Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates
- Autores
- Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Castellano, Eduardo Ernesto; Parajón Costa, Beatriz Susana; Baran, Enrique José
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Three new acesulfamate salts, NaC4H4NO4S, RbC4H4NO4S and CsC4H4NO4S, were prepared by reactions in aqueous solutions and thoroughly characterized. Their crystal and molecular structures were determined by single crystal X-ray diffraction methods. They crystallize in the monoclinic space group P21/a with a = 7.2518(2), b = 8.9414(4), c = 10.5929(4) Å, β = 99.951(3)°, V = 676.52(4) Å3 for the Na salt; a = 7.4663(3), b = 9.6962(4), c = 10.4391(4) Å, β = 95.150(3)°, V = 752.68(5) Å3 for the Rb salt and a = 7.5995(4), b = 9.9439(4), c = 10.8814(6) Å, β = 91.298(5)°, V = 822.08(7) Å3 for the Cs salt, and Z = 4 molecules per unit cell. The three compounds are isotypic to each other and to the previously reported potassium salt. The metal ions are in irregular polyhedral coordination with six neighboring acesulfamate anions through their nitrogen and carbonyl and sulfoxide oxygen atoms. The FTIR spectra of the compounds were also recorded and are briefly discussed.
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Castellano, Eduardo Ernesto. Universidade de Sao Paulo; Brasil
Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina - Materia
-
CESIUM ACESULFAMATE
CRYSTAL STRUCTURE
FTIR SPECTRA
RUBIDIUM ACESULFAMATE
SODIUM ACESULFAMATE
SYNTHESIS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/182331
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Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamatesPiro, Oscar EnriqueEcheverría, Gustavo AlbertoCastellano, Eduardo ErnestoParajón Costa, Beatriz SusanaBaran, Enrique JoséCESIUM ACESULFAMATECRYSTAL STRUCTUREFTIR SPECTRARUBIDIUM ACESULFAMATESODIUM ACESULFAMATESYNTHESIShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Three new acesulfamate salts, NaC4H4NO4S, RbC4H4NO4S and CsC4H4NO4S, were prepared by reactions in aqueous solutions and thoroughly characterized. Their crystal and molecular structures were determined by single crystal X-ray diffraction methods. They crystallize in the monoclinic space group P21/a with a = 7.2518(2), b = 8.9414(4), c = 10.5929(4) Å, β = 99.951(3)°, V = 676.52(4) Å3 for the Na salt; a = 7.4663(3), b = 9.6962(4), c = 10.4391(4) Å, β = 95.150(3)°, V = 752.68(5) Å3 for the Rb salt and a = 7.5995(4), b = 9.9439(4), c = 10.8814(6) Å, β = 91.298(5)°, V = 822.08(7) Å3 for the Cs salt, and Z = 4 molecules per unit cell. The three compounds are isotypic to each other and to the previously reported potassium salt. The metal ions are in irregular polyhedral coordination with six neighboring acesulfamate anions through their nitrogen and carbonyl and sulfoxide oxygen atoms. The FTIR spectra of the compounds were also recorded and are briefly discussed.Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Castellano, Eduardo Ernesto. Universidade de Sao Paulo; BrasilFil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaVerlag der Zeitschrift für Naturforschung2015-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/182331Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Castellano, Eduardo Ernesto; Parajón Costa, Beatriz Susana; Baran, Enrique José; Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates; Verlag der Zeitschrift für Naturforschung; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 70; 7; 7-2015; 491-4960932-07761865-7117CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/document/doi/10.1515/znb-2015-0042/htmlinfo:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2015-0042info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:18:32Zoai:ri.conicet.gov.ar:11336/182331instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:18:33.221CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates |
title |
Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates |
spellingShingle |
Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates Piro, Oscar Enrique CESIUM ACESULFAMATE CRYSTAL STRUCTURE FTIR SPECTRA RUBIDIUM ACESULFAMATE SODIUM ACESULFAMATE SYNTHESIS |
title_short |
Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates |
title_full |
Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates |
title_fullStr |
Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates |
title_full_unstemmed |
Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates |
title_sort |
Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates |
dc.creator.none.fl_str_mv |
