Nickel and Cobalt Ilmenites-Based Catalysts for Upgrading Pyrolytic Oil during Pyrolysis of Waste Tires

Autores
Correa Muriel, Daniela; Valencia Sánchez, Hoover Albeiro; Cortes Hernández, Héctor; González Vera, Daniela; Herrera, Javiera; Campos, Cristian H.; Casella, Mónica Laura; Arteaga Perez, Luis Ernesto; Osorio Vargas, Paula Alejandra
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Pyrolysis as a waste treatment method has gained relevance because it can generate higher value-added products in addition to reducing the environment’s secondary pollution. In this study, the catalytic pyrolysis of waste tires was evaluated using NiTiO3 and CoTiO3 ilmenites as catalysts and precursors of metal catalysts with the aim to produce an oil enriched in high-value hydrocarbons, such as benzene, toluene, a xylenes mixture, and products less-reported, such as p-cymene and p-cymenene. The experiments were performed in an analytical pyrolyzer coupled to GC/MS. The effect of the nature of the catalysts on the product distribution was compared with the uncatalyzed reaction. The main products of uncatalyzed pyrolysis were D, L-limonene (~60%), and isoprene (~25%) due to the depolymerization of natural rubber. Meanwhile, Ni-ilmenites-based catalysts favored the formation of target compounds to expense D, L-limonene. Moreover, the presence of metal in reduced-ilmenite sharply enhanced the selectivity by ~50% concerning oxidized ilmenite and above 80% compared to the uncatalyzed reaction for p-cymene and p-cymenene. By contrast, the Co-ilmenites-based catalysts showed a marginal effect on secondary reactions. Finally, the feasibility of forming the aromatic terpenes, p-cymene, and p-cymenene from limonene in the non-catalytic pyrolysis was evaluated.
Fil: Correa Muriel, Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Valencia Sánchez, Hoover Albeiro. Universidad Tecnológica de Pereira; Colombia
Fil: Cortes Hernández, Héctor. Universidad Tecnológica de Pereira; Colombia
Fil: González Vera, Daniela. Universidad de Concepción; Chile
Fil: Herrera, Javiera. Universidad de Concepción; Chile
Fil: Campos, Cristian H.. Universidad de Concepción; Chile
Fil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Arteaga Perez, Luis Ernesto. Universidad del Bio Bio; Chile
Fil: Osorio Vargas, Paula Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Materia
AROMATICS PRODUCTION
ILMENITES
METAL CATALYSTS
WASTE TIRE PYROLYSIS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/217335
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/217335
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Nickel and Cobalt Ilmenites-Based Catalysts for Upgrading Pyrolytic Oil during Pyrolysis of Waste TiresCorrea Muriel, DanielaValencia Sánchez, Hoover AlbeiroCortes Hernández, HéctorGonzález Vera, DanielaHerrera, JavieraCampos, Cristian H.Casella, Mónica LauraArteaga Perez, Luis ErnestoOsorio Vargas, Paula AlejandraAROMATICS PRODUCTIONILMENITESMETAL CATALYSTSWASTE TIRE PYROLYSIShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Pyrolysis as a waste treatment method has gained relevance because it can generate higher value-added products in addition to reducing the environment’s secondary pollution. In this study, the catalytic pyrolysis of waste tires was evaluated using NiTiO3 and CoTiO3 ilmenites as catalysts and precursors of metal catalysts with the aim to produce an oil enriched in high-value hydrocarbons, such as benzene, toluene, a xylenes mixture, and products less-reported, such as p-cymene and p-cymenene. The experiments were performed in an analytical pyrolyzer coupled to GC/MS. The effect of the nature of the catalysts on the product distribution was