Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates

Autores
Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Castellano, Eduardo Ernesto; Parajón Costa, Beatriz Susana; Baran, Enrique José
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Three new acesulfamate salts, NaC4H4NO4S, RbC4H4NO4S and CsC4H4NO4S, were prepared by reactions in aqueous solutions and thoroughly characterized. Their crystal and molecular structures were determined by single crystal X-ray diffraction methods. They crystallize in the monoclinic space group P21/a with a = 7.2518(2), b = 8.9414(4), c = 10.5929(4) Å, β = 99.951(3)°, V = 676.52(4) Å3 for the Na salt; a = 7.4663(3), b = 9.6962(4), c = 10.4391(4) Å, β = 95.150(3)°, V = 752.68(5) Å3 for the Rb salt and a = 7.5995(4), b = 9.9439(4), c = 10.8814(6) Å, β = 91.298(5)°, V = 822.08(7) Å3 for the Cs salt, and Z = 4 molecules per unit cell. The three compounds are isotypic to each other and to the previously reported potassium salt. The metal ions are in irregular polyhedral coordination with six neighboring acesulfamate anions through their nitrogen and carbonyl and sulfoxide oxygen atoms. The FTIR spectra of the compounds were also recorded and are briefly discussed.
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Castellano, Eduardo Ernesto. Universidade de Sao Paulo; Brasil
Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Materia
CESIUM ACESULFAMATE
CRYSTAL STRUCTURE
FTIR SPECTRA
RUBIDIUM ACESULFAMATE
SODIUM ACESULFAMATE
SYNTHESIS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/182331
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/182331
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamatesPiro, Oscar EnriqueEcheverría, Gustavo AlbertoCastellano, Eduardo ErnestoParajón Costa, Beatriz SusanaBaran, Enrique JoséCESIUM ACESULFAMATECRYSTAL STRUCTUREFTIR SPECTRARUBIDIUM ACESULFAMATESODIUM ACESULFAMATESYNTHESIShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Three new acesulfamate salts, NaC4H4NO4S, RbC4H4NO4S and CsC4H4NO4S, were prepared by reactions in aqueous solutions and thoroughly characterized. Their crystal and molecular structures were determined by single crystal X-ray diffraction methods. They crystallize in the monoclinic space group P21/a with a = 7.2518(2), b = 8.9414(4), c = 10.5929(4) Å, β = 99.951(3)°, V = 676.52(4) Å3 for the Na salt; a = 7.4663(3), b = 9.6962(4), c = 10.4391(4) Å, β = 95.150(3)°, V = 752.68(5) Å3 for the Rb salt and a = 7.5995(4), b = 9.9439(4), c = 10.8814(6) Å, β = 91.298(5)°, V = 822.08(7) Å3 for the Cs salt, and Z = 4 molecules per unit cell. The three compounds are isotypic to each other and to the previously reported potassium salt. The metal ions are in irregular polyhedral coordination with six neighboring acesulfamate anions through their nitrogen and carbonyl and sulfoxide oxygen atoms. The FTIR spectra of the compounds were also recorded and are briefly discussed.Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Castellano, Eduardo Ernesto. Universidade de Sao Paulo; BrasilFil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaVerlag der Zeitschrift für Naturforschung2015-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/182331Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Castellano, Eduardo Ernesto; Parajón Costa, Beatriz Susana; Baran, Enrique José; Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates; Verlag der Zeitschrift für Naturforschung; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 70; 7; 7-2015; 491-4960932-07761865-7117CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/document/doi/10.1515/znb-2015-0042/htmlinfo:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2015-0042info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:15:46Zoai:ri.conicet.gov.ar:11336/182331instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:15:46.284CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates
title Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates
spellingShingle Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates
Piro, Oscar Enrique
CESIUM ACESULFAMATE
CRYSTAL STRUCTURE
FTIR SPECTRA
RUBIDIUM ACESULFAMATE
SODIUM ACESULFAMATE
SYNTHESIS
title_short Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates
title_full Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates
title_fullStr Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates
