Cation self-diffusion of 44 Ca, 88 Y, and 96 Zr in single-crystalline calcia- and yttria-doped zirconia

Autores
Kilo, M.; Taylor, Marcela Andrea; Argirusis, Ch.; Borchardt, G.; Lesage, B.; Weber, S.; Scherrer, S.; Scherrer, H.; Schroeder, M.; Martin, M.
Año de publicación
2003
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Self-diffusion of calcium, yttrium, and zirconium in single-crystalline yttria-stabilized zirconia (YSZ) and calcia-stabilized zirconia (CSZ) was investigated. The stable isotopes 44 Ca and 96 Zr were used as tracers for zirconium and calcium diffusion. It was observed that in YSZ, zirconium and yttrium bulk diffusivity were maximum for a stabilizer content of 10-11 mol%, and in CSZ both calcium and zirconium tracer diffusion are independent of the calcium content. Results show that the cation diffusion occurs either via free vacancies or via bound vacancies.
Fil: Kilo, M.. Technische Universität Clausthal; Alemania
Fil: Taylor, Marcela Andrea. Technische Universität Clausthal; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Argirusis, Ch.. Technische Universität Clausthal; Alemania
Fil: Borchardt, G.. Technische Universität Clausthal; Alemania
Fil: Lesage, B.. Universite Paris-sud Xi; Francia
Fil: Weber, S.. École Nationale Supérieure Des Mines de Nancy; Francia
Fil: Scherrer, S.. École Nationale Supérieure Des Mines de Nancy; Francia
Fil: Scherrer, H.. École Nationale Supérieure Des Mines de Nancy; Francia
Fil: Schroeder, M.. Rwth Aachen University; Alemania
Fil: Martin, M.. Rwth Aachen University; Alemania
Materia
Cation diffusion
Zirconia
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/74361
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Cation self-diffusion of 44 Ca, 88 Y, and 96 Zr in single-crystalline calcia- and yttria-doped zirconiaKilo, M.Taylor, Marcela AndreaArgirusis, Ch.Borchardt, G.Lesage, B.Weber, S.Scherrer, S.Scherrer, H.Schroeder, M.Martin, M.Cation diffusionZirconiahttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Self-diffusion of calcium, yttrium, and zirconium in single-crystalline yttria-stabilized zirconia (YSZ) and calcia-stabilized zirconia (CSZ) was investigated. The stable isotopes 44 Ca and 96 Zr were used as tracers for zirconium and calcium diffusion. It was observed that in YSZ, zirconium and yttrium bulk diffusivity were maximum for a stabilizer content of 10-11 mol%, and in CSZ both calcium and zirconium tracer diffusion are independent of the calcium content. Results show that the cation diffusion occurs either via free vacancies or via bound vacancies.Fil: Kilo, M.. Technische Universität Clausthal; AlemaniaFil: Taylor, Marcela Andrea. Technische Universität Clausthal; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Argirusis, Ch.. Technische Universität Clausthal; AlemaniaFil: Borchardt, G.. Technische Universität Clausthal; AlemaniaFil: Lesage, B.. Universite Paris-sud Xi; FranciaFil: Weber, S.. École Nationale Supérieure Des Mines de Nancy; FranciaFil: Scherrer, S.. École Nationale Supérieure Des Mines de Nancy; FranciaFil: Scherrer, H.. École Nationale Supérieure Des Mines de Nancy; FranciaFil: Schroeder, M.. Rwth Aachen University; AlemaniaFil: Martin, M.. Rwth Aachen University; AlemaniaAmerican Institute of Physics2003-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/74361Kilo, M.; Taylor, Marcela Andrea; Argirusis, Ch.; Borchardt, G.; Lesage, B.; et al.; Cation self-diffusion of 44 Ca, 88 Y, and 96 Zr in single-crystalline calcia- and yttria-doped zirconia; American Institute of Physics; Journal of Applied Physics; 94; 12; 12-2003; 7547-75520021-8979CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1063/1.1628379info:eu-repo/semantics/altIdentifier/url/https://aip.scitation.org/doi/abs/10.1063/1.1628379info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:15:49Zoai:ri.conicet.gov.ar:11336/74361instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:15:49.883CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Cation self-diffusion of 44 Ca, 88 Y, and 96 Zr in single-crystalline calcia- and yttria-doped zirconia
title Cation self-diffusion of 44 Ca, 88 Y, and 96 Zr in single-crystalline calcia- and yttria-doped zirconia
spellingShingle Cation self-diffusion of 44 Ca, 88 Y, and 96 Zr in single-crystalline calcia- and yttria-doped zirconia
Kilo, M.
