Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions

Autores
Posadas, Dionisio; Arvia, Alejandro Jorge
Año de publicación
1973
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Rapid galvanostatic and potentiostatic stationary E/I curves, E/time characteristics at current interruption and electrode capacitance measurements were made to investigate hydrogen-ion discharge on mercury in HCl-DMSO solutions, with and without the addition of LiCl as supporting electrolyte. Kinetic parameters and their temperature and concentration dependences are discussed in terms of the initial electron-trnsfer reaction as rate-determining.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Ciencias Exactas
Química
Temperature
Kinetics
Hydrogen evolution
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/121727
Acceder
id SEDICI_b956ba35382b82a283319da87e3c7a28
oai_identifier_str oai:sedici.unlp.edu.ar:10915/121727
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutionsPosadas, DionisioArvia, Alejandro JorgeCiencias ExactasQuímicaTemperatureKineticsHydrogen evolutionRapid galvanostatic and potentiostatic stationary E/I curves, E/time characteristics at current interruption and electrode capacitance measurements were made to investigate hydrogen-ion discharge on mercury in HCl-DMSO solutions, with and without the addition of LiCl as supporting electrolyte. Kinetic parameters and their temperature and concentration dependences are discussed in terms of the initial electron-trnsfer reaction as rate-determining.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1973info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf205-209http://sedici.unlp.edu.ar/handle/10915/121727enginfo:eu-repo/semantics/altIdentifier/issn/0013-4686info:eu-repo/semantics/altIdentifier/doi/10.1016/0013-4686(73)80013-1info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-22T17:09:49Zoai:sedici.unlp.edu.ar:10915/121727Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-22 17:09:49.499SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
title Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
spellingShingle Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
Posadas, Dionisio
Ciencias Exactas
Química
Temperature
Kinetics
Hydrogen evolution
title_short Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
title_full Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
title_fullStr Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
title_full_unstemmed Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
title_sort Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
dc.creator.none.fl_str_mv Posadas, Dionisio
Arvia, Alejandro Jorge
author Posadas, Dionisio
author_facet Posadas, Dionisio
Arvia, Alejandro Jorge
author_role author
author2 Arvia, Alejandro Jorge
author2_role author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
Temperature
Kinetics
Hydrogen evolution
topic Ciencias Exactas
Química
Temperature
Kinetics
Hydrogen evolution
dc.description.none.fl_txt_mv Rapid galvanostatic and potentiostatic stationary E/I curves, E/time characteristics at current interruption and electrode capacitance measurements were made to investigate hydrogen-ion discharge on mercury in HCl-DMSO solutions, with and without the addition of LiCl as supporting electrolyte. Kinetic parameters and their temperature and concentration dependences are discussed in terms of the initial electron-trnsfer reaction as rate-determining.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description Rapid galvanostatic and potentiostatic stationary E/I curves, E/time characteristics at current interruption and electrode capacitance measurements were made to investigate hydrogen-ion discharge on mercury in HCl-DMSO solutions, with and without the addition of LiCl as supporting electrolyte. Kinetic parameters and their temperature and concentration dependences are discussed in terms of the initial electron-trnsfer reaction as rate-determining.
publishDate 1973
dc.date.none.fl_str_mv 1973
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/121727
url http://sedici.unlp.edu.ar/handle/10915/121727
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0013-4686
info:eu-repo/semantics/altIdentifier/doi/10.1016/0013-4686(73)80013-1
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
205-209
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 12.982451

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