title_full_unstemmed Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates
title_sort Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates
dc.creator.none.fl_str_mv Piro, Oscar Enrique
Echeverría, Gustavo Alberto
Castellano, Eduardo Ernesto
Parajón Costa, Beatriz Susana
Baran, Enrique José
author Piro, Oscar Enrique
author_facet Piro, Oscar Enrique
Echeverría, Gustavo Alberto
Castellano, Eduardo Ernesto
Parajón Costa, Beatriz Susana
Baran, Enrique José
author_role author
author2 Echeverría, Gustavo Alberto
Castellano, Eduardo Ernesto
Parajón Costa, Beatriz Susana
Baran, Enrique José
author2_role author
author
author
author
dc.subject.none.fl_str_mv CESIUM ACESULFAMATE
CRYSTAL STRUCTURE
FTIR SPECTRA
RUBIDIUM ACESULFAMATE
SODIUM ACESULFAMATE
SYNTHESIS
topic CESIUM ACESULFAMATE
CRYSTAL STRUCTURE
FTIR SPECTRA
RUBIDIUM ACESULFAMATE
SODIUM ACESULFAMATE
SYNTHESIS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Three new acesulfamate salts, NaC4H4NO4S, RbC4H4NO4S and CsC4H4NO4S, were prepared by reactions in aqueous solutions and thoroughly characterized. Their crystal and molecular structures were determined by single crystal X-ray diffraction methods. They crystallize in the monoclinic space group P21/a with a = 7.2518(2), b = 8.9414(4), c = 10.5929(4) Å, β = 99.951(3)°, V = 676.52(4) Å3 for the Na salt; a = 7.4663(3), b = 9.6962(4), c = 10.4391(4) Å, β = 95.150(3)°, V = 752.68(5) Å3 for the Rb salt and a = 7.5995(4), b = 9.9439(4), c = 10.8814(6) Å, β = 91.298(5)°, V = 822.08(7) Å3 for the Cs salt, and Z = 4 molecules per unit cell. The three compounds are isotypic to each other and to the previously reported potassium salt. The metal ions are in irregular polyhedral coordination with six neighboring acesulfamate anions through their nitrogen and carbonyl and sulfoxide oxygen atoms. The FTIR spectra of the compounds were also recorded and are briefly discussed.
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Castellano, Eduardo Ernesto. Universidade de Sao Paulo; Brasil
Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
description Three new acesulfamate salts, NaC4H4NO4S, RbC4H4NO4S and CsC4H4NO4S, were prepared by reactions in aqueous solutions and thoroughly characterized. Their crystal and molecular structures were determined by single crystal X-ray diffraction methods. They crystallize in the monoclinic space group P21/a with a = 7.2518(2), b = 8.9414(4), c = 10.5929(4) Å, β = 99.951(3)°, V = 676.52(4) Å3 for the Na salt; a = 7.4663(3), b = 9.6962(4), c = 10.4391(4) Å, β = 95.150(3)°, V = 752.68(5) Å3 for the Rb salt and a = 7.5995(4), b = 9.9439(4), c = 10.8814(6) Å, β = 91.298(5)°, V = 822.08(7) Å3 for the Cs salt, and Z = 4 molecules per unit cell. The three compounds are isotypic to each other and to the previously reported potassium salt. The metal ions are in irregular polyhedral coordination with six neighboring acesulfamate anions through their nitrogen and carbonyl and sulfoxide oxygen atoms. The FTIR spectra of the compounds were also recorded and are briefly discussed.
publishDate 2015
dc.date.none.fl_str_mv 2015-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/182331
Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Castellano, Eduardo Ernesto; Parajón Costa, Beatriz Susana; Baran, Enrique José; Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates; Verlag der Zeitschrift für Naturforschung; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 70; 7; 7-2015; 491-496
0932-0776
1865-7117
CONICET Digital
CONICET
url http://hdl.handle.net/11336/182331
identifier_str_mv Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Castellano, Eduardo Ernesto; Parajón Costa, Beatriz Susana; Baran, Enrique José; Structural and spectroscopic characterization of isotypic sodium, rubidium and cesium acesulfamates; Verlag der Zeitschrift für Naturforschung; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 70; 7; 7-2015; 491-496
0932-0776
1865-7117
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/document/doi/10.1515/znb-2015-0042/html
info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2015-0042
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Verlag der Zeitschrift für Naturforschung
publisher.none.fl_str_mv Verlag der Zeitschrift für Naturforschung
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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