Cation diffusion
Zirconia
title_short Cation self-diffusion of 44 Ca, 88 Y, and 96 Zr in single-crystalline calcia- and yttria-doped zirconia
title_full Cation self-diffusion of 44 Ca, 88 Y, and 96 Zr in single-crystalline calcia- and yttria-doped zirconia
title_fullStr Cation self-diffusion of 44 Ca, 88 Y, and 96 Zr in single-crystalline calcia- and yttria-doped zirconia
title_full_unstemmed Cation self-diffusion of 44 Ca, 88 Y, and 96 Zr in single-crystalline calcia- and yttria-doped zirconia
title_sort Cation self-diffusion of 44 Ca, 88 Y, and 96 Zr in single-crystalline calcia- and yttria-doped zirconia
dc.creator.none.fl_str_mv Kilo, M.
Taylor, Marcela Andrea
Argirusis, Ch.
Borchardt, G.
Lesage, B.
Weber, S.
Scherrer, S.
Scherrer, H.
Schroeder, M.
Martin, M.
author Kilo, M.
author_facet Kilo, M.
Taylor, Marcela Andrea
Argirusis, Ch.
Borchardt, G.
Lesage, B.
Weber, S.
Scherrer, S.
Scherrer, H.
Schroeder, M.
Martin, M.
author_role author
author2 Taylor, Marcela Andrea
Argirusis, Ch.
Borchardt, G.
Lesage, B.
Weber, S.
Scherrer, S.
Scherrer, H.
Schroeder, M.
Martin, M.
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Cation diffusion
Zirconia
topic Cation diffusion
Zirconia
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Self-diffusion of calcium, yttrium, and zirconium in single-crystalline yttria-stabilized zirconia (YSZ) and calcia-stabilized zirconia (CSZ) was investigated. The stable isotopes 44 Ca and 96 Zr were used as tracers for zirconium and calcium diffusion. It was observed that in YSZ, zirconium and yttrium bulk diffusivity were maximum for a stabilizer content of 10-11 mol%, and in CSZ both calcium and zirconium tracer diffusion are independent of the calcium content. Results show that the cation diffusion occurs either via free vacancies or via bound vacancies.
Fil: Kilo, M.. Technische Universität Clausthal; Alemania
Fil: Taylor, Marcela Andrea. Technische Universität Clausthal; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Argirusis, Ch.. Technische Universität Clausthal; Alemania
Fil: Borchardt, G.. Technische Universität Clausthal; Alemania
Fil: Lesage, B.. Universite Paris-sud Xi; Francia
Fil: Weber, S.. École Nationale Supérieure Des Mines de Nancy; Francia
Fil: Scherrer, S.. École Nationale Supérieure Des Mines de Nancy; Francia
Fil: Scherrer, H.. École Nationale Supérieure Des Mines de Nancy; Francia
Fil: Schroeder, M.. Rwth Aachen University; Alemania
Fil: Martin, M.. Rwth Aachen University; Alemania
description Self-diffusion of calcium, yttrium, and zirconium in single-crystalline yttria-stabilized zirconia (YSZ) and calcia-stabilized zirconia (CSZ) was investigated. The stable isotopes 44 Ca and 96 Zr were used as tracers for zirconium and calcium diffusion. It was observed that in YSZ, zirconium and yttrium bulk diffusivity were maximum for a stabilizer content of 10-11 mol%, and in CSZ both calcium and zirconium tracer diffusion are independent of the calcium content. Results show that the cation diffusion occurs either via free vacancies or via bound vacancies.
publishDate 2003
dc.date.none.fl_str_mv 2003-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/74361
Kilo, M.; Taylor, Marcela Andrea; Argirusis, Ch.; Borchardt, G.; Lesage, B.; et al.; Cation self-diffusion of 44 Ca, 88 Y, and 96 Zr in single-crystalline calcia- and yttria-doped zirconia; American Institute of Physics; Journal of Applied Physics; 94; 12; 12-2003; 7547-7552
0021-8979
CONICET Digital
CONICET
url http://hdl.handle.net/11336/74361
identifier_str_mv Kilo, M.; Taylor, Marcela Andrea; Argirusis, Ch.; Borchardt, G.; Lesage, B.; et al.; Cation self-diffusion of 44 Ca, 88 Y, and 96 Zr in single-crystalline calcia- and yttria-doped zirconia; American Institute of Physics; Journal of Applied Physics; 94; 12; 12-2003; 7547-7552
0021-8979
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1063/1.1628379
info:eu-repo/semantics/altIdentifier/url/https://aip.scitation.org/doi/abs/10.1063/1.1628379
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Institute of Physics
publisher.none.fl_str_mv American Institute of Physics
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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