Structural and IR-spectroscopic characterization of cadmium and lead(II) acesulfamates

Autores
Echeverría, Gustavo Alberto; Piro, Oscar Enrique; Parajón Costa, Beatriz Susana; Baran, Enrique José
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Cadmium and lead(II) acesulfamate, Cd(C4H4NO4S)2 2H2O and Pb(C4H4NO4S)2, were prepared by the reaction of acesulfamic acid and the respective metal carbonates in aqueous solution, and characterized by elemental analysis. Their crystal structures were determined by single crystal X-ray diffraction methods. The Cd(II) compound crystallizes in the monoclinic space group P21/c with Z = 4 and the corresponding Pb(II) salt in the triclinic space group P1 with Z = 2. In both salts, acesulfamate acts both as a bi-dentate ligand through its nitrogen and carbonyl oxygen atoms and also as a mono-dentate ligand through this same oxygen atom, giving rise to polymeric structures; in the Pb(II) salt the ligand also binds the cation through its sulfoxido oxygen atoms. The FTIR spectra of the compounds were recorded and are briefly discussed. Some comparisons with other related acesulfamate and saccharinate complexes are made.
Fil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Materia
Cadmium Acesulfamate
Crystal Structures
Ftir Spectra
Lead(Ii) Acesulfamate
Synthesis
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/64343
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/64343
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Structural and IR-spectroscopic characterization of cadmium and lead(II) acesulfamatesEcheverría, Gustavo AlbertoPiro, Oscar EnriqueParajón Costa, Beatriz SusanaBaran, Enrique JoséCadmium AcesulfamateCrystal StructuresFtir SpectraLead(Ii) AcesulfamateSynthesishttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Cadmium and lead(II) acesulfamate, Cd(C4H4NO4S)2 2H2O and Pb(C4H4NO4S)2, were prepared by the reaction of acesulfamic acid and the respective metal carbonates in aqueous solution, and characterized by elemental analysis. Their crystal structures were determined by single crystal X-ray diffraction methods. The Cd(II) compound crystallizes in the monoclinic space group P21/c with Z = 4 and the corresponding Pb(II) salt in the triclinic space group P1 with Z = 2. In both salts, acesulfamate acts both as a bi-dentate ligand through its nitrogen and carbonyl oxygen atoms and also as a mono-dentate ligand through this same oxygen atom, giving rise to polymeric structures; in the Pb(II) salt the ligand also binds the cation through its sulfoxido oxygen atoms. The FTIR spectra of the compounds were recorded and are briefly discussed. Some comparisons with other related acesulfamate and saccharinate complexes are made.Fil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaVerlag der Zeitschrift für Naturforschung2017-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/64343Echeverría, Gustavo Alberto; Piro, Oscar Enrique; Parajón Costa, Beatriz Susana; Baran, Enrique José; Structural and IR-spectroscopic characterization of cadmium and lead(II) acesulfamates; Verlag der Zeitschrift für Naturforschung; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 72; 10; 10-2017; 739-7450932-0776CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2017-0116info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/znb.2017.72.issue-10/znb-2017-0116/znb-2017-0116.xmlinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:49:45Zoai:ri.conicet.gov.ar:11336/64343instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:49:45.541CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Structural and IR-spectroscopic characterization of cadmium and lead(II) acesulfamates
title Structural and IR-spectroscopic characterization of cadmium and lead(II) acesulfamates
spellingShingle Structural and IR-spectroscopic characterization of cadmium and lead(II) acesulfamates
Echeverría, Gustavo Alberto
Cadmium Acesulfamate
Crystal Structures
Ftir Spectra
Lead(Ii) Acesulfamate
Synthesis
title_short Structural and IR-spectroscopic characterization of cadmium and lead(II) acesulfamates
title_full Structural and IR-spectroscopic characterization of cadmium and lead(II) acesulfamates
