Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C

Autores
Bolzan, J. A.; Arvia, Alejandro Jorge
Año de publicación
1970
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The electrical conductance of hydrogen chloride solutions in DMSO at 25°C has been studied. The limiting molar conductance is 38·7 int mho cm2 int mho cm2/mol. Conductivity data were interpreted with the Fuoss' theory for associated 1-1 type electrolytes. The association constant related to pair formation is 115·7 l/mol. The mechanism of electricl conduction of HCl in DMSO at infinite dilution resembles that of other 1-1 type electrolytes in the same solvent, in which charges are transported by simple entities in a viscous continuum.
On a étudié la conductivité électrique des solutions de chlorure d'hydrogéne dans le DMSO à 25°C. La conductivité limite molare est de 38,7 mho int cm2/mol. Les données expŕimentalles de la conductivité furent interprétées d'aprés la théorie de Fuoss pour des électrolytes associé du type 1-1. La constante d'association liée à la formation de paires ioniques simple est 115,7 l/mol. Le mechanisme de la conduction électrique du HCl dans le DMSO à dilution infinie ressemble celui des autres électrolytes du type 1-1 dans le même dissulvant, puisque les charges sont transportées par des entités simples dans un milieu visqueux continu.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Ciencias Exactas
Química
Hydrogen chloride
Dimethylsulphoxide
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/119387

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network_name_str SEDICI (UNLP)
spelling Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°CBolzan, J. A.Arvia, Alejandro JorgeCiencias ExactasQuímicaHydrogen chlorideDimethylsulphoxideThe electrical conductance of hydrogen chloride solutions in DMSO at 25°C has been studied. The limiting molar conductance is 38·7 int mho cm<sub>2</sub> int mho cm<sub>2</sub>/mol. Conductivity data were interpreted with the Fuoss' theory for associated 1-1 type electrolytes. The association constant related to pair formation is 115·7 l/mol. The mechanism of electricl conduction of HCl in DMSO at infinite dilution resembles that of other 1-1 type electrolytes in the same solvent, in which charges are transported by simple entities in a viscous continuum.On a étudié la conductivité électrique des solutions de chlorure d'hydrogéne dans le DMSO à 25°C. La conductivité limite molare est de 38,7 mho int cm<sub>2</sub>/mol. Les données expŕimentalles de la conductivité furent interprétées d'aprés la théorie de Fuoss pour des électrolytes associé du type 1-1. La constante d'association liée à la formation de paires ioniques simple est 115,7 l/mol. Le mechanisme de la conduction électrique du HCl dans le DMSO à dilution infinie ressemble celui des autres électrolytes du type 1-1 dans le même dissulvant, puisque les charges sont transportées par des entités simples dans un milieu visqueux continu.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1970info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf39-46http://sedici.unlp.edu.ar/handle/10915/119387enginfo:eu-repo/semantics/altIdentifier/issn/0013-4686info:eu-repo/semantics/altIdentifier/doi/10.1016/0013-4686(70)90005-8info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:28:10Zoai:sedici.unlp.edu.ar:10915/119387Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:28:10.666SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
title Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
spellingShingle Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
Bolzan, J. A.
Ciencias Exactas
Química
Hydrogen chloride
Dimethylsulphoxide
title_short Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
title_full Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
title_fullStr Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
title_full_unstemmed Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
title_sort Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
dc.creator.none.fl_str_mv Bolzan, J. A.
Arvia, Alejandro Jorge
author Bolzan, J. A.
author_facet Bolzan, J. A.
Arvia, Alejandro Jorge
author_role author
author2 Arvia, Alejandro Jorge
author2_role author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
Hydrogen chloride
Dimethylsulphoxide
topic Ciencias Exactas
Química
Hydrogen chloride
Dimethylsulphoxide
dc.description.none.fl_txt_mv The electrical conductance of hydrogen chloride solutions in DMSO at 25°C has been studied. The limiting molar conductance is 38·7 int mho cm<sub>2</sub> int mho cm<sub>2</sub>/mol. Conductivity data were interpreted with the Fuoss' theory for associated 1-1 type electrolytes. The association constant related to pair formation is 115·7 l/mol. The mechanism of electricl conduction of HCl in DMSO at infinite dilution resembles that of other 1-1 type electrolytes in the same solvent, in which charges are transported by simple entities in a viscous continuum.
On a étudié la conductivité électrique des solutions de chlorure d'hydrogéne dans le DMSO à 25°C. La conductivité limite molare est de 38,7 mho int cm<sub>2</sub>/mol. Les données expŕimentalles de la conductivité furent interprétées d'aprés la théorie de Fuoss pour des électrolytes associé du type 1-1. La constante d'association liée à la formation de paires ioniques simple est 115,7 l/mol. Le mechanisme de la conduction électrique du HCl dans le DMSO à dilution infinie ressemble celui des autres électrolytes du type 1-1 dans le même dissulvant, puisque les charges sont transportées par des entités simples dans un milieu visqueux continu.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description The electrical conductance of hydrogen chloride solutions in DMSO at 25°C has been studied. The limiting molar conductance is 38·7 int mho cm<sub>2</sub> int mho cm<sub>2</sub>/mol. Conductivity data were interpreted with the Fuoss' theory for associated 1-1 type electrolytes. The association constant related to pair formation is 115·7 l/mol. The mechanism of electricl conduction of HCl in DMSO at infinite dilution resembles that of other 1-1 type electrolytes in the same solvent, in which charges are transported by simple entities in a viscous continuum.
publishDate 1970
dc.date.none.fl_str_mv 1970
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
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dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/119387
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dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0013-4686
info:eu-repo/semantics/altIdentifier/doi/10.1016/0013-4686(70)90005-8
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
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