Synthesis and characterization of ammonium acesulfamate

Autores
Echeverría, Gustavo Alberto; Piro, Oscar Enrique; Parajón Costa, Beatriz S.; Barán, Enrique José
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Ammonium acesulfamate, (NH4)C4H4NO 4S, was prepared by the reaction of acesulfamic acid and ammonium carbonate in aqueous solution, and characterized by elemental analysis and 1H and 13C NMR spectroscopy. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods. The substance crystallizes in the orthorhombic space group Pnma with Z = 4 molecules per unit cell. The NH4 + ion generates medium to strong hydrogen bonds with the carbonylic oxygen, the iminic nitrogen and the sulfonyl oxygen atoms of the acesulfamate anion. The FTIR spectrum of the compound was also recorded and is briefly discussed.
Facultad de Ciencias Exactas
Instituto de Física La Plata
Centro de Química Inorgánica
Materia
Química
Ammonium Acesulfamate
Crystal Structure
FTIR Spectra
Synthesis
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/85161
Acceder
id SEDICI_608b12ff0b8976bb83f8181f0592868f
oai_identifier_str oai:sedici.unlp.edu.ar:10915/85161
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Synthesis and characterization of ammonium acesulfamateEcheverría, Gustavo AlbertoPiro, Oscar EnriqueParajón Costa, Beatriz S.Barán, Enrique JoséQuímicaAmmonium AcesulfamateCrystal StructureFTIR SpectraSynthesisAmmonium acesulfamate, (NH4)C4H4NO 4S, was prepared by the reaction of acesulfamic acid and ammonium carbonate in aqueous solution, and characterized by elemental analysis and 1H and 13C NMR spectroscopy. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods. The substance crystallizes in the orthorhombic space group Pnma with Z = 4 molecules per unit cell. The NH4 + ion generates medium to strong hydrogen bonds with the carbonylic oxygen, the iminic nitrogen and the sulfonyl oxygen atoms of the acesulfamate anion. The FTIR spectrum of the compound was also recorded and is briefly discussed.Facultad de Ciencias ExactasInstituto de Física La PlataCentro de Química Inorgánica2014info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf737-741http://sedici.unlp.edu.ar/handle/10915/85161enginfo:eu-repo/semantics/altIdentifier/issn/0932-0776info:eu-repo/semantics/altIdentifier/doi/10.5560/ZNB.2014-4061info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:16:24Zoai:sedici.unlp.edu.ar:10915/85161Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:16:25.145SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Synthesis and characterization of ammonium acesulfamate
title Synthesis and characterization of ammonium acesulfamate
spellingShingle Synthesis and characterization of ammonium acesulfamate
Echeverría, Gustavo Alberto
Química
Ammonium Acesulfamate
Crystal Structure
FTIR Spectra
Synthesis
title_short Synthesis and characterization of ammonium acesulfamate
title_full Synthesis and characterization of ammonium acesulfamate
title_fullStr Synthesis and characterization of ammonium acesulfamate
title_full_unstemmed Synthesis and characterization of ammonium acesulfamate
title_sort Synthesis and characterization of ammonium acesulfamate
dc.creator.none.fl_str_mv Echeverría, Gustavo Alberto
Piro, Oscar Enrique
Parajón Costa, Beatriz S.
Barán, Enrique José
author Echeverría, Gustavo Alberto
author_facet Echeverría, Gustavo Alberto
Piro, Oscar Enrique
Parajón Costa, Beatriz S.
Barán, Enrique José
author_role author
author2 Piro, Oscar Enrique
Parajón Costa, Beatriz S.
Barán, Enrique José
author2_role author
author
author
dc.subject.none.fl_str_mv Química
Ammonium Acesulfamate
Crystal Structure
FTIR Spectra
Synthesis
topic Química
Ammonium Acesulfamate
Crystal Structure
FTIR Spectra
Synthesis
dc.description.none.fl_txt_mv Ammonium acesulfamate, (NH4)C4H4NO 4S, was prepared by the reaction of acesulfamic acid and ammonium carbonate in aqueous solution, and characterized by elemental analysis and 1H and 13C NMR spectroscopy. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods. The substance crystallizes in the orthorhombic space group Pnma with Z = 4 molecules per unit cell. The NH4 + ion generates medium to strong hydrogen bonds with the carbonylic oxygen, the iminic nitrogen and the sulfonyl oxygen atoms of the acesulfamate anion. The FTIR spectrum of the compound was also recorded and is briefly discussed.
Facultad de Ciencias Exactas
Instituto de Física La Plata
Centro de Química Inorgánica
description Ammonium acesulfamate, (NH4)C4H4NO 4S, was prepared by the reaction of acesulfamic acid and ammonium carbonate in aqueous solution, and characterized by elemental analysis and 1H and 13C NMR spectroscopy. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods. The substance crystallizes in the orthorhombic space group Pnma with Z = 4 molecules per unit cell. The NH4 + ion generates medium to strong hydrogen bonds with the carbonylic oxygen, the iminic nitrogen and the sulfonyl oxygen atoms of the acesulfamate anion. The FTIR spectrum of the compound was also recorded and is briefly discussed.
publishDate 2014
dc.date.none.fl_str_mv 2014
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/85161
url http://sedici.unlp.edu.ar/handle/10915/85161
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0932-0776
info:eu-repo/semantics/altIdentifier/doi/10.5560/ZNB.2014-4061
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
737-741
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.069144

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