A crystallographic and vibrational study of cesium di-μ-aqua bis[tetraaquasodium(I)] decavanadate, Cs₄[Na₂(H₂O)₁₀](V₁₀O₂₈)

Autores
Piro, Oscar Enrique; Varetti, Eduardo Lelio; Brandán, Silvia Antonia; Altabef, A. Ben
Año de publicación
2003
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The title compound crystallizes in the triclinic space group P͞1, with a = 8.6161(4) Å, b = 10.591(1) Å, c = 11.406(1) Å, α = 67.976(7)°, β = 86.868(6)°, γ = 67.798(6)°, and Z = 1. The structure was refined to R1 = 0.0413. The decavanadate anion V₁₀O₂₈⁶⁻ and the [Na₂(H₂O)₁₀]²⁺ bridged cation are located at inversion centers. Partial deuteration of the substance indicates that the coordinated water molecules are strongly asymmetric, forming weak hydrogen bonds with acceptor oxygen atoms from the decavanadate anion. The infrared and Raman spectra are dominated by the water and decavanadate anion bands.
Instituto de Física La Plata
Centro de Química Inorgánica
Materia
Ciencias Exactas
Química
decavanadate
cesium
water bridged sodium dimeric group
crystal structure
infrared spectrum
Raman spectrum
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/146449
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/146449
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling A crystallographic and vibrational study of cesium di-μ-aqua bis[tetraaquasodium(I)] decavanadate, Cs₄[Na₂(H₂O)₁₀](V₁₀O₂₈)Piro, Oscar EnriqueVaretti, Eduardo LelioBrandán, Silvia AntoniaAltabef, A. BenCiencias ExactasQuímicadecavanadatecesiumwater bridged sodium dimeric groupcrystal structureinfrared spectrumRaman spectrumThe title compound crystallizes in the triclinic space group P͞1, with a = 8.6161(4) Å, b = 10.591(1) Å, c = 11.406(1) Å, α = 67.976(7)°, β = 86.868(6)°, γ = 67.798(6)°, and Z = 1. The structure was refined to R1 = 0.0413. The decavanadate anion V₁₀O₂₈⁶⁻ and the [Na₂(H₂O)₁₀]²⁺ bridged cation are located at inversion centers. Partial deuteration of the substance indicates that the coordinated water molecules are strongly asymmetric, forming weak hydrogen bonds with acceptor oxygen atoms from the decavanadate anion. The infrared and Raman spectra are dominated by the water and decavanadate anion bands.Instituto de Física La PlataCentro de Química Inorgánica2003-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf57-63http://sedici.unlp.edu.ar/handle/10915/146449enginfo:eu-repo/semantics/altIdentifier/issn/1074-1542info:eu-repo/semantics/altIdentifier/issn/1572-8854info:eu-repo/semantics/altIdentifier/doi/10.1023/a:1021303917680info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:32:26Zoai:sedici.unlp.edu.ar:10915/146449Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:32:27.052SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv A crystallographic and vibrational study of cesium di-μ-aqua bis[tetraaquasodium(I)] decavanadate, Cs₄[Na₂(H₂O)₁₀](V₁₀O₂₈)
title A crystallographic and vibrational study of cesium di-μ-aqua bis[tetraaquasodium(I)] decavanadate, Cs₄[Na₂(H₂O)₁₀](V₁₀O₂₈)
spellingShingle A crystallographic and vibrational study of cesium di-μ-aqua bis[tetraaquasodium(I)] decavanadate, Cs₄[Na₂(H₂O)₁₀](V₁₀O₂₈)
Piro, Oscar Enrique
Ciencias Exactas
Química
decavanadate
cesium
water bridged sodium dimeric group
crystal structure
infrared spectrum
Raman spectrum
title_short A crystallographic and vibrational study of cesium di-μ-aqua bis[tetraaquasodium(I)] decavanadate, Cs₄[Na₂(H₂O)₁₀](V₁₀O₂₈)
title_full A crystallographic and vibrational study of cesium di-μ-aqua bis[tetraaquasodium(I)] decavanadate, Cs₄[Na₂(H₂O)₁₀](V₁₀O₂₈)
title_fullStr A crystallographic and vibrational study of cesium di-μ-aqua bis[tetraaquasodium(I)] decavanadate, Cs₄[Na₂(H₂O)₁₀](V₁₀O₂₈)
title_full_unstemmed A crystallographic and vibrational study of cesium di-μ-aqua bis[tetraaquasodium(I)] decavanadate, Cs₄[Na₂(H₂O)₁₀](V₁₀O₂₈)
title_sort A crystallographic and vibrational study of cesium di-μ-aqua bis[tetraaquasodium(I)] decavanadate, Cs₄[Na₂(H₂O)₁₀](V₁₀O₂₈)
dc.creator.none.fl_str_mv Piro, Oscar Enrique
Varetti, Eduardo Lelio
Brandán, Silvia Antonia
Altabef, A. Ben
author Piro, Oscar Enrique
author_facet Piro, Oscar Enrique
Varetti, Eduardo Lelio
Brandán, Silvia Antonia
Altabef, A. Ben
author_role author
author2 Varetti, Eduardo Lelio
Brandán, Silvia Antonia
Altabef, A. Ben
author2_role author
author
author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
decavanadate
cesium
water bridged sodium dimeric group
crystal structure
infrared spectrum
Raman spectrum
topic Ciencias Exactas
Química
decavanadate
cesium
water bridged sodium dimeric group
crystal structure
infrared spectrum
Raman spectrum
dc.description.none.fl_txt_mv The title compound crystallizes in the triclinic space group P͞1, with a = 8.6161(4) Å, b = 10.591(1) Å, c = 11.406(1) Å, α = 67.976(7)°, β = 86.868(6)°, γ = 67.798(6)°, and Z = 1. The structure was refined to R1 = 0.0413. The decavanadate anion V₁₀O₂₈⁶⁻ and the [Na₂(H₂O)₁₀]²⁺ bridged cation are located at inversion centers. Partial deuteration of the substance indicates that the coordinated water molecules are strongly asymmetric, forming weak hydrogen bonds with acceptor oxygen atoms from the decavanadate anion. The infrared and Raman spectra are dominated by the water and decavanadate anion bands.
Instituto de Física La Plata
Centro de Química Inorgánica
description The title compound crystallizes in the triclinic space group P͞1, with a = 8.6161(4) Å, b = 10.591(1) Å, c = 11.406(1) Å, α = 67.976(7)°, β = 86.868(6)°, γ = 67.798(6)°, and Z = 1. The structure was refined to R1 = 0.0413. The decavanadate anion V₁₀O₂₈⁶⁻ and the [Na₂(H₂O)₁₀]²⁺ bridged cation are located at inversion centers. Partial deuteration of the substance indicates that the coordinated water molecules are strongly asymmetric, forming weak hydrogen bonds with acceptor oxygen atoms from the decavanadate anion. The infrared and Raman spectra are dominated by the water and decavanadate anion bands.
publishDate 2003
dc.date.none.fl_str_mv 2003-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/146449
url http://sedici.unlp.edu.ar/handle/10915/146449
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1074-1542
info:eu-repo/semantics/altIdentifier/issn/1572-8854
info:eu-repo/semantics/altIdentifier/doi/10.1023/a:1021303917680
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
57-63
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.070432

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