Tuning the product distribution during the catalytic pyrolysis of waste tires: The effect of the nature of metals and the reaction temperature

Autores
Osorio Vargas, Paula Alejandra; Menares, Tamara; Lick, Ileana Daniela; Casella, Mónica Laura; Romero, Romina; Jiménez, Romel; Arteaga Pérez, Luis E.
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Metal catalysts based on Ni, Co, and Pd supported on SiO2 were evaluated in the catalytic pyrolysis of waste tires using pyrolysis experiments coupled to gas chromatography/mass spectrometry (Py–GC/MS) and thermogravimetric analysis coupled with Fourier Transform Infrared spectrometer (TGA–FTIR) techniques. The effect of temperature and the nature of metals on the product distribution and reaction pathways was determined. Catalytic pyrolysis promoted aromatization and cracking reactions at particularly low temperatures ca. 350 °C, leading mainly to the formation of alkenes (isoprene), aromatic terpenes (p-cymene), aliphatic terpenes (d,l-limonene), and other aromatic compounds such as benzene, toluene, and xylenes (BTX). The Pd/SiO2 catalyst was the most selective toward aromatic compounds (around 40 %), owing to its well-known hydrogenation/dehydrogenation capacity, while CCsingle bond bond cleavage reactions, leading to alkenes, were more favored on the Ni/SiO2 and Co/SiO2 catalysts. In all cases, high selectivity to limonene and isoprene was observed at low temperature. Above 400 °C, no significant differences in product distribution were observed between catalyzed and uncatalyzed pyrolysis. Herein, selectivity toward high-value hydrocarbons (i.e., d,l-limonene, isoprene, BTX, and p-cymene) during the catalytic pyrolysis of waste tires was tuned by the nature of the supported transition metals (i.e., Ni, Co, Pd) and the reaction temperature (e.g., <400 °C). The results demonstrate that the use of these catalysts is a promising strategy to valorize waste tires into high added-value products.
Fil: Osorio Vargas, Paula Alejandra. Universidad del Bio Bio; Chile. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Menares, Tamara. Universidad del Bio Bio; Chile. Universidad de Concepción; Chile
Fil: Lick, Ileana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Romero, Romina. Universidad de Concepción; Chile. Universidad de Tarapaca. Instituto de Alta Investigacion.; Chile
Fil: Jiménez, Romel. Universidad de Concepción; Chile
Fil: Arteaga Pérez, Luis E.. Universidad del Bio Bio; Chile. Universidad de Concepción; Chile
Materia
catalytic pyrolysis
waste tires
high added-value products
BTX
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/139857
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Tuning the product distribution during the catalytic pyrolysis of waste tires: The effect of the nature of metals and the reaction temperatureOsorio Vargas, Paula AlejandraMenares, TamaraLick, Ileana DanielaCasella, Mónica LauraRomero, RominaJiménez, RomelArteaga Pérez, Luis E.catalytic pyrolysiswaste tireshigh added-value productsBTXhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Metal catalysts based on Ni, Co, and Pd supported on SiO2 were evaluated in the catalytic pyrolysis of waste tires using pyrolysis experiments coupled to gas chromatography/mass spectrometry (Py–GC/MS) and thermogravimetric analysis coupled with Fourier Transform Infrared spectrometer (TGA–FTIR) techniques. The effect of temperature and the nature of metals on the product distribution and reaction pathways was determined. Catalytic pyrolysis promoted aromatization and cracking reactions at particularly low temperatures ca. 350 °C, leading mainly to the formation of alkenes (isoprene), aromatic terpenes (p-cymene), aliphatic terpenes (d,l-limonene), and other aromatic compounds such as benzene, toluene, and xylenes (BTX). The Pd/SiO2 catalyst was the most selective toward aromatic compounds (around 40 %), owing to its