Catalytic pyrolysis of used tires on noble-metal-based catalysts to obtain high-value chemicals: Reaction pathways

Autores
Osorio Vargas, Paula; Campos, Cristian H.; Torres, Cecilia C.; Herrera, Carla; Shanmugaraj, Krishnamoorthy; Bustamante, Tatiana M.; Diaz de Leon, J. N.; Medina, Francisco; Arteaga-Pérez, Luis E.
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A systematic study on the use of noble metals (Pd, Pt, Au) supported on titanate nanotubes (NT-Ti) for selectively producing BTX and p-cymene from waste tire pyrolysis is provided here. All the materials were characterized for chemical, textural and structural properties using a range of analytical techniques. The M/NT-Ti (M: Pd, Pt, or Au) catalysts exhibit low nanoparticle sizes (1.8 Pt ≈ Au > support > non-catalyst. The Py-GC/MS suggest that the catalysts participate in the secondary reactions of dealkylation, dehydrogenation, isomerization, aromatization, and cyclization leading to a higher formation of BTX than the uncatalyzed reaction. Finally, a comprehensive reaction pathway describing the catalytic pyrolysis of WT over Pd/NT-Ti was proposed by studying the catalytic pyrolysis of individual polymers constituting the waste tires, and D,L-Limonene.
Puede accederse a los datos primarios de este trabajo haciendo clic en "Documentos relacionados".
Centro de Investigación y Desarrollo en Ciencias Aplicadas
Materia
Ciencias Exactas
Química
Waste tires
Catalytic pyrolysis
Noble metal
Titanate nanotubes
BTX
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/154475
Acceder
id SEDICI_3b40a545977cc87d515bdb9df47a6655
oai_identifier_str oai:sedici.unlp.edu.ar:10915/154475
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Catalytic pyrolysis of used tires on noble-metal-based catalysts to obtain high-value chemicals: Reaction pathwaysOsorio Vargas, PaulaCampos, Cristian H.Torres, Cecilia C.Herrera, CarlaShanmugaraj, KrishnamoorthyBustamante, Tatiana M.Diaz de Leon, J. N.Medina, FranciscoArteaga-Pérez, Luis E.Ciencias ExactasQuímicaWaste tiresCatalytic pyrolysisNoble metalTitanate nanotubesBTXA systematic study on the use of noble metals (Pd, Pt, Au) supported on titanate nanotubes (NT-Ti) for selectively producing BTX and p-cymene from waste tire pyrolysis is provided here. All the materials were characterized for chemical, textural and structural properties using a range of analytical techniques. The M/NT-Ti (M: Pd, Pt, or Au) catalysts exhibit low nanoparticle sizes (1.8 <NPs<2.2 nm), and a homogeneous pore size distribution. The catalysts demonstrated excellent activity for converting WT into BTX-enriched oil when tested in a micropyrolysis system coupled to chromatography/mass spectrometry (Py–GC/MS). The BTX production was enhanced by the presence of catalysts with a selectivity order as follows Pd > Pt ≈ Au > support > non-catalyst. The Py-GC/MS suggest that the catalysts participate in the secondary reactions of dealkylation, dehydrogenation, isomerization, aromatization, and cyclization leading to a higher formation of BTX than the uncatalyzed reaction. Finally, a comprehensive reaction pathway describing the catalytic pyrolysis of WT over Pd/NT-Ti was proposed by studying the catalytic pyrolysis of individual polymers constituting the waste tires, and D,L-Limonene.Puede accederse a los datos primarios de este trabajo haciendo clic en "Documentos relacionados".Centro de Investigación y Desarrollo en Ciencias Aplicadas2022-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf475-485http://sedici.unlp.edu.ar/handle/10915/154475enginfo:eu-repo/semantics/altIdentifier/issn/0920-5861info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2021.06.029info:eu-repo/semantics/reference/hdl/10915/154487info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:40:03Zoai:sedici.unlp.edu.ar:10915/154475Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:40:03.429SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Catalytic pyrolysis of used tires on noble-metal-based catalysts to obtain high-value chemicals: Reaction pathways
title Catalytic pyrolysis of used tires on noble-metal-based catalysts to obtain high-value chemicals: Reaction pathways
spellingShingle Catalytic pyrolysis of used tires on noble-metal-based catalysts to obtain high-value chemicals: Reaction pathways
Osorio Vargas, Paula
Ciencias Exactas
Química
Waste tires
Catalytic pyrolysis
Noble metal
Titanate nanotubes
BTX
title_short Catalytic pyrolysis of used tires on noble-metal-based catalysts to obtain high-value chemicals: Reaction pathways
title_full Catalytic pyrolysis of used tires on noble-metal-based catalysts to obtain high-value chemicals: Reaction pathways
title_fullStr Catalytic pyrolysis of used tires on noble-metal-based catalysts to obtain high-value chemicals: Reaction pathways
title_full_unstemmed Catalytic pyrolysis of used tires on noble-metal-based catalysts to obtain high-value chemicals: Reaction pathways
title_sort Catalytic pyrolysis of used tires on noble-metal-based catalysts to obtain high-value chemicals: Reaction pathways
dc.creator.none.fl_str_mv Osorio Vargas, Paula
Campos, Cristian H.