Piro, Oscar Enrique Echeverría, Gustavo Alberto Castellano, Eduardo Ernesto Parajón Costa, Beatriz Susana Baran, Enrique José |
author |
Piro, Oscar Enrique |
author_facet |
Piro, Oscar Enrique Echeverría, Gustavo Alberto Castellano, Eduardo Ernesto Parajón Costa, Beatriz Susana Baran, Enrique José |
author_role |
author |
author2 |
Echeverría, Gustavo Alberto Castellano, Eduardo Ernesto Parajón Costa, Beatriz Susana Baran, Enrique José |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
CESIUM ACESULFAMATE CRYSTAL STRUCTURE FTIR SPECTRA RUBIDIUM ACESULFAMATE SODIUM ACESULFAMATE SYNTHESIS |
topic |
CESIUM ACESULFAMATE CRYSTAL STRUCTURE FTIR SPECTRA RUBIDIUM ACESULFAMATE SODIUM ACESULFAMATE SYNTHESIS |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Three new acesulfamate salts, NaC4H4NO4S, RbC4H4NO4S and CsC4H4NO4S, were prepared by reactions in aqueous solutions and thoroughly characterized. Their crystal and molecular structures were determined by single crystal X-ray diffraction methods. They crystallize in the monoclinic space group P21/a with a = 7.2518(2), b = 8.9414(4), c = 10.5929(4) Å, β = 99.951(3)°, V = 676.52(4) Å3 for the Na salt; a = 7.4663(3), b = 9.6962(4), c = 10.4391(4) Å, β = 95.150(3)°, V = 752.68(5) Å3 for the Rb salt and a = 7.5995(4), b = 9.9439(4), c = 10.8814(6) Å, β = 91.298(5)°, V = 822.08(7) Å3 for the Cs salt, and Z = 4 molecules per unit cell. The three compounds are isotypic to each other and to the previously reported potassium salt. The metal ions are in irregular polyhedral coordination with six neighboring acesulfamate anions through their nitrogen and carbonyl and sulfoxide oxygen atoms. The FTIR spectra of the compounds were also recorded and are briefly discussed. Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina Fil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina Fil: Castellano, Eduardo Ernesto. Universidade de Sao Paulo; Brasil Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina |
description |
Three new acesulfamate salts, NaC4H4NO4S, RbC4H4NO4S and CsC4H4NO4S, were prepared by reactions in aqueous solutions and thoroughly characterized. Their crystal and molecular structures were determined by single crystal X-ray diffraction methods. They crystallize in the monoclinic space group P21/a with a = 7.2518(2), b = 8.9414(4), c = 10.5929(4) Å, β = 99.951(3)°, V = 676.52(4) Å3 for the Na salt; a = 7.4663(3), b = 9.6962(4), c = 10.4391(4) Å, β = 95.150(3)°, V = 752.68(5) Å3 for the Rb salt and a = 7.5995(4), b = 9.9439(4), c = 10.8814(6) Å, β = 91.298(5)°, V = 822.08(7) Å3 for the Cs salt, and Z = 4 molecules per unit cell. The three compounds are isotypic to each other and to the previously reported potassium salt. The metal ions are in irregular polyhedral coordination with six neighboring acesulfamate anions through their nitrogen and carbonyl and sulfoxide oxygen atoms. The FTIR spectra of the compounds were also recorded and are briefly discussed. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-07 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/182331 Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Castellano, Eduardo Ernesto; Parajón Costa, Beatriz Susana; Baran, Enrique José; Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates; Verlag der Zeitschrift für Naturforschung; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 70; 7; 7-2015; 491-496 0932-0776 1865-7117 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/182331 |
identifier_str_mv |
Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Castellano, Eduardo Ernesto; Parajón Costa, Beatriz Susana; Baran, Enrique José; Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates; Verlag der Zeitschrift für Naturforschung; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 70; 7; 7-2015; 491-496 0932-0776 1865-7117 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/document/doi/10.1515/znb-2015-0042/html info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2015-0042 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
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application/pdf application/pdf application/pdf application/pdf application/pdf |
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Verlag der Zeitschrift für Naturforschung |
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Verlag der Zeitschrift für Naturforschung |
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reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
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dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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