Structural and IR-Spectroscopic Characterization of Aqua Lithium Acesulfamate, an Outlier of the M(ace), M: Na+, K+, Rb+, Cs+, Isomorphi...

Autores: Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Parajón Costa, Beatriz Susana; Baran, Enrique José
Año de publicación: 2017
Idioma: español castellano
Tipo de recurso: artículo
Estado: versión publicada
Descripción: The crystal structure of aqua lithium 6-methyl-1,2,3,-oxathiazine-4(3H)-one, 2.2-dioxide, for short Li(ace)H₂O, was determined by X-ray diffraction methods. It crystallizes in the triclinic P1¯ space group with a = 6.1750(9) Å, b = 7.3969(9) Å, c = 9.016(1) Å, α = 105.88(1)°, β = 94.59(1)°, γ = 97.80(1)°, and Z = 2 molecules per unit cell. The crystal structure of Li(ace)H₂O sharply departs from the other heavier alkaline-metal acesulfamates, namely the monoclinic isotypic M-ace (M from Na⁺ to Cs⁺) family of salts. Lithium is in a distorted LiO₄ tetrahedral coordination with acesulfamate carbonyl, sulfoxide and water oxygen atoms. The FTIR spectrum of the new compound was also recorded and is briefly discussed. Some comparisons with other simple acesulfamate salts are also made.
Instituto de Física La Plata
Centro de Química Inorgánica
Materia: Ciencias Exactas
Aqua lithium acesulfamate
Synthesis
FTIR spectrum
Crystal structure
Nivel de accesibilidad: acceso abierto
Condiciones de uso: http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
Institución: Universidad Nacional de La Plata
OAI Identificador: oai:sedici.unlp.edu.ar:10915/103362