compared with the uncatalyzed reaction. The main products of uncatalyzed pyrolysis were D, L-limonene (~60%), and isoprene (~25%) due to the depolymerization of natural rubber. Meanwhile, Ni-ilmenites-based catalysts favored the formation of target compounds to expense D, L-limonene. Moreover, the presence of metal in reduced-ilmenite sharply enhanced the selectivity by ~50% concerning oxidized ilmenite and above 80% compared to the uncatalyzed reaction for p-cymene and p-cymenene. By contrast, the Co-ilmenites-based catalysts showed a marginal effect on secondary reactions. Finally, the feasibility of forming the aromatic terpenes, p-cymene, and p-cymenene from limonene in the non-catalytic pyrolysis was evaluated.Fil: Correa Muriel, Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Valencia Sánchez, Hoover Albeiro. Universidad Tecnológica de Pereira; ColombiaFil: Cortes Hernández, Héctor. Universidad Tecnológica de Pereira; ColombiaFil: González Vera, Daniela. Universidad de Concepción; ChileFil: Herrera, Javiera. Universidad de Concepción; ChileFil: Campos, Cristian H.. Universidad de Concepción; ChileFil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Arteaga Perez, Luis Ernesto. Universidad del Bio Bio; ChileFil: Osorio Vargas, Paula Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaMDPI2022-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/217335Correa Muriel, Daniela; Valencia Sánchez, Hoover Albeiro; Cortes Hernández, Héctor; González Vera, Daniela; Herrera, Javiera; et al.; Nickel and Cobalt Ilmenites-Based Catalysts for Upgrading Pyrolytic Oil during Pyrolysis of Waste Tires; MDPI; Catalysts; 12; 11; 11-2022; 1-172073-4344CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4344/12/11/1437info:eu-repo/semantics/altIdentifier/doi/10.3390/catal12111437info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:22:05Zoai:ri.conicet.gov.ar:11336/217335instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:22:05.711CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Nickel and Cobalt Ilmenites-Based Catalysts for Upgrading Pyrolytic Oil during Pyrolysis of Waste Tires
title Nickel and Cobalt Ilmenites-Based Catalysts for Upgrading Pyrolytic Oil during Pyrolysis of Waste Tires
spellingShingle Nickel and Cobalt Ilmenites-Based Catalysts for Upgrading Pyrolytic Oil during Pyrolysis of Waste Tires
Correa Muriel, Daniela
AROMATICS PRODUCTION
ILMENITES
METAL CATALYSTS
WASTE TIRE PYROLYSIS
title_short Nickel and Cobalt Ilmenites-Based Catalysts for Upgrading Pyrolytic Oil during Pyrolysis of Waste Tires
title_full Nickel and Cobalt Ilmenites-Based Catalysts for Upgrading Pyrolytic Oil during Pyrolysis of Waste Tires
title_fullStr Nickel and Cobalt Ilmenites-Based Catalysts for Upgrading Pyrolytic Oil during Pyrolysis of Waste Tires
title_full_unstemmed Nickel and Cobalt Ilmenites-Based Catalysts for Upgrading Pyrolytic Oil during Pyrolysis of Waste Tires
title_sort Nickel and Cobalt Ilmenites-Based Catalysts for Upgrading Pyrolytic Oil during Pyrolysis of Waste Tires
dc.creator.none.fl_str_mv Correa Muriel, Daniela
Valencia Sánchez, Hoover Albeiro
Cortes Hernández, Héctor
González Vera, Daniela
Herrera, Javiera
Campos, Cristian H.
Casella, Mónica Laura
Arteaga Perez, Luis Ernesto
Osorio Vargas, Paula Alejandra
author Correa Muriel, Daniela
author_facet Correa Muriel, Daniela
Valencia Sánchez, Hoover Albeiro
Cortes Hernández, Héctor
González Vera, Daniela
Herrera, Javiera
Campos, Cristian H.
Casella, Mónica Laura
Arteaga Perez, Luis Ernesto
Osorio Vargas, Paula Alejandra
author_role author
author2 Valencia Sánchez, Hoover Albeiro
Cortes Hernández, Héctor
González Vera, Daniela
Herrera, Javiera
Campos, Cristian H.
