Synthesis and characterization of ammonium acesulfamate
- Autores
- Echeverría, Gustavo Alberto; Piro, Oscar Enrique; Parajón Costa, Beatriz S.; Barán, Enrique José
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Ammonium acesulfamate, (NH4)C4H4NO 4S, was prepared by the reaction of acesulfamic acid and ammonium carbonate in aqueous solution, and characterized by elemental analysis and 1H and 13C NMR spectroscopy. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods. The substance crystallizes in the orthorhombic space group Pnma with Z = 4 molecules per unit cell. The NH4 + ion generates medium to strong hydrogen bonds with the carbonylic oxygen, the iminic nitrogen and the sulfonyl oxygen atoms of the acesulfamate anion. The FTIR spectrum of the compound was also recorded and is briefly discussed.
Facultad de Ciencias Exactas
Instituto de Física La Plata
Centro de Química Inorgánica - Materia
-
Química
Ammonium Acesulfamate
Crystal Structure
FTIR Spectra
Synthesis - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-sa/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/85161
Ver los metadatos del registro completo
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Synthesis and characterization of ammonium acesulfamateEcheverría, Gustavo AlbertoPiro, Oscar EnriqueParajón Costa, Beatriz S.Barán, Enrique JoséQuímicaAmmonium AcesulfamateCrystal StructureFTIR SpectraSynthesisAmmonium acesulfamate, (NH4)C4H4NO 4S, was prepared by the reaction of acesulfamic acid and ammonium carbonate in aqueous solution, and characterized by elemental analysis and 1H and 13C NMR spectroscopy. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods. The substance crystallizes in the orthorhombic space group Pnma with Z = 4 molecules per unit cell. The NH4 + ion generates medium to strong hydrogen bonds with the carbonylic oxygen, the iminic nitrogen and the sulfonyl oxygen atoms of the acesulfamate anion. The FTIR spectrum of the compound was also recorded and is briefly discussed.Facultad de Ciencias ExactasInstituto de Física La PlataCentro de Química Inorgánica2014info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf737-741http://sedici.unlp.edu.ar/handle/10915/85161enginfo:eu-repo/semantics/altIdentifier/issn/0932-0776info:eu-repo/semantics/altIdentifier/doi/10.5560/ZNB.2014-4061info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-03T10:48:41Zoai:sedici.unlp.edu.ar:10915/85161Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-03 10:48:42.032SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
Synthesis and characterization of ammonium acesulfamate |
title |
Synthesis and characterization of ammonium acesulfamate |
spellingShingle |
Synthesis and characterization of ammonium acesulfamate Echeverría, Gustavo Alberto Química Ammonium Acesulfamate Crystal Structure FTIR Spectra Synthesis |
title_short |
Synthesis and characterization of ammonium acesulfamate |
title_full |
Synthesis and characterization of ammonium acesulfamate |
title_fullStr |
Synthesis and characterization of ammonium acesulfamate |
title_full_unstemmed |
Synthesis and characterization of ammonium acesulfamate |
title_sort |
Synthesis and characterization of ammonium acesulfamate |
dc.creator.none.fl_str_mv |
Echeverría, Gustavo Alberto Piro, Oscar Enrique Parajón Costa, Beatriz S. Barán, Enrique José |
author |
Echeverría, Gustavo Alberto |
author_facet |
Echeverría, Gustavo Alberto Piro, Oscar Enrique Parajón Costa, Beatriz S. Barán, Enrique José |
author_role |
author |
author2 |
Piro, Oscar Enrique Parajón Costa, Beatriz S. Barán, Enrique José |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Química Ammonium Acesulfamate Crystal Structure FTIR Spectra Synthesis |
topic |
Química Ammonium Acesulfamate Crystal Structure FTIR Spectra Synthesis |
dc.description.none.fl_txt_mv |
Ammonium acesulfamate, (NH4)C4H4NO 4S, was prepared by the reaction of acesulfamic acid and ammonium carbonate in aqueous solution, and characterized by elemental analysis and 1H and 13C NMR spectroscopy. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods. The substance crystallizes in the orthorhombic space group Pnma with Z = 4 molecules per unit cell. The NH4 + ion generates medium to strong hydrogen bonds with the carbonylic oxygen, the iminic nitrogen and the sulfonyl oxygen atoms of the acesulfamate anion. The FTIR spectrum of the compound was also recorded and is briefly discussed. Facultad de Ciencias Exactas Instituto de Física La Plata Centro de Química Inorgánica |
description |
Ammonium acesulfamate, (NH4)C4H4NO 4S, was prepared by the reaction of acesulfamic acid and ammonium carbonate in aqueous solution, and characterized by elemental analysis and 1H and 13C NMR spectroscopy. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods. The substance crystallizes in the orthorhombic space group Pnma with Z = 4 molecules per unit cell. The NH4 + ion generates medium to strong hydrogen bonds with the carbonylic oxygen, the iminic nitrogen and the sulfonyl oxygen atoms of the acesulfamate anion. The FTIR spectrum of the compound was also recorded and is briefly discussed. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/85161 |
url |
http://sedici.unlp.edu.ar/handle/10915/85161 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/0932-0776 info:eu-repo/semantics/altIdentifier/doi/10.5560/ZNB.2014-4061 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
dc.format.none.fl_str_mv |
application/pdf 737-741 |
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