Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications
- Autores
- Orsetti, Nicolás Gabriel; Pérez-Coll, Domingo; Lorenzo, Gabriel; Moreno, Rodrigo; Suárez, Gustavo
- Año de publicación
- 2025
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Ti-doped lithium zirconate (LZTO) sheets were successfully made by aqueous tape casting, by starting from an innovative colloidal synthesis route and optimizing the colloidal processing parameters. Zeta potential and particles size measurements, together with rheological characterization, were performed to adjust the slip composition. Then, the suspension with 1.0 wt% of ammonium polyacrylate dispersant (APA) and solid loading of 31 vol.% resulted in flat and flexible sheets, thinner than 450 μm, by adding 20 wt% of acrylic binder emulsion. After annealing at 1150 ◦C/15 h, LZTO sheets densified up to 85.5 %, presented a microstructure with grains of 6.4 μm in diameter, and exhibited electrical conductivity values in the order of 10⁻⁷, 10⁻⁶ and 10⁻⁵ S⋅cm⁻¹ at 350, 450 and 600 ◦C, respectively. Besides, XRD phase analysis revealed monoclinic Li₂ZrO₃ and minor ZrO₂ impurities originated from Li₂O volatilization during sintering, but no sign of TiO₂ segregation, indicating the formation of Li₂Zr₁-ₓTiₓO₃ solid solution.
Centro de Tecnología de Recursos Minerales y Cerámica
Centro de Investigación y Desarrollo en Criotecnología de Alimentos - Materia
-
Química
Lithium zirconate
Colloidal processing
Rheology
Aqueous tape casting
Electrical Conductivity - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-nd/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/181855
Ver los metadatos del registro completo
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Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applicationsOrsetti, Nicolás GabrielPérez-Coll, DomingoLorenzo, GabrielMoreno, RodrigoSuárez, GustavoQuímicaLithium zirconateColloidal processingRheologyAqueous tape castingElectrical ConductivityTi-doped lithium zirconate (LZTO) sheets were successfully made by aqueous tape casting, by starting from an innovative colloidal synthesis route and optimizing the colloidal processing parameters. Zeta potential and particles size measurements, together with rheological characterization, were performed to adjust the slip composition. Then, the suspension with 1.0 wt% of ammonium polyacrylate dispersant (APA) and solid loading of 31 vol.% resulted in flat and flexible sheets, thinner than 450 μm, by adding 20 wt% of acrylic binder emulsion. After annealing at 1150 ◦C/15 h, LZTO sheets densified up to 85.5 %, presented a microstructure with grains of 6.4 μm in diameter, and exhibited electrical conductivity values in the order of 10⁻⁷, 10⁻⁶ and 10⁻⁵ S⋅cm⁻¹ at 350, 450 and 600 ◦C, respectively. Besides, XRD phase analysis revealed monoclinic Li₂ZrO₃ and minor ZrO₂ impurities originated from Li₂O volatilization during sintering, but no sign of TiO₂ segregation, indicating the formation of Li₂Zr₁-ₓTiₓO₃ solid solution.Centro de Tecnología de Recursos Minerales y CerámicaCentro de Investigación y Desarrollo en Criotecnología de Alimentos2025-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://sedici.unlp.edu.ar/handle/10915/181855enginfo:eu-repo/semantics/altIdentifier/issn/2666-5395info:eu-repo/semantics/altIdentifier/doi/10.1016/j.oceram.2025.100737info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:49:38Zoai:sedici.unlp.edu.ar:10915/181855Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:49:38.993SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications |
title |
Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications |
spellingShingle |
Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications Orsetti, Nicolás Gabriel Química Lithium zirconate Colloidal processing Rheology Aqueous tape casting Electrical Conductivity |
title_short |
Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications |
title_full |
Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications |
title_fullStr |
Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications |
title_full_unstemmed |
Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications |
title_sort |
Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications |
dc.creator.none.fl_str_mv |
Orsetti, Nicolás Gabriel Pérez-Coll, Domingo Lorenzo, Gabriel Moreno, Rodrigo Suárez, Gustavo |
author |
Orsetti, Nicolás Gabriel |
author_facet |
Orsetti, Nicolás Gabriel Pérez-Coll, Domingo Lorenzo, Gabriel Moreno, Rodrigo Suárez, Gustavo |
author_role |
author |
author2 |
Pérez-Coll, Domingo Lorenzo, Gabriel Moreno, Rodrigo Suárez, Gustavo |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Química Lithium zirconate Colloidal processing Rheology Aqueous tape casting Electrical Conductivity |
topic |
Química Lithium zirconate Colloidal processing Rheology Aqueous tape casting Electrical Conductivity |
dc.description.none.fl_txt_mv |
Ti-doped lithium zirconate (LZTO) sheets were successfully made by aqueous tape casting, by starting from an innovative colloidal synthesis route and optimizing the colloidal processing parameters. Zeta potential and particles size measurements, together with rheological characterization, were performed to adjust the slip composition. Then, the suspension with 1.0 wt% of ammonium polyacrylate dispersant (APA) and solid loading of 31 vol.% resulted in flat and flexible sheets, thinner than 450 μm, by adding 20 wt% of acrylic binder emulsion. After annealing at 1150 ◦C/15 h, LZTO sheets densified up to 85.5 %, presented a microstructure with grains of 6.4 μm in diameter, and exhibited electrical conductivity values in the order of 10⁻⁷, 10⁻⁶ and 10⁻⁵ S⋅cm⁻¹ at 350, 450 and 600 ◦C, respectively. Besides, XRD phase analysis revealed monoclinic Li₂ZrO₃ and minor ZrO₂ impurities originated from Li₂O volatilization during sintering, but no sign of TiO₂ segregation, indicating the formation of Li₂Zr₁-ₓTiₓO₃ solid solution. Centro de Tecnología de Recursos Minerales y Cerámica Centro de Investigación y Desarrollo en Criotecnología de Alimentos |
description |
Ti-doped lithium zirconate (LZTO) sheets were successfully made by aqueous tape casting, by starting from an innovative colloidal synthesis route and optimizing the colloidal processing parameters. Zeta potential and particles size measurements, together with rheological characterization, were performed to adjust the slip composition. Then, the suspension with 1.0 wt% of ammonium polyacrylate dispersant (APA) and solid loading of 31 vol.% resulted in flat and flexible sheets, thinner than 450 μm, by adding 20 wt% of acrylic binder emulsion. After annealing at 1150 ◦C/15 h, LZTO sheets densified up to 85.5 %, presented a microstructure with grains of 6.4 μm in diameter, and exhibited electrical conductivity values in the order of 10⁻⁷, 10⁻⁶ and 10⁻⁵ S⋅cm⁻¹ at 350, 450 and 600 ◦C, respectively. Besides, XRD phase analysis revealed monoclinic Li₂ZrO₃ and minor ZrO₂ impurities originated from Li₂O volatilization during sintering, but no sign of TiO₂ segregation, indicating the formation of Li₂Zr₁-ₓTiₓO₃ solid solution. |
publishDate |
2025 |
dc.date.none.fl_str_mv |
2025-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/181855 |
url |
http://sedici.unlp.edu.ar/handle/10915/181855 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/2666-5395 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.oceram.2025.100737 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-nd/4.0/ Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) |
eu_rights_str_mv |
openAccess |
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http://creativecommons.org/licenses/by-nc-nd/4.0/ Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) |
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