Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen

Autores
Delgado, A.; Posadas, Dionisio; Arvia, Alejandro Jorge
Año de publicación
1973
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The electrochemical reduction of the solvated hydrogen ion dissolved in DMSO as HCl was investigated from 25 to 45°C, at different concentrations and ionic strength. Stationary and non-stationary techniques were employed to obtained the kinetic parameters. The results were interpreted with a reaction scheme involving an initial electron transfer as rds, probably followed by an electrochemical desorption step.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Ciencias Exactas
Química
Hydrogen
Nickel
HCl-dimethylsulphoxide
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/119948
Acceder
id SEDICI_28a9194d6039351ca7a202ffe4ac10f3
oai_identifier_str oai:sedici.unlp.edu.ar:10915/119948
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogenDelgado, A.Posadas, DionisioArvia, Alejandro JorgeCiencias ExactasQuímicaHydrogenNickelHCl-dimethylsulphoxideThe electrochemical reduction of the solvated hydrogen ion dissolved in DMSO as HCl was investigated from 25 to 45°C, at different concentrations and ionic strength. Stationary and non-stationary techniques were employed to obtained the kinetic parameters. The results were interpreted with a reaction scheme involving an initial electron transfer as <i>rds</i>, probably followed by an electrochemical desorption step.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1973info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf657-663http://sedici.unlp.edu.ar/handle/10915/119948enginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/0013468673800775info:eu-repo/semantics/altIdentifier/issn/0013-4686info:eu-repo/semantics/altIdentifier/doi/10.1016/0013-4686(73)80077-5info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-22T17:09:14Zoai:sedici.unlp.edu.ar:10915/119948Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-22 17:09:15.2SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
title Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
spellingShingle Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
Delgado, A.
Ciencias Exactas
Química
Hydrogen
Nickel
HCl-dimethylsulphoxide
title_short Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
title_full Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
title_fullStr Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
title_full_unstemmed Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
title_sort Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
dc.creator.none.fl_str_mv Delgado, A.
Posadas, Dionisio
Arvia, Alejandro Jorge
author Delgado, A.
author_facet Delgado, A.
Posadas, Dionisio
Arvia, Alejandro Jorge
author_role author
author2 Posadas, Dionisio
Arvia, Alejandro Jorge
author2_role author
author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
Hydrogen
Nickel
HCl-dimethylsulphoxide
topic Ciencias Exactas
Química
Hydrogen
Nickel
HCl-dimethylsulphoxide
dc.description.none.fl_txt_mv The electrochemical reduction of the solvated hydrogen ion dissolved in DMSO as HCl was investigated from 25 to 45°C, at different concentrations and ionic strength. Stationary and non-stationary techniques were employed to obtained the kinetic parameters. The results were interpreted with a reaction scheme involving an initial electron transfer as <i>rds</i>, probably followed by an electrochemical desorption step.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description The electrochemical reduction of the solvated hydrogen ion dissolved in DMSO as HCl was investigated from 25 to 45°C, at different concentrations and ionic strength. Stationary and non-stationary techniques were employed to obtained the kinetic parameters. The results were interpreted with a reaction scheme involving an initial electron transfer as <i>rds</i>, probably followed by an electrochemical desorption step.
publishDate 1973
dc.date.none.fl_str_mv 1973
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/119948
url http://sedici.unlp.edu.ar/handle/10915/119948
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/0013468673800775
info:eu-repo/semantics/altIdentifier/issn/0013-4686
info:eu-repo/semantics/altIdentifier/doi/10.1016/0013-4686(73)80077-5
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
657-663
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 12.982451

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