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network_name_str	SEDICI (UNLP)
spelling	Structural and IR-Spectroscopic Characterization of Aqua Lithium Acesulfamate, an Outlier of the M(ace), M: Na<sup>+</sup>, K<sup>+</sup>, Rb<sup>+</sup>, Cs<sup>+</sup>, Isomorphic SeriesPiro, Oscar EnriqueEcheverría, Gustavo AlbertoParajón Costa, Beatriz SusanaBaran, Enrique JoséCiencias ExactasAqua lithium acesulfamateSynthesisFTIR spectrumCrystal structureThe crystal structure of aqua lithium 6-methyl-1,2,3,-oxathiazine-4(3H)-one, 2.2-dioxide, for short Li(ace)H<sub>2</sub>O, was determined by X-ray diffraction methods. It crystallizes in the triclinic P1¯ space group with a = 6.1750(9) Å, b = 7.3969(9) Å, c = 9.016(1) Å, α = 105.88(1)°, β = 94.59(1)°, γ = 97.80(1)°, and Z = 2 molecules per unit cell. The crystal structure of Li(ace)H<sub>2</sub>O sharply departs from the other heavier alkaline-metal acesulfamates, namely the monoclinic isotypic M-ace (M from Na<sup>+</sup> to Cs<sup>+</sup>) family of salts. Lithium is in a distorted LiO<sub>4</sub> tetrahedral coordination with acesulfamate carbonyl, sulfoxide and water oxygen atoms. The FTIR spectrum of the new compound was also recorded and is briefly discussed. Some comparisons with other simple acesulfamate salts are also made.Instituto de Física La PlataCentro de Química Inorgánica2017-10-25info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf226–232http://sedici.unlp.edu.ar/handle/10915/103362spainfo:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/s10870-017-0701-3info:eu-repo/semantics/altIdentifier/issn/1572-8854info:eu-repo/semantics/altIdentifier/doi/10.1007/s10870-017-0701-3info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-15T11:14:20Zoai:sedici.unlp.edu.ar:10915/103362Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-15 11:14:20.714SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv	Structural and IR-Spectroscopic Characterization of Aqua Lithium Acesulfamate, an Outlier of the M(ace), M: Na<sup>+</sup>, K<sup>+</sup>, Rb<sup>+</sup>, Cs<sup>+</sup>, Isomorphic Series
title	Structural and IR-Spectroscopic Characterization of Aqua Lithium Acesulfamate, an Outlier of the M(ace), M: Na<sup>+</sup>, K<sup>+</sup>, Rb<sup>+</sup>, Cs<sup>+</sup>, Isomorphic Series
spellingShingle	Structural and IR-Spectroscopic Characterization of Aqua Lithium Acesulfamate, an Outlier of the M(ace), M: Na<sup>+</sup>, K<sup>+</sup>, Rb<sup>+</sup>, Cs<sup>+</sup>, Isomorphic Series Piro, Oscar Enrique Ciencias Exactas Aqua lithium acesulfamate Synthesis FTIR spectrum Crystal structure
title_short	Structural and IR-Spectroscopic Characterization of Aqua Lithium Acesulfamate, an Outlier of the M(ace), M: Na<sup>+</sup>, K<sup>+</sup>, Rb<sup>+</sup>, Cs<sup>+</sup>, Isomorphic Series
title_full	Structural and IR-Spectroscopic Characterization of Aqua Lithium Acesulfamate, an Outlier of the M(ace), M: Na<sup>+</sup>, K<sup>+</sup>, Rb<sup>+</sup>, Cs<sup>+</sup>, Isomorphic Series
title_fullStr	Structural and IR-Spectroscopic Characterization of Aqua Lithium Acesulfamate, an Outlier of the M(ace), M: Na<sup>+</sup>, K<sup>+</sup>, Rb<sup>+</sup>, Cs<sup>+</sup>, Isomorphic Series
title_full_unstemmed	Structural and IR-Spectroscopic Characterization of Aqua Lithium Acesulfamate, an Outlier of the M(ace), M: Na<sup>+</sup>, K<sup>+</sup>, Rb<sup>+</sup>, Cs<sup>+</sup>, Isomorphic Series
title_sort	Structural and IR-Spectroscopic Characterization of Aqua Lithium Acesulfamate, an Outlier of the M(ace), M: Na<sup>+</sup>, K<sup>+</sup>, Rb<sup>+</sup>, Cs<sup>+</sup>, Isomorphic Series
dc.creator.none.fl_str_mv	Piro, Oscar Enrique Echeverría, Gustavo Alberto Parajón Costa, Beatriz Susana Baran, Enrique José
author	Piro, Oscar Enrique
author_facet	Piro, Oscar Enrique Echeverría, Gustavo Alberto Parajón Costa, Beatriz Susana Baran, Enrique José
author_role	author
author2	Echeverría, Gustavo Alberto Parajón Costa, Beatriz Susana Baran, Enrique José
author2_role	author author author
dc.subject.none.fl_str_mv	Ciencias Exactas Aqua lithium acesulfamate Synthesis FTIR spectrum Crystal structure
topic	Ciencias Exactas Aqua lithium acesulfamate Synthesis FTIR spectrum Crystal structure
dc.description.none.fl_txt_mv	The crystal structure of aqua lithium 6-methyl-1,2,3,-oxathiazine-4(3H)-one, 2.2-dioxide, for short Li(ace)H<sub>2</sub>O, was determined by X-ray diffraction methods. It crystallizes in the triclinic P1¯ space group with a = 6.1750(9) Å, b = 7.3969(9) Å, c = 9.016(1) Å, α = 105.88(1)°, β = 94.59(1)°, γ = 97.80(1)°, and Z = 2 molecules per unit cell. The crystal structure of Li(ace)H<sub>2</sub>O sharply departs from the other heavier alkaline-metal acesulfamates, namely the monoclinic isotypic M-ace (M from Na<sup>+</sup> to Cs<sup>+</sup>) family of salts. Lithium is in a distorted LiO<sub>4</sub> tetrahedral coordination with acesulfamate carbonyl, sulfoxide and water oxygen atoms. The FTIR spectrum of the new compound was also recorded and is briefly discussed. Some comparisons with other simple acesulfamate salts are also made. Instituto de Física La Plata Centro de Química Inorgánica
description	The crystal structure of aqua lithium 6-methyl-1,2,3,-oxathiazine-4(3H)-one, 2.2-dioxide, for short Li(ace)H<sub>2</sub>O, was determined by X-ray diffraction methods. It crystallizes in the triclinic P1¯ space group with a = 6.1750(9) Å, b = 7.3969(9) Å, c = 9.016(1) Å, α = 105.88(1)°, β = 94.59(1)°, γ = 97.80(1)°, and Z = 2 molecules per unit cell. The crystal structure of Li(ace)H<sub>2</sub>O sharply departs from the other heavier alkaline-metal acesulfamates, namely the monoclinic isotypic M-ace (M from Na<sup>+</sup> to Cs<sup>+</sup>) family of salts. Lithium is in a distorted LiO<sub>4</sub> tetrahedral coordination with acesulfamate carbonyl, sulfoxide and water oxygen atoms. The FTIR spectrum of the new compound was also recorded and is briefly discussed. Some comparisons with other simple acesulfamate salts are also made.
publishDate	2017
dc.date.none.fl_str_mv	2017-10-25
dc.type.none.fl_str_mv	info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo
format	article
status_str	publishedVersion
dc.identifier.none.fl_str_mv	http://sedici.unlp.edu.ar/handle/10915/103362
url	http://sedici.unlp.edu.ar/handle/10915/103362
dc.language.none.fl_str_mv	spa
language	spa
dc.relation.none.fl_str_mv	info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/s10870-017-0701-3 info:eu-repo/semantics/altIdentifier/issn/1572-8854 info:eu-repo/semantics/altIdentifier/doi/10.1007/s10870-017-0701-3
dc.rights.none.fl_str_mv	info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv	openAccess
rights_invalid_str_mv	http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv	application/pdf 226–232
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repository.name.fl_str_mv	SEDICI (UNLP) - Universidad Nacional de La Plata
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Structural and IR-Spectroscopic Characterization of Aqua Lithium Acesulfamate, an Outlier of the M(ace), M: Na<sup>+</sup>, K<sup>+</sup>, Rb<sup>+</sup>, Cs<sup>+</sup>, Isomorphi...

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