Nitrogen diffusion in nitrogen-doped yttria stabilised zirconia

Autores
Kilo, Martin; Taylor, Marcela Andrea; Argirusis, Christos; Borchardt, Günter; Lerch, Martin; Kaïtasov, Odile; Lesage, Bernard
Año de publicación
2004
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Nitrogen self-diffusion was measured in single crystalline nitrogen-doped yttria-stabilised zirconia (YZrON) containing 10 mol% yttrium oxide. Samples containing two different nitrogen contents (5 and 6 mol% N on the anion sublattice) were investigated as a function of temperature (650–1000 K) using implanted 15N as a stable tracer. For a given temperature, the nitrogen diffusivity was nearly independent of the nitrogen content in the nitrogen-doped yttria-stabilised zirconia, which can be only partially understood using defect chemistry. The activation enthalpy of nitrogen diffusion was between 2 and 2.5 eV with a preexponential factor of the order of 100 cm2 s−1, which corresponds to a migration entropy of 5 kB. The surface exchange reaction between nitrogen and the oxonitride surface was investigated at 1073 K using 200 mbar gaseous 15N2 and was found to be slow but considerable. Decreasing the oxygen content in the gas phase can enhance the nitrogen incorporation into the oxonitrides.
Instituto de Física La Plata
Materia
Astronomía
Física
Ciencias Exactas
Nitrogen diffusion
Sims
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/97644
Acceder
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network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Nitrogen diffusion in nitrogen-doped yttria stabilised zirconiaKilo, MartinTaylor, Marcela AndreaArgirusis, ChristosBorchardt, GünterLerch, MartinKaïtasov, OdileLesage, BernardAstronomíaFísicaCiencias ExactasNitrogen diffusionSimsNitrogen self-diffusion was measured in single crystalline nitrogen-doped yttria-stabilised zirconia (YZrON) containing 10 mol% yttrium oxide. Samples containing two different nitrogen contents (5 and 6 mol% N on the anion sublattice) were investigated as a function of temperature (650–1000 K) using implanted <sup>15</sup>N as a stable tracer. For a given temperature, the nitrogen diffusivity was nearly independent of the nitrogen content in the nitrogen-doped yttria-stabilised zirconia, which can be only partially understood using defect chemistry. The activation enthalpy of nitrogen diffusion was between 2 and 2.5 eV with a preexponential factor of the order of 10<sup>0</sup> cm<sup>2</sup> s<sup>−1</sup>, which corresponds to a migration entropy of 5 k<sub>B</sub>. The surface exchange reaction between nitrogen and the oxonitride surface was investigated at 1073 K using 200 mbar gaseous <sup>15</sup>N<sub>2</sub> and was found to be slow but considerable. Decreasing the oxygen content in the gas phase can enhance the nitrogen incorporation into the oxonitrides.Instituto de Física La Plata2004info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf3645-3649http://sedici.unlp.edu.ar/handle/10915/97644enginfo:eu-repo/semantics/altIdentifier/url/https://ri.conicet.gov.ar/11336/74366info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2004/CP/B315123A#!divAbstractinfo:eu-repo/semantics/altIdentifier/issn/1463-9076info:eu-repo/semantics/altIdentifier/doi/10.1039/b315123ainfo:eu-repo/semantics/altIdentifier/hdl/11336/74366info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/2.5/ar/Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Argentina (CC BY-NC-SA 2.5)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:20:21Zoai:sedici.unlp.edu.ar:10915/97644Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:20:22.027SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Nitrogen diffusion in nitrogen-doped yttria stabilised zirconia
title Nitrogen diffusion in nitrogen-doped yttria stabilised zirconia
spellingShingle Nitrogen diffusion in nitrogen-doped yttria stabilised zirconia
Kilo, Martin
Astronomía
Física
Ciencias Exactas
Nitrogen diffusion
Sims
title_short Nitrogen diffusion in nitrogen-doped yttria stabilised zirconia
