Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications

Autores
Orsetti, Nicolás Gabriel; Pérez-Coll, Domingo; Lorenzo, Gabriel; Moreno, Rodrigo; Suárez, Gustavo
Año de publicación
2025
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Ti-doped lithium zirconate (LZTO) sheets were successfully made by aqueous tape casting, by starting from an innovative colloidal synthesis route and optimizing the colloidal processing parameters. Zeta potential and particles size measurements, together with rheological characterization, were performed to adjust the slip composition. Then, the suspension with 1.0 wt% of ammonium polyacrylate dispersant (APA) and solid loading of 31 vol.% resulted in flat and flexible sheets, thinner than 450 μm, by adding 20 wt% of acrylic binder emulsion. After annealing at 1150 ◦C/15 h, LZTO sheets densified up to 85.5 %, presented a microstructure with grains of 6.4 μm in diameter, and exhibited electrical conductivity values in the order of 10⁻⁷, 10⁻⁶ and 10⁻⁵ S⋅cm⁻¹ at 350, 450 and 600 ◦C, respectively. Besides, XRD phase analysis revealed monoclinic Li₂ZrO₃ and minor ZrO₂ impurities originated from Li₂O volatilization during sintering, but no sign of TiO₂ segregation, indicating the formation of Li₂Zr₁-ₓTiₓO₃ solid solution.
Centro de Tecnología de Recursos Minerales y Cerámica
Centro de Investigación y Desarrollo en Criotecnología de Alimentos
Materia
Química
Lithium zirconate
Colloidal processing
Rheology
Aqueous tape casting
Electrical Conductivity
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-nd/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/181855
Acceder
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network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applicationsOrsetti, Nicolás GabrielPérez-Coll, DomingoLorenzo, GabrielMoreno, RodrigoSuárez, GustavoQuímicaLithium zirconateColloidal processingRheologyAqueous tape castingElectrical ConductivityTi-doped lithium zirconate (LZTO) sheets were successfully made by aqueous tape casting, by starting from an innovative colloidal synthesis route and optimizing the colloidal processing parameters. Zeta potential and particles size measurements, together with rheological characterization, were performed to adjust the slip composition. Then, the suspension with 1.0 wt% of ammonium polyacrylate dispersant (APA) and solid loading of 31 vol.% resulted in flat and flexible sheets, thinner than 450 μm, by adding 20 wt% of acrylic binder emulsion. After annealing at 1150 ◦C/15 h, LZTO sheets densified up to 85.5 %, presented a microstructure with grains of 6.4 μm in diameter, and exhibited electrical conductivity values in the order of 10⁻⁷, 10⁻⁶ and 10⁻⁵ S⋅cm⁻¹ at 350, 450 and 600 ◦C, respectively. Besides, XRD phase analysis revealed monoclinic Li₂ZrO₃ and minor ZrO₂ impurities originated from Li₂O volatilization during sintering, but no sign of TiO₂ segregation, indicating the formation of Li₂Zr₁-ₓTiₓO₃ solid solution.Centro de Tecnología de Recursos Minerales y CerámicaCentro de Investigación y Desarrollo en Criotecnología de Alimentos2025-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://sedici.unlp.edu.ar/handle/10915/181855enginfo:eu-repo/semantics/altIdentifier/issn/2666-5395info:eu-repo/semantics/altIdentifier/doi/10.1016/j.oceram.2025.100737info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-15T11:41:25Zoai:sedici.unlp.edu.ar:10915/181855Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-15 11:41:26.136SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications
title Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications
spellingShingle Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications
Orsetti, Nicolás Gabriel
Química
Lithium zirconate
Colloidal processing
Rheology
Aqueous tape casting
Electrical Conductivity
title_short Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications
title_full Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications
title_fullStr Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications
title_full_unstemmed Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications
title_sort Aqueous tape casting of titanium-doped lithium metazirconate (Ti-Li₂ZrO₃) sheets for solid-state electrolyte applications
dc.creator.none.fl_str_mv Orsetti, Nicolás Gabriel
Pérez-Coll, Domingo
Lorenzo, Gabriel
Moreno, Rodrigo
Suárez, Gustavo
author Orsetti, Nicolás Gabriel
author_facet Orsetti, Nicolás Gabriel
Pérez-Coll, Domingo
Lorenzo, Gabriel
Moreno, Rodrigo
Suárez, Gustavo
author_role author
author2 Pérez-Coll, Domingo
Lorenzo, Gabriel
Moreno, Rodrigo
Suárez, Gustavo
author2_role author
author
author
author
dc.subject.none.fl_str_mv Química
Lithium zirconate
Colloidal processing
Rheology
Aqueous tape casting
Electrical Conductivity
topic Química
Lithium zirconate
Colloidal processing
Rheology
Aqueous tape casting
Electrical Conductivity
dc.description.none.fl_txt_mv Ti-doped lithium zirconate (LZTO) sheets were successfully made by aqueous tape casting, by starting from an innovative colloidal synthesis route and optimizing the colloidal processing parameters. Zeta potential and particles size measurements, together with rheological characterization, were performed to adjust the slip composition. Then, the suspension with 1.0 wt% of ammonium polyacrylate dispersant (APA) and solid loading of 31 vol.% resulted in flat and flexible sheets, thinner than 450 μm, by adding 20 wt% of acrylic binder emulsion. After annealing at 1150 ◦C/15 h, LZTO sheets densified up to 85.5 %, presented a microstructure with grains of 6.4 μm in diameter, and exhibited electrical conductivity values in the order of 10⁻⁷, 10⁻⁶ and 10⁻⁵ S⋅cm⁻¹ at 350, 450 and 600 ◦C, respectively. Besides, XRD phase analysis revealed monoclinic Li₂ZrO₃ and minor ZrO₂ impurities originated from Li₂O volatilization during sintering, but no sign of TiO₂ segregation, indicating the formation of Li₂Zr₁-ₓTiₓO₃ solid solution.
Centro de Tecnología de Recursos Minerales y Cerámica
Centro de Investigación y Desarrollo en Criotecnología de Alimentos
description Ti-doped lithium zirconate (LZTO) sheets were successfully made by aqueous tape casting, by starting from an innovative colloidal synthesis route and optimizing the colloidal processing parameters. Zeta potential and particles size measurements, together with rheological characterization, were performed to adjust the slip composition. Then, the suspension with 1.0 wt% of ammonium polyacrylate dispersant (APA) and solid loading of 31 vol.% resulted in flat and flexible sheets, thinner than 450 μm, by adding 20 wt% of acrylic binder emulsion. After annealing at 1150 ◦C/15 h, LZTO sheets densified up to 85.5 %, presented a microstructure with grains of 6.4 μm in diameter, and exhibited electrical conductivity values in the order of 10⁻⁷, 10⁻⁶ and 10⁻⁵ S⋅cm⁻¹ at 350, 450 and 600 ◦C, respectively. Besides, XRD phase analysis revealed monoclinic Li₂ZrO₃ and minor ZrO₂ impurities originated from Li₂O volatilization during sintering, but no sign of TiO₂ segregation, indicating the formation of Li₂Zr₁-ₓTiₓO₃ solid solution.
publishDate 2025
dc.date.none.fl_str_mv 2025-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/181855
url http://sedici.unlp.edu.ar/handle/10915/181855
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/2666-5395
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.oceram.2025.100737
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.22299

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