SIMS study of transition metal transport in single crystalline yttria stabilised zirconia

Autores
Argirusis, Christos; Taylor, Marcela Andrea; Kilo, Martin; Borchardt, Günter; Jomard, François; Lesage, Bernard; Kaïtasov, Odile
Año de publicación
2004
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The diffusion of Co, Fe and Ni in single crystalline yttria stabilized zirconia (YSZ) containing 9.5 mol% Y2O3 was studied in the temperature range between 1373 and 1673 K using secondary ion mass spectroscopy. Two different types of diffusion sources were used: thin oxide layers made by spin coating with a thickness of about 150 nm containing all three transition metals (Fe, Co and Ni) on YSZ single crystals and YSZ single crystals implanted with Ni (3 × 1016 ions cm-2, 100 keV) at a mean depth of 45 nm. The determined diffusivities varied in the order D(Fe) < D(Co) < D(Ni). Activation energies for the diffusion of the elements were determined to.be 2.7 ± 0.4 eV, 3.9 ± 0.3 eV and 3.8 ± 0.3 eV for Fe, Co and Ni (3.6 ± 0.5 eV for implanted Ni), respectively. For the latter ion, the value of the activation energy was practically independent of the type of Ni source. The values for all elements were lower by 1-2 eV than for the host cation (Y and Zr) diffusion.
Fil: Argirusis, Christos. Technische Universität Clausthal; Alemania
Fil: Taylor, Marcela Andrea. Technische Universität Clausthal; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Kilo, Martin. Technische Universität Clausthal; Alemania
Fil: Borchardt, Günter. Technische Universität Clausthal; Alemania
Fil: Jomard, François. Centre National de la Recherche Scientifique; Francia
Fil: Lesage, Bernard. Université Paris Sud; Francia
Fil: Kaïtasov, Odile. Université Paris Sud; Francia
Materia
Cation Diffusion
Sims
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/74022
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/74022
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling SIMS study of transition metal transport in single crystalline yttria stabilised zirconiaArgirusis, ChristosTaylor, Marcela AndreaKilo, MartinBorchardt, GünterJomard, FrançoisLesage, BernardKaïtasov, OdileCation DiffusionSimshttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The diffusion of Co, Fe and Ni in single crystalline yttria stabilized zirconia (YSZ) containing 9.5 mol% Y2O3 was studied in the temperature range between 1373 and 1673 K using secondary ion mass spectroscopy. Two different types of diffusion sources were used: thin oxide layers made by spin coating with a thickness of about 150 nm containing all three transition metals (Fe, Co and Ni) on YSZ single crystals and YSZ single crystals implanted with Ni (3 × 1016 ions cm-2, 100 keV) at a mean depth of 45 nm. The determined diffusivities varied in the order D(Fe) < D(Co) < D(Ni). Activation energies for the diffusion of the elements were determined to.be 2.7 ± 0.4 eV, 3.9 ± 0.3 eV and 3.8 ± 0.3 eV for Fe, Co and Ni (3.6 ± 0.5 eV for implanted Ni), respectively. For the latter ion, the value of the activation energy was practically independent of the type of Ni source. The values for all elements were lower by 1-2 eV than for the host cation (Y and Zr) diffusion.Fil: Argirusis, Christos. Technische Universität Clausthal; AlemaniaFil: Taylor, Marcela Andrea. Technische Universität Clausthal; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Kilo, Martin. Technische Universität Clausthal; AlemaniaFil: Borchardt, Günter. Technische Universität Clausthal; AlemaniaFil: Jomard, François. Centre National de la Recherche Scientifique; FranciaFil: Lesage, Bernard. Université Paris Sud; FranciaFil: Kaïtasov, Odile. Université Paris Sud; FranciaRoyal Society of Chemistry2004-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/74022Argirusis, Christos; Taylor, Marcela Andrea; Kilo, Martin; Borchardt, Günter; Jomard, François; et al.; SIMS study of transition metal transport in single crystalline yttria stabilised zirconia; Royal Society of Chemistry; Physical Chemistry Chemical Physics; 6; 13; 7-2004; 3650-36531463-9076CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/b315294dinfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2004/CP/B315294Dinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:14:26Zoai:ri.conicet.gov.ar:11336/74022instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:14:27.167CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv SIMS study of transition metal transport in single crystalline yttria stabilised zirconia
title SIMS study of transition metal transport in single crystalline yttria stabilised zirconia
spellingShingle SIMS study of transition metal transport in single crystalline yttria stabilised zirconia