well-known hydrogenation/dehydrogenation capacity, while CCsingle bond bond cleavage reactions, leading to alkenes, were more favored on the Ni/SiO2 and Co/SiO2 catalysts. In all cases, high selectivity to limonene and isoprene was observed at low temperature. Above 400 °C, no significant differences in product distribution were observed between catalyzed and uncatalyzed pyrolysis. Herein, selectivity toward high-value hydrocarbons (i.e., d,l-limonene, isoprene, BTX, and p-cymene) during the catalytic pyrolysis of waste tires was tuned by the nature of the supported transition metals (i.e., Ni, Co, Pd) and the reaction temperature (e.g., <400 °C). The results demonstrate that the use of these catalysts is a promising strategy to valorize waste tires into high added-value products.Fil: Osorio Vargas, Paula Alejandra. Universidad del Bio Bio; Chile. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Menares, Tamara. Universidad del Bio Bio; Chile. Universidad de Concepción; ChileFil: Lick, Ileana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Romero, Romina. Universidad de Concepción; Chile. Universidad de Tarapaca. Instituto de Alta Investigacion.; ChileFil: Jiménez, Romel. Universidad de Concepción; ChileFil: Arteaga Pérez, Luis E.. Universidad del Bio Bio; Chile. Universidad de Concepción; ChileElsevier Science2021-07-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/139857Osorio Vargas, Paula Alejandra; Menares, Tamara; Lick, Ileana Daniela; Casella, Mónica Laura; Romero, Romina; et al.; Tuning the product distribution during the catalytic pyrolysis of waste tires: The effect of the nature of metals and the reaction temperature; Elsevier Science; Catalysis Today; 372; 2; 15-7-2021; 164-1740920-5861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0920586120307409info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2020.10.035info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:58:48Zoai:ri.conicet.gov.ar:11336/139857instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:58:48.962CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Tuning the product distribution during the catalytic pyrolysis of waste tires: The effect of the nature of metals and the reaction temperature
title Tuning the product distribution during the catalytic pyrolysis of waste tires: The effect of the nature of metals and the reaction temperature
spellingShingle Tuning the product distribution during the catalytic pyrolysis of waste tires: The effect of the nature of metals and the reaction temperature
Osorio Vargas, Paula Alejandra
catalytic pyrolysis
waste tires
high added-value products
BTX
title_short Tuning the product distribution during the catalytic pyrolysis of waste tires: The effect of the nature of metals and the reaction temperature
title_full Tuning the product distribution during the catalytic pyrolysis of waste tires: The effect of the nature of metals and the reaction temperature
title_fullStr Tuning the product distribution during the catalytic pyrolysis of waste tires: The effect of the nature of metals and the reaction temperature
title_full_unstemmed Tuning the product distribution during the catalytic pyrolysis of waste tires: The effect of the nature of metals and the reaction temperature
title_sort Tuning the product distribution during the catalytic pyrolysis of waste tires: The effect of the nature of metals and the reaction temperature
dc.creator.none.fl_str_mv Osorio Vargas, Paula Alejandra
Menares, Tamara
Lick, Ileana Daniela
Casella, Mónica Laura
Romero, Romina
Jiménez, Romel
Arteaga Pérez, Luis E.
author Osorio Vargas, Paula Alejandra
author_facet Osorio Vargas, Paula Alejandra
Menares, Tamara
Lick, Ileana Daniela
Casella, Mónica Laura
Romero, Romina
Jiménez, Romel
Arteaga Pérez, Luis E.
author_role author
author2 Menares, Tamara
Lick, Ileana Daniela
Casella, Mónica Laura
Romero, Romina
Jiménez, Romel
Arteaga Pérez, Luis E.