title_full Nitrogen diffusion in nitrogen-doped yttria stabilised zirconia
title_fullStr Nitrogen diffusion in nitrogen-doped yttria stabilised zirconia
title_full_unstemmed Nitrogen diffusion in nitrogen-doped yttria stabilised zirconia
title_sort Nitrogen diffusion in nitrogen-doped yttria stabilised zirconia
dc.creator.none.fl_str_mv Kilo, Martin
Taylor, Marcela Andrea
Argirusis, Christos
Borchardt, Günter
Lerch, Martin
Kaïtasov, Odile
Lesage, Bernard
author Kilo, Martin
author_facet Kilo, Martin
Taylor, Marcela Andrea
Argirusis, Christos
Borchardt, Günter
Lerch, Martin
Kaïtasov, Odile
Lesage, Bernard
author_role author
author2 Taylor, Marcela Andrea
Argirusis, Christos
Borchardt, Günter
Lerch, Martin
Kaïtasov, Odile
Lesage, Bernard
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Astronomía
Física
Ciencias Exactas
Nitrogen diffusion
Sims
topic Astronomía
Física
Ciencias Exactas
Nitrogen diffusion
Sims
dc.description.none.fl_txt_mv Nitrogen self-diffusion was measured in single crystalline nitrogen-doped yttria-stabilised zirconia (YZrON) containing 10 mol% yttrium oxide. Samples containing two different nitrogen contents (5 and 6 mol% N on the anion sublattice) were investigated as a function of temperature (650–1000 K) using implanted <sup>15</sup>N as a stable tracer. For a given temperature, the nitrogen diffusivity was nearly independent of the nitrogen content in the nitrogen-doped yttria-stabilised zirconia, which can be only partially understood using defect chemistry. The activation enthalpy of nitrogen diffusion was between 2 and 2.5 eV with a preexponential factor of the order of 10<sup>0</sup> cm<sup>2</sup> s<sup>−1</sup>, which corresponds to a migration entropy of 5 k<sub>B</sub>. The surface exchange reaction between nitrogen and the oxonitride surface was investigated at 1073 K using 200 mbar gaseous <sup>15</sup>N<sub>2</sub> and was found to be slow but considerable. Decreasing the oxygen content in the gas phase can enhance the nitrogen incorporation into the oxonitrides.
Instituto de Física La Plata
description Nitrogen self-diffusion was measured in single crystalline nitrogen-doped yttria-stabilised zirconia (YZrON) containing 10 mol% yttrium oxide. Samples containing two different nitrogen contents (5 and 6 mol% N on the anion sublattice) were investigated as a function of temperature (650–1000 K) using implanted <sup>15</sup>N as a stable tracer. For a given temperature, the nitrogen diffusivity was nearly independent of the nitrogen content in the nitrogen-doped yttria-stabilised zirconia, which can be only partially understood using defect chemistry. The activation enthalpy of nitrogen diffusion was between 2 and 2.5 eV with a preexponential factor of the order of 10<sup>0</sup> cm<sup>2</sup> s<sup>−1</sup>, which corresponds to a migration entropy of 5 k<sub>B</sub>. The surface exchange reaction between nitrogen and the oxonitride surface was investigated at 1073 K using 200 mbar gaseous <sup>15</sup>N<sub>2</sub> and was found to be slow but considerable. Decreasing the oxygen content in the gas phase can enhance the nitrogen incorporation into the oxonitrides.
publishDate 2004
dc.date.none.fl_str_mv 2004
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/97644
url http://sedici.unlp.edu.ar/handle/10915/97644
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://ri.conicet.gov.ar/11336/74366
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2004/CP/B315123A#!divAbstract
info:eu-repo/semantics/altIdentifier/issn/1463-9076
info:eu-repo/semantics/altIdentifier/doi/10.1039/b315123a
info:eu-repo/semantics/altIdentifier/hdl/11336/74366
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Argentina (CC BY-NC-SA 2.5)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Argentina (CC BY-NC-SA 2.5)
dc.format.none.fl_str_mv application/pdf
3645-3649
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
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reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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