |
Parajón Costa, Beatriz Susana Echeverría, Gustavo Alberto Piro, Oscar Enrique |
| author2_role |
author author author |
| dc.subject.none.fl_str_mv |
Química Thallium(I) acesulfamate Synthesis Crystal structure IR spectra Raman spectra |
| topic |
Química Thallium(I) acesulfamate Synthesis Crystal structure IR spectra Raman spectra |
| dc.description.none.fl_txt_mv |
The new acesulfamate salt, TlC4H4NO4S, was prepared by reaction of acesulfamic acid and thallium(I) carbonate in aqueous solution. Its crystal and molecular structure was determined by single crystal X-ray diffraction methods. The substance crystallizes in the monoclinic space group P21/a, with unit cell parameters a = 7.5844(4) Å, b = 9.7268(5) Å, c = 10.8105(5) Å, β = 105.174(6)°, and Z = 4 molecules per unit cell, and is isostructural with the corresponding sodium, potassium, rubidium and cesium salts. The FTIR and Raman spectra of the compound are also recorded and briefly discussed. Centro de Química Inorgánica Instituto de Física La Plata |
| description |
The new acesulfamate salt, TlC4H4NO4S, was prepared by reaction of acesulfamic acid and thallium(I) carbonate in aqueous solution. Its crystal and molecular structure was determined by single crystal X-ray diffraction methods. The substance crystallizes in the monoclinic space group P21/a, with unit cell parameters a = 7.5844(4) Å, b = 9.7268(5) Å, c = 10.8105(5) Å, β = 105.174(6)°, and Z = 4 molecules per unit cell, and is isostructural with the corresponding sodium, potassium, rubidium and cesium salts. The FTIR and Raman spectra of the compound are also recorded and briefly discussed. |
| publishDate |
2015 |
| dc.date.none.fl_str_mv |
2015 |
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info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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publishedVersion |
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http://sedici.unlp.edu.ar/handle/10915/128456 |
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eng |
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eng |
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openAccess |
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