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv catalytic pyrolysis
waste tires
high added-value products
BTX
topic catalytic pyrolysis
waste tires
high added-value products
BTX
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Metal catalysts based on Ni, Co, and Pd supported on SiO2 were evaluated in the catalytic pyrolysis of waste tires using pyrolysis experiments coupled to gas chromatography/mass spectrometry (Py–GC/MS) and thermogravimetric analysis coupled with Fourier Transform Infrared spectrometer (TGA–FTIR) techniques. The effect of temperature and the nature of metals on the product distribution and reaction pathways was determined. Catalytic pyrolysis promoted aromatization and cracking reactions at particularly low temperatures ca. 350 °C, leading mainly to the formation of alkenes (isoprene), aromatic terpenes (p-cymene), aliphatic terpenes (d,l-limonene), and other aromatic compounds such as benzene, toluene, and xylenes (BTX). The Pd/SiO2 catalyst was the most selective toward aromatic compounds (around 40 %), owing to its well-known hydrogenation/dehydrogenation capacity, while CCsingle bond bond cleavage reactions, leading to alkenes, were more favored on the Ni/SiO2 and Co/SiO2 catalysts. In all cases, high selectivity to limonene and isoprene was observed at low temperature. Above 400 °C, no significant differences in product distribution were observed between catalyzed and uncatalyzed pyrolysis. Herein, selectivity toward high-value hydrocarbons (i.e., d,l-limonene, isoprene, BTX, and p-cymene) during the catalytic pyrolysis of waste tires was tuned by the nature of the supported transition metals (i.e., Ni, Co, Pd) and the reaction temperature (e.g., <400 °C). The results demonstrate that the use of these catalysts is a promising strategy to valorize waste tires into high added-value products.
Fil: Osorio Vargas, Paula Alejandra. Universidad del Bio Bio; Chile. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Menares, Tamara. Universidad del Bio Bio; Chile. Universidad de Concepción; Chile
Fil: Lick, Ileana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Romero, Romina. Universidad de Concepción; Chile. Universidad de Tarapaca. Instituto de Alta Investigacion.; Chile
Fil: Jiménez, Romel. Universidad de Concepción; Chile
Fil: Arteaga Pérez, Luis E.. Universidad del Bio Bio; Chile. Universidad de Concepción; Chile
description Metal catalysts based on Ni, Co, and Pd supported on SiO2 were evaluated in the catalytic pyrolysis of waste tires using pyrolysis experiments coupled to gas chromatography/mass spectrometry (Py–GC/MS) and thermogravimetric analysis coupled with Fourier Transform Infrared spectrometer (TGA–FTIR) techniques. The effect of temperature and the nature of metals on the product distribution and reaction pathways was determined. Catalytic pyrolysis promoted aromatization and cracking reactions at particularly low temperatures ca. 350 °C, leading mainly to the formation of alkenes (isoprene), aromatic terpenes (p-cymene), aliphatic terpenes (d,l-limonene), and other aromatic compounds such as benzene, toluene, and xylenes (BTX). The Pd/SiO2 catalyst was the most selective toward aromatic compounds (around 40 %), owing to its well-known hydrogenation/dehydrogenation capacity, while CCsingle bond bond cleavage reactions, leading to alkenes, were more favored on the Ni/SiO2 and Co/SiO2 catalysts. In all cases, high selectivity to limonene and isoprene was observed at low temperature. Above 400 °C, no significant differences in product distribution were observed between catalyzed and uncatalyzed pyrolysis. Herein, selectivity toward high-value hydrocarbons (i.e., d,l-limonene, isoprene, BTX, and p-cymene) during the catalytic pyrolysis of waste tires was tuned by the nature of the supported transition metals (i.e., Ni, Co, Pd) and the reaction temperature (e.g., <400 °C). The results demonstrate that the use of these catalysts is a promising strategy to valorize waste tires into high added-value products.
publishDate 2021
dc.date.none.fl_str_mv 2021-07-15
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/139857
Osorio Vargas, Paula Alejandra; Menares, Tamara; Lick, Ileana Daniela; Casella, Mónica Laura; Romero, Romina; et al.; Tuning the product distribution during the catalytic pyrolysis of waste tires: The effect of the nature of metals and the reaction temperature; Elsevier Science; Catalysis Today; 372; 2; 15-7-2021; 164-174
0920-5861
CONICET Digital
CONICET
url http://hdl.handle.net/11336/139857
identifier_str_mv Osorio Vargas, Paula Alejandra; Menares, Tamara; Lick, Ileana Daniela; Casella, Mónica Laura; Romero, Romina; et al.; Tuning the product distribution during the catalytic pyrolysis of waste tires: The effect of the nature of metals and the reaction temperature; Elsevier Science; Catalysis Today; 372; 2; 15-7-2021; 164-174
0920-5861
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0920586120307409
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2020.10.035
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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