Effect on Temporary Protection and Adhesion Promoter of Silane Nanofilms Applied on Electro-galvanized Steel

Autores
Seré, Pablo Ricardo; Banera, Mauro Jonathan; Egli, Walter Alfredo; Elsner, Cecilia Inés; Di Sarli, Alejandro Ramón; Deyá, Marta Cecilia
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this paper, the effectiveness of γ-mercaptopropyltrimethoxysilane (MTMO) films as temporary corrosion protection and adhesion promoter on electro-galvanized steel was studied. The films were synthesized from hydrolyzed MTMO with ethanol or methanol, applied by immersion on electro-galvanized steel and cured under different conditions. The porosity of the coating was evaluated by cyclic voltammetry, the corrosion behavior by polarization curves and the protection degree by exposure in the humidity and prohesion chambers. The films were characterized by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). From the obtained experimental results, it was concluded that this protection is markedly affected by the coating curing conditions and the alcohol used in the hydrolysis. MTMO is a good temporary protector against electro-galvanized steel corrosion in high humidity environment but it is less effective in environments containing aggressive ions such as Cl− and SO4−2. In a second stage, pretreated samples were coated with an alkyd anticorrosive paint and exposed to the salt spray chamber. Dry adhesion tests as well as SEM and EDS studies were also done in order to know the nature of the disbonding fails (adhesion or cohesion).
Centro de Investigación y Desarrollo en Tecnología de Pinturas
Materia
Química
Electro-galvanized steel
Temporary protection
Adhesion
Sol-gel pretreatment
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-nd/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/81954
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/81954
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Effect on Temporary Protection and Adhesion Promoter of Silane Nanofilms Applied on Electro-galvanized SteelSeré, Pablo RicardoBanera, Mauro JonathanEgli, Walter AlfredoElsner, Cecilia InésDi Sarli, Alejandro RamónDeyá, Marta CeciliaQuímicaElectro-galvanized steelTemporary protectionAdhesionSol-gel pretreatmentIn this paper, the effectiveness of γ-mercaptopropyltrimethoxysilane (MTMO) films as temporary corrosion protection and adhesion promoter on electro-galvanized steel was studied. The films were synthesized from hydrolyzed MTMO with ethanol or methanol, applied by immersion on electro-galvanized steel and cured under different conditions. The porosity of the coating was evaluated by cyclic voltammetry, the corrosion behavior by polarization curves and the protection degree by exposure in the humidity and prohesion chambers. The films were characterized by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). From the obtained experimental results, it was concluded that this protection is markedly affected by the coating curing conditions and the alcohol used in the hydrolysis. MTMO is a good temporary protector against electro-galvanized steel corrosion in high humidity environment but it is less effective in environments containing aggressive ions such as Cl− and SO4−2. In a second stage, pretreated samples were coated with an alkyd anticorrosive paint and exposed to the salt spray chamber. Dry adhesion tests as well as SEM and EDS studies were also done in order to know the nature of the disbonding fails (adhesion or cohesion).Centro de Investigación y Desarrollo en Tecnología de Pinturas2016info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf88-95http://sedici.unlp.edu.ar/handle/10915/81954enginfo:eu-repo/semantics/altIdentifier/issn/0143-7496info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijadhadh.2015.11.008info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:15:17Zoai:sedici.unlp.edu.ar:10915/81954Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:15:17.52SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Effect on Temporary Protection and Adhesion Promoter of Silane Nanofilms Applied on Electro-galvanized Steel
title Effect on Temporary Protection and Adhesion Promoter of Silane Nanofilms Applied on Electro-galvanized Steel
spellingShingle Effect on Temporary Protection and Adhesion Promoter of Silane Nanofilms Applied on Electro-galvanized Steel
Seré, Pablo Ricardo
Química
Electro-galvanized steel
Temporary protection