Argirusis, Christos
Cation Diffusion
Sims
title_short SIMS study of transition metal transport in single crystalline yttria stabilised zirconia
title_full SIMS study of transition metal transport in single crystalline yttria stabilised zirconia
title_fullStr SIMS study of transition metal transport in single crystalline yttria stabilised zirconia
title_full_unstemmed SIMS study of transition metal transport in single crystalline yttria stabilised zirconia
title_sort SIMS study of transition metal transport in single crystalline yttria stabilised zirconia
dc.creator.none.fl_str_mv Argirusis, Christos
Taylor, Marcela Andrea
Kilo, Martin
Borchardt, Günter
Jomard, François
Lesage, Bernard
Kaïtasov, Odile
author Argirusis, Christos
author_facet Argirusis, Christos
Taylor, Marcela Andrea
Kilo, Martin
Borchardt, Günter
Jomard, François
Lesage, Bernard
Kaïtasov, Odile
author_role author
author2 Taylor, Marcela Andrea
Kilo, Martin
Borchardt, Günter
Jomard, François
Lesage, Bernard
Kaïtasov, Odile
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Cation Diffusion
Sims
topic Cation Diffusion
Sims
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The diffusion of Co, Fe and Ni in single crystalline yttria stabilized zirconia (YSZ) containing 9.5 mol% Y2O3 was studied in the temperature range between 1373 and 1673 K using secondary ion mass spectroscopy. Two different types of diffusion sources were used: thin oxide layers made by spin coating with a thickness of about 150 nm containing all three transition metals (Fe, Co and Ni) on YSZ single crystals and YSZ single crystals implanted with Ni (3 × 1016 ions cm-2, 100 keV) at a mean depth of 45 nm. The determined diffusivities varied in the order D(Fe) < D(Co) < D(Ni). Activation energies for the diffusion of the elements were determined to.be 2.7 ± 0.4 eV, 3.9 ± 0.3 eV and 3.8 ± 0.3 eV for Fe, Co and Ni (3.6 ± 0.5 eV for implanted Ni), respectively. For the latter ion, the value of the activation energy was practically independent of the type of Ni source. The values for all elements were lower by 1-2 eV than for the host cation (Y and Zr) diffusion.
Fil: Argirusis, Christos. Technische Universität Clausthal; Alemania
Fil: Taylor, Marcela Andrea. Technische Universität Clausthal; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Kilo, Martin. Technische Universität Clausthal; Alemania
Fil: Borchardt, Günter. Technische Universität Clausthal; Alemania
Fil: Jomard, François. Centre National de la Recherche Scientifique; Francia
Fil: Lesage, Bernard. Université Paris Sud; Francia
Fil: Kaïtasov, Odile. Université Paris Sud; Francia
description The diffusion of Co, Fe and Ni in single crystalline yttria stabilized zirconia (YSZ) containing 9.5 mol% Y2O3 was studied in the temperature range between 1373 and 1673 K using secondary ion mass spectroscopy. Two different types of diffusion sources were used: thin oxide layers made by spin coating with a thickness of about 150 nm containing all three transition metals (Fe, Co and Ni) on YSZ single crystals and YSZ single crystals implanted with Ni (3 × 1016 ions cm-2, 100 keV) at a mean depth of 45 nm. The determined diffusivities varied in the order D(Fe) < D(Co) < D(Ni). Activation energies for the diffusion of the elements were determined to.be 2.7 ± 0.4 eV, 3.9 ± 0.3 eV and 3.8 ± 0.3 eV for Fe, Co and Ni (3.6 ± 0.5 eV for implanted Ni), respectively. For the latter ion, the value of the activation energy was practically independent of the type of Ni source. The values for all elements were lower by 1-2 eV than for the host cation (Y and Zr) diffusion.
publishDate 2004
dc.date.none.fl_str_mv 2004-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/74022
Argirusis, Christos; Taylor, Marcela Andrea; Kilo, Martin; Borchardt, Günter; Jomard, François; et al.; SIMS study of transition metal transport in single crystalline yttria stabilised zirconia; Royal Society of Chemistry; Physical Chemistry Chemical Physics; 6; 13; 7-2004; 3650-3653
1463-9076
CONICET Digital
CONICET
url http://hdl.handle.net/11336/74022
identifier_str_mv Argirusis, Christos; Taylor, Marcela Andrea; Kilo, Martin; Borchardt, Günter; Jomard, François; et al.; SIMS study of transition metal transport in single crystalline yttria stabilised zirconia; Royal Society of Chemistry; Physical Chemistry Chemical Physics; 6; 13; 7-2004; 3650-3653
1463-9076
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/b315294d
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2004/CP/B315294D
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083292030304256
score 13.22299

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