Torres, Cecilia C.
Herrera, Carla
Shanmugaraj, Krishnamoorthy
Bustamante, Tatiana M.
Diaz de Leon, J. N.
Medina, Francisco
Arteaga-Pérez, Luis E.
author Osorio Vargas, Paula
author_facet Osorio Vargas, Paula
Campos, Cristian H.
Torres, Cecilia C.
Herrera, Carla
Shanmugaraj, Krishnamoorthy
Bustamante, Tatiana M.
Diaz de Leon, J. N.
Medina, Francisco
Arteaga-Pérez, Luis E.
author_role author
author2 Campos, Cristian H.
Torres, Cecilia C.
Herrera, Carla
Shanmugaraj, Krishnamoorthy
Bustamante, Tatiana M.
Diaz de Leon, J. N.
Medina, Francisco
Arteaga-Pérez, Luis E.
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
Waste tires
Catalytic pyrolysis
Noble metal
Titanate nanotubes
BTX
topic Ciencias Exactas
Química
Waste tires
Catalytic pyrolysis
Noble metal
Titanate nanotubes
BTX
dc.description.none.fl_txt_mv A systematic study on the use of noble metals (Pd, Pt, Au) supported on titanate nanotubes (NT-Ti) for selectively producing BTX and p-cymene from waste tire pyrolysis is provided here. All the materials were characterized for chemical, textural and structural properties using a range of analytical techniques. The M/NT-Ti (M: Pd, Pt, or Au) catalysts exhibit low nanoparticle sizes (1.8 <NPs<2.2 nm), and a homogeneous pore size distribution. The catalysts demonstrated excellent activity for converting WT into BTX-enriched oil when tested in a micropyrolysis system coupled to chromatography/mass spectrometry (Py–GC/MS). The BTX production was enhanced by the presence of catalysts with a selectivity order as follows Pd > Pt ≈ Au > support > non-catalyst. The Py-GC/MS suggest that the catalysts participate in the secondary reactions of dealkylation, dehydrogenation, isomerization, aromatization, and cyclization leading to a higher formation of BTX than the uncatalyzed reaction. Finally, a comprehensive reaction pathway describing the catalytic pyrolysis of WT over Pd/NT-Ti was proposed by studying the catalytic pyrolysis of individual polymers constituting the waste tires, and D,L-Limonene.
Puede accederse a los datos primarios de este trabajo haciendo clic en "Documentos relacionados".
Centro de Investigación y Desarrollo en Ciencias Aplicadas
description A systematic study on the use of noble metals (Pd, Pt, Au) supported on titanate nanotubes (NT-Ti) for selectively producing BTX and p-cymene from waste tire pyrolysis is provided here. All the materials were characterized for chemical, textural and structural properties using a range of analytical techniques. The M/NT-Ti (M: Pd, Pt, or Au) catalysts exhibit low nanoparticle sizes (1.8 <NPs<2.2 nm), and a homogeneous pore size distribution. The catalysts demonstrated excellent activity for converting WT into BTX-enriched oil when tested in a micropyrolysis system coupled to chromatography/mass spectrometry (Py–GC/MS). The BTX production was enhanced by the presence of catalysts with a selectivity order as follows Pd > Pt ≈ Au > support > non-catalyst. The Py-GC/MS suggest that the catalysts participate in the secondary reactions of dealkylation, dehydrogenation, isomerization, aromatization, and cyclization leading to a higher formation of BTX than the uncatalyzed reaction. Finally, a comprehensive reaction pathway describing the catalytic pyrolysis of WT over Pd/NT-Ti was proposed by studying the catalytic pyrolysis of individual polymers constituting the waste tires, and D,L-Limonene.
publishDate 2022
dc.date.none.fl_str_mv 2022-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/154475
url http://sedici.unlp.edu.ar/handle/10915/154475
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0920-5861
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2021.06.029
info:eu-repo/semantics/reference/hdl/10915/154487
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
475-485
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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