Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
- Autores
- Bolzan, J. A.; Arvia, Alejandro Jorge
- Año de publicación
- 1970
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The electrical conductance of hydrogen chloride solutions in DMSO at 25°C has been studied. The limiting molar conductance is 38·7 int mho cm2 int mho cm2/mol. Conductivity data were interpreted with the Fuoss' theory for associated 1-1 type electrolytes. The association constant related to pair formation is 115·7 l/mol. The mechanism of electricl conduction of HCl in DMSO at infinite dilution resembles that of other 1-1 type electrolytes in the same solvent, in which charges are transported by simple entities in a viscous continuum.
On a étudié la conductivité électrique des solutions de chlorure d'hydrogéne dans le DMSO à 25°C. La conductivité limite molare est de 38,7 mho int cm2/mol. Les données expŕimentalles de la conductivité furent interprétées d'aprés la théorie de Fuoss pour des électrolytes associé du type 1-1. La constante d'association liée à la formation de paires ioniques simple est 115,7 l/mol. Le mechanisme de la conduction électrique du HCl dans le DMSO à dilution infinie ressemble celui des autres électrolytes du type 1-1 dans le même dissulvant, puisque les charges sont transportées par des entités simples dans un milieu visqueux continu.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas - Materia
-
Ciencias Exactas
Química
Hydrogen chloride
Dimethylsulphoxide - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
.jpg)
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/119387
Ver los metadatos del registro completo
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Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°CBolzan, J. A.Arvia, Alejandro JorgeCiencias ExactasQuímicaHydrogen chlorideDimethylsulphoxideThe electrical conductance of hydrogen chloride solutions in DMSO at 25°C has been studied. The limiting molar conductance is 38·7 int mho cm<sub>2</sub> int mho cm<sub>2</sub>/mol. Conductivity data were interpreted with the Fuoss' theory for associated 1-1 type electrolytes. The association constant related to pair formation is 115·7 l/mol. The mechanism of electricl conduction of HCl in DMSO at infinite dilution resembles that of other 1-1 type electrolytes in the same solvent, in which charges are transported by simple entities in a viscous continuum.On a étudié la conductivité électrique des solutions de chlorure d'hydrogéne dans le DMSO à 25°C. La conductivité limite molare est de 38,7 mho int cm<sub>2</sub>/mol. Les données expŕimentalles de la conductivité furent interprétées d'aprés la théorie de Fuoss pour des électrolytes associé du type 1-1. La constante d'association liée à la formation de paires ioniques simple est 115,7 l/mol. Le mechanisme de la conduction électrique du HCl dans le DMSO à dilution infinie ressemble celui des autres électrolytes du type 1-1 dans le même dissulvant, puisque les charges sont transportées par des entités simples dans un milieu visqueux continu.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1970info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf39-46http://sedici.unlp.edu.ar/handle/10915/119387enginfo:eu-repo/semantics/altIdentifier/issn/0013-4686info:eu-repo/semantics/altIdentifier/doi/10.1016/0013-4686(70)90005-8info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-22T17:09:04Zoai:sedici.unlp.edu.ar:10915/119387Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-22 17:09:05.275SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C |
| title |
Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C |
| spellingShingle |
Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C Bolzan, J. A. Ciencias Exactas Química Hydrogen chloride Dimethylsulphoxide |
| title_short |
Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C |
| title_full |
Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C |
| title_fullStr |
Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C |
| title_full_unstemmed |
Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C |
| title_sort |
Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C |
| dc.creator.none.fl_str_mv |
Bolzan, J. A. Arvia, Alejandro Jorge |
| author |
Bolzan, J. A. |
| author_facet |
Bolzan, J. A. Arvia, Alejandro Jorge |
| author_role |
author |
| author2 |
Arvia, Alejandro Jorge |
| author2_role |
author |
| dc.subject.none.fl_str_mv |
Ciencias Exactas Química Hydrogen chloride Dimethylsulphoxide |
| topic |
Ciencias Exactas Química Hydrogen chloride Dimethylsulphoxide |
| dc.description.none.fl_txt_mv |
The electrical conductance of hydrogen chloride solutions in DMSO at 25°C has been studied. The limiting molar conductance is 38·7 int mho cm<sub>2</sub> int mho cm<sub>2</sub>/mol. Conductivity data were interpreted with the Fuoss' theory for associated 1-1 type electrolytes. The association constant related to pair formation is 115·7 l/mol. The mechanism of electricl conduction of HCl in DMSO at infinite dilution resembles that of other 1-1 type electrolytes in the same solvent, in which charges are transported by simple entities in a viscous continuum. On a étudié la conductivité électrique des solutions de chlorure d'hydrogéne dans le DMSO à 25°C. La conductivité limite molare est de 38,7 mho int cm<sub>2</sub>/mol. Les données expŕimentalles de la conductivité furent interprétées d'aprés la théorie de Fuoss pour des électrolytes associé du type 1-1. La constante d'association liée à la formation de paires ioniques simple est 115,7 l/mol. Le mechanisme de la conduction électrique du HCl dans le DMSO à dilution infinie ressemble celui des autres électrolytes du type 1-1 dans le même dissulvant, puisque les charges sont transportées par des entités simples dans un milieu visqueux continu. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas |
| description |
The electrical conductance of hydrogen chloride solutions in DMSO at 25°C has been studied. The limiting molar conductance is 38·7 int mho cm<sub>2</sub> int mho cm<sub>2</sub>/mol. Conductivity data were interpreted with the Fuoss' theory for associated 1-1 type electrolytes. The association constant related to pair formation is 115·7 l/mol. The mechanism of electricl conduction of HCl in DMSO at infinite dilution resembles that of other 1-1 type electrolytes in the same solvent, in which charges are transported by simple entities in a viscous continuum. |
| publishDate |
1970 |
| dc.date.none.fl_str_mv |
1970 |
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info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
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publishedVersion |
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http://sedici.unlp.edu.ar/handle/10915/119387 |
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http://sedici.unlp.edu.ar/handle/10915/119387 |
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eng |
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eng |
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info:eu-repo/semantics/altIdentifier/issn/0013-4686 info:eu-repo/semantics/altIdentifier/doi/10.1016/0013-4686(70)90005-8 |
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info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
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openAccess |
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application/pdf 39-46 |
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