Adhesion
Sol-gel pretreatment
title_short Effect on Temporary Protection and Adhesion Promoter of Silane Nanofilms Applied on Electro-galvanized Steel
title_full Effect on Temporary Protection and Adhesion Promoter of Silane Nanofilms Applied on Electro-galvanized Steel
title_fullStr Effect on Temporary Protection and Adhesion Promoter of Silane Nanofilms Applied on Electro-galvanized Steel
title_full_unstemmed Effect on Temporary Protection and Adhesion Promoter of Silane Nanofilms Applied on Electro-galvanized Steel
title_sort Effect on Temporary Protection and Adhesion Promoter of Silane Nanofilms Applied on Electro-galvanized Steel
dc.creator.none.fl_str_mv Seré, Pablo Ricardo
Banera, Mauro Jonathan
Egli, Walter Alfredo
Elsner, Cecilia Inés
Di Sarli, Alejandro Ramón
Deyá, Marta Cecilia
author Seré, Pablo Ricardo
author_facet Seré, Pablo Ricardo
Banera, Mauro Jonathan
Egli, Walter Alfredo
Elsner, Cecilia Inés
Di Sarli, Alejandro Ramón
Deyá, Marta Cecilia
author_role author
author2 Banera, Mauro Jonathan
Egli, Walter Alfredo
Elsner, Cecilia Inés
Di Sarli, Alejandro Ramón
Deyá, Marta Cecilia
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Química
Electro-galvanized steel
Temporary protection
Adhesion
Sol-gel pretreatment
topic Química
Electro-galvanized steel
Temporary protection
Adhesion
Sol-gel pretreatment
dc.description.none.fl_txt_mv In this paper, the effectiveness of γ-mercaptopropyltrimethoxysilane (MTMO) films as temporary corrosion protection and adhesion promoter on electro-galvanized steel was studied. The films were synthesized from hydrolyzed MTMO with ethanol or methanol, applied by immersion on electro-galvanized steel and cured under different conditions. The porosity of the coating was evaluated by cyclic voltammetry, the corrosion behavior by polarization curves and the protection degree by exposure in the humidity and prohesion chambers. The films were characterized by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). From the obtained experimental results, it was concluded that this protection is markedly affected by the coating curing conditions and the alcohol used in the hydrolysis. MTMO is a good temporary protector against electro-galvanized steel corrosion in high humidity environment but it is less effective in environments containing aggressive ions such as Cl− and SO4−2. In a second stage, pretreated samples were coated with an alkyd anticorrosive paint and exposed to the salt spray chamber. Dry adhesion tests as well as SEM and EDS studies were also done in order to know the nature of the disbonding fails (adhesion or cohesion).
Centro de Investigación y Desarrollo en Tecnología de Pinturas
description In this paper, the effectiveness of γ-mercaptopropyltrimethoxysilane (MTMO) films as temporary corrosion protection and adhesion promoter on electro-galvanized steel was studied. The films were synthesized from hydrolyzed MTMO with ethanol or methanol, applied by immersion on electro-galvanized steel and cured under different conditions. The porosity of the coating was evaluated by cyclic voltammetry, the corrosion behavior by polarization curves and the protection degree by exposure in the humidity and prohesion chambers. The films were characterized by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). From the obtained experimental results, it was concluded that this protection is markedly affected by the coating curing conditions and the alcohol used in the hydrolysis. MTMO is a good temporary protector against electro-galvanized steel corrosion in high humidity environment but it is less effective in environments containing aggressive ions such as Cl− and SO4−2. In a second stage, pretreated samples were coated with an alkyd anticorrosive paint and exposed to the salt spray chamber. Dry adhesion tests as well as SEM and EDS studies were also done in order to know the nature of the disbonding fails (adhesion or cohesion).
publishDate 2016
dc.date.none.fl_str_mv 2016
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/81954
url http://sedici.unlp.edu.ar/handle/10915/81954
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0143-7496
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijadhadh.2015.11.008
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
dc.format.none.fl_str_mv application/pdf
88-95
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.070432

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