Casella, Mónica Laura
Arteaga Perez, Luis Ernesto
Osorio Vargas, Paula Alejandra
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv AROMATICS PRODUCTION
ILMENITES
METAL CATALYSTS
WASTE TIRE PYROLYSIS
topic AROMATICS PRODUCTION
ILMENITES
METAL CATALYSTS
WASTE TIRE PYROLYSIS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Pyrolysis as a waste treatment method has gained relevance because it can generate higher value-added products in addition to reducing the environment’s secondary pollution. In this study, the catalytic pyrolysis of waste tires was evaluated using NiTiO3 and CoTiO3 ilmenites as catalysts and precursors of metal catalysts with the aim to produce an oil enriched in high-value hydrocarbons, such as benzene, toluene, a xylenes mixture, and products less-reported, such as p-cymene and p-cymenene. The experiments were performed in an analytical pyrolyzer coupled to GC/MS. The effect of the nature of the catalysts on the product distribution was compared with the uncatalyzed reaction. The main products of uncatalyzed pyrolysis were D, L-limonene (~60%), and isoprene (~25%) due to the depolymerization of natural rubber. Meanwhile, Ni-ilmenites-based catalysts favored the formation of target compounds to expense D, L-limonene. Moreover, the presence of metal in reduced-ilmenite sharply enhanced the selectivity by ~50% concerning oxidized ilmenite and above 80% compared to the uncatalyzed reaction for p-cymene and p-cymenene. By contrast, the Co-ilmenites-based catalysts showed a marginal effect on secondary reactions. Finally, the feasibility of forming the aromatic terpenes, p-cymene, and p-cymenene from limonene in the non-catalytic pyrolysis was evaluated.
Fil: Correa Muriel, Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Valencia Sánchez, Hoover Albeiro. Universidad Tecnológica de Pereira; Colombia
Fil: Cortes Hernández, Héctor. Universidad Tecnológica de Pereira; Colombia
Fil: González Vera, Daniela. Universidad de Concepción; Chile
Fil: Herrera, Javiera. Universidad de Concepción; Chile
Fil: Campos, Cristian H.. Universidad de Concepción; Chile
Fil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Arteaga Perez, Luis Ernesto. Universidad del Bio Bio; Chile
Fil: Osorio Vargas, Paula Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
description Pyrolysis as a waste treatment method has gained relevance because it can generate higher value-added products in addition to reducing the environment’s secondary pollution. In this study, the catalytic pyrolysis of waste tires was evaluated using NiTiO3 and CoTiO3 ilmenites as catalysts and precursors of metal catalysts with the aim to produce an oil enriched in high-value hydrocarbons, such as benzene, toluene, a xylenes mixture, and products less-reported, such as p-cymene and p-cymenene. The experiments were performed in an analytical pyrolyzer coupled to GC/MS. The effect of the nature of the catalysts on the product distribution was compared with the uncatalyzed reaction. The main products of uncatalyzed pyrolysis were D, L-limonene (~60%), and isoprene (~25%) due to the depolymerization of natural rubber. Meanwhile, Ni-ilmenites-based catalysts favored the formation of target compounds to expense D, L-limonene. Moreover, the presence of metal in reduced-ilmenite sharply enhanced the selectivity by ~50% concerning oxidized ilmenite and above 80% compared to the uncatalyzed reaction for p-cymene and p-cymenene. By contrast, the Co-ilmenites-based catalysts showed a marginal effect on secondary reactions. Finally, the feasibility of forming the aromatic terpenes, p-cymene, and p-cymenene from limonene in the non-catalytic pyrolysis was evaluated.
publishDate 2022
dc.date.none.fl_str_mv 2022-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/217335
Correa Muriel, Daniela; Valencia Sánchez, Hoover Albeiro; Cortes Hernández, Héctor; González Vera, Daniela; Herrera, Javiera; et al.; Nickel and Cobalt Ilmenites-Based Catalysts for Upgrading Pyrolytic Oil during Pyrolysis of Waste Tires; MDPI; Catalysts; 12; 11; 11-2022; 1-17
2073-4344
CONICET Digital
CONICET
url http://hdl.handle.net/11336/217335
identifier_str_mv Correa Muriel, Daniela; Valencia Sánchez, Hoover Albeiro; Cortes Hernández, Héctor; González Vera, Daniela; Herrera, Javiera; et al.; Nickel and Cobalt Ilmenites-Based Catalysts for Upgrading Pyrolytic Oil during Pyrolysis of Waste Tires; MDPI; Catalysts; 12; 11; 11-2022; 1-17
2073-4344
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4344/12/11/1437
info:eu-repo/semantics/altIdentifier/doi/10.3390/catal12111437
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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