Phenomenology related to the kinetics of Kolbe electrosynthesis

Autores
Cerviño, R. M.; Triaca, Walter Enrique; Arvia, Alejandro Jorge
Año de publicación
1984
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The Kolbe electrosynthesis on polycrystalline platinum in 1 M acetic acid/1 M potassium acetate electrolyte at 30 ° C was studied by using potentiostatic, low-frequency potentiodynamic and impedance techniques. Reaction products and their distribution as a function of potential were determined. There is a good correspondence in the potential ranges where changes in both stationary and non-stationary kinetic data, electrode resistance, electrode capacitance and reaction products were found. Results confirm the existence of different electrochemical reactions and correspondingly different reaction intermediates in the various Tafel regions.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Ciencias Exactas
Química
Kolbe electrosynthesis
Kinetics
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/122408
Acceder
id SEDICI_b66ceb888ebe128f62c4dbfbeb1b60f9
oai_identifier_str oai:sedici.unlp.edu.ar:10915/122408
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Phenomenology related to the kinetics of Kolbe electrosynthesisCerviño, R. M.Triaca, Walter EnriqueArvia, Alejandro JorgeCiencias ExactasQuímicaKolbe electrosynthesisKineticsThe Kolbe electrosynthesis on polycrystalline platinum in 1 M acetic acid/1 M potassium acetate electrolyte at 30 ° C was studied by using potentiostatic, low-frequency potentiodynamic and impedance techniques. Reaction products and their distribution as a function of potential were determined. There is a good correspondence in the potential ranges where changes in both stationary and non-stationary kinetic data, electrode resistance, electrode capacitance and reaction products were found. Results confirm the existence of different electrochemical reactions and correspondingly different reaction intermediates in the various Tafel regions.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1984-08-24info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf255-264http://sedici.unlp.edu.ar/handle/10915/122408enginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/0022072884801904?via%3Dihubinfo:eu-repo/semantics/altIdentifier/issn/0022-0728info:eu-repo/semantics/altIdentifier/doi/10.1016/0022-0728(84)80190-4info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:29:08Zoai:sedici.unlp.edu.ar:10915/122408Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:29:09.27SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Phenomenology related to the kinetics of Kolbe electrosynthesis
title Phenomenology related to the kinetics of Kolbe electrosynthesis
spellingShingle Phenomenology related to the kinetics of Kolbe electrosynthesis
Cerviño, R. M.
Ciencias Exactas
Química
Kolbe electrosynthesis
Kinetics
title_short Phenomenology related to the kinetics of Kolbe electrosynthesis
title_full Phenomenology related to the kinetics of Kolbe electrosynthesis
title_fullStr Phenomenology related to the kinetics of Kolbe electrosynthesis
title_full_unstemmed Phenomenology related to the kinetics of Kolbe electrosynthesis
title_sort Phenomenology related to the kinetics of Kolbe electrosynthesis
dc.creator.none.fl_str_mv Cerviño, R. M.
Triaca, Walter Enrique
Arvia, Alejandro Jorge
author Cerviño, R. M.
author_facet Cerviño, R. M.
Triaca, Walter Enrique
Arvia, Alejandro Jorge
author_role author
author2 Triaca, Walter Enrique
Arvia, Alejandro Jorge
author2_role author
author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
Kolbe electrosynthesis
Kinetics
topic Ciencias Exactas
Química
Kolbe electrosynthesis
Kinetics
dc.description.none.fl_txt_mv The Kolbe electrosynthesis on polycrystalline platinum in 1 M acetic acid/1 M potassium acetate electrolyte at 30 ° C was studied by using potentiostatic, low-frequency potentiodynamic and impedance techniques. Reaction products and their distribution as a function of potential were determined. There is a good correspondence in the potential ranges where changes in both stationary and non-stationary kinetic data, electrode resistance, electrode capacitance and reaction products were found. Results confirm the existence of different electrochemical reactions and correspondingly different reaction intermediates in the various Tafel regions.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description The Kolbe electrosynthesis on polycrystalline platinum in 1 M acetic acid/1 M potassium acetate electrolyte at 30 ° C was studied by using potentiostatic, low-frequency potentiodynamic and impedance techniques. Reaction products and their distribution as a function of potential were determined. There is a good correspondence in the potential ranges where changes in both stationary and non-stationary kinetic data, electrode resistance, electrode capacitance and reaction products were found. Results confirm the existence of different electrochemical reactions and correspondingly different reaction intermediates in the various Tafel regions.
publishDate 1984
dc.date.none.fl_str_mv 1984-08-24
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/122408
url http://sedici.unlp.edu.ar/handle/10915/122408
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/0022072884801904?via%3Dihub
info:eu-repo/semantics/altIdentifier/issn/0022-0728
info:eu-repo/semantics/altIdentifier/doi/10.1016/0022-0728(84)80190-4
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
255-264
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
_version_ 1844616170363158528
score 13.070432

Publicaciones similares