title_fullStr Structural and IR-spectroscopic characterization of cadmium and lead(II) acesulfamates
title_full_unstemmed Structural and IR-spectroscopic characterization of cadmium and lead(II) acesulfamates
title_sort Structural and IR-spectroscopic characterization of cadmium and lead(II) acesulfamates
dc.creator.none.fl_str_mv Echeverría, Gustavo Alberto
Piro, Oscar Enrique
Parajón Costa, Beatriz Susana
Baran, Enrique José
author Echeverría, Gustavo Alberto
author_facet Echeverría, Gustavo Alberto
Piro, Oscar Enrique
Parajón Costa, Beatriz Susana
Baran, Enrique José
author_role author
author2 Piro, Oscar Enrique
Parajón Costa, Beatriz Susana
Baran, Enrique José
author2_role author
author
author
dc.subject.none.fl_str_mv Cadmium Acesulfamate
Crystal Structures
Ftir Spectra
Lead(Ii) Acesulfamate
Synthesis
topic Cadmium Acesulfamate
Crystal Structures
Ftir Spectra
Lead(Ii) Acesulfamate
Synthesis
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Cadmium and lead(II) acesulfamate, Cd(C4H4NO4S)2 2H2O and Pb(C4H4NO4S)2, were prepared by the reaction of acesulfamic acid and the respective metal carbonates in aqueous solution, and characterized by elemental analysis. Their crystal structures were determined by single crystal X-ray diffraction methods. The Cd(II) compound crystallizes in the monoclinic space group P21/c with Z = 4 and the corresponding Pb(II) salt in the triclinic space group P1 with Z = 2. In both salts, acesulfamate acts both as a bi-dentate ligand through its nitrogen and carbonyl oxygen atoms and also as a mono-dentate ligand through this same oxygen atom, giving rise to polymeric structures; in the Pb(II) salt the ligand also binds the cation through its sulfoxido oxygen atoms. The FTIR spectra of the compounds were recorded and are briefly discussed. Some comparisons with other related acesulfamate and saccharinate complexes are made.
Fil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
description Cadmium and lead(II) acesulfamate, Cd(C4H4NO4S)2 2H2O and Pb(C4H4NO4S)2, were prepared by the reaction of acesulfamic acid and the respective metal carbonates in aqueous solution, and characterized by elemental analysis. Their crystal structures were determined by single crystal X-ray diffraction methods. The Cd(II) compound crystallizes in the monoclinic space group P21/c with Z = 4 and the corresponding Pb(II) salt in the triclinic space group P1 with Z = 2. In both salts, acesulfamate acts both as a bi-dentate ligand through its nitrogen and carbonyl oxygen atoms and also as a mono-dentate ligand through this same oxygen atom, giving rise to polymeric structures; in the Pb(II) salt the ligand also binds the cation through its sulfoxido oxygen atoms. The FTIR spectra of the compounds were recorded and are briefly discussed. Some comparisons with other related acesulfamate and saccharinate complexes are made.
publishDate 2017
dc.date.none.fl_str_mv 2017-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/64343
Echeverría, Gustavo Alberto; Piro, Oscar Enrique; Parajón Costa, Beatriz Susana; Baran, Enrique José; Structural and IR-spectroscopic characterization of cadmium and lead(II) acesulfamates; Verlag der Zeitschrift für Naturforschung; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 72; 10; 10-2017; 739-745
0932-0776
CONICET Digital
CONICET
url http://hdl.handle.net/11336/64343
identifier_str_mv Echeverría, Gustavo Alberto; Piro, Oscar Enrique; Parajón Costa, Beatriz Susana; Baran, Enrique José; Structural and IR-spectroscopic characterization of cadmium and lead(II) acesulfamates; Verlag der Zeitschrift für Naturforschung; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 72; 10; 10-2017; 739-745
0932-0776
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2017-0116
info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/znb.2017.72.issue-10/znb-2017-0116/znb-2017-0116.xml
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Verlag der Zeitschrift für Naturforschung
publisher.none.fl_str_mv Verlag der Zeitschrift für Naturforschung
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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