Kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) in aqueous solution
- Autores
- Ronco, Silvia Elisa; Aymonino, Pedro José
- Año de publicación
- 1987
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) ion in aqueous solution in the presence ofo-phenanthroline was studied spectrophotometrically. The first-order rate constant (k; ϑ) at 30° C [I=1 M(NaCl)] for the thermal reaction is (1.49±0.13)×10−6 s−1 with ΔH; ≠=(158±7)kJ mol−1 and ΔS≠=(42±4) JK−1 mol−1. The initial quantum yield for the photochemical reaction at pH=7 is independent of the light intensity and is (1.49±0.33)×10−2 mol einstein−1.
Centro de Química Inorgánica - Materia
-
Química
Ciencias Exactas
photolysis
aquapentacyanoferrate(III) - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
.jpg)
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/139677
Ver los metadatos del registro completo
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Kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) in aqueous solutionRonco, Silvia ElisaAymonino, Pedro JoséQuímicaCiencias Exactasphotolysisaquapentacyanoferrate(III)The kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) ion in aqueous solution in the presence ofo-phenanthroline was studied spectrophotometrically. The first-order rate constant (k; ϑ) at 30° C [I=1 M(NaCl)] for the thermal reaction is (1.49±0.13)×10−6 s−1 with ΔH; ≠=(158±7)kJ mol−1 and ΔS≠=(42±4) JK−1 mol−1. The initial quantum yield for the photochemical reaction at pH=7 is independent of the light intensity and is (1.49±0.33)×10−2 mol einstein−1.Centro de Química Inorgánica1987info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf174-178http://sedici.unlp.edu.ar/handle/10915/139677enginfo:eu-repo/semantics/altIdentifier/issn/0340-4285info:eu-repo/semantics/altIdentifier/issn/1572-901xinfo:eu-repo/semantics/altIdentifier/doi/10.1007/bf01022350info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-15T11:23:53Zoai:sedici.unlp.edu.ar:10915/139677Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-15 11:23:54.215SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
Kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) in aqueous solution |
| title |
Kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) in aqueous solution |
| spellingShingle |
Kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) in aqueous solution Ronco, Silvia Elisa Química Ciencias Exactas photolysis aquapentacyanoferrate(III) |
| title_short |
Kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) in aqueous solution |
| title_full |
Kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) in aqueous solution |
| title_fullStr |
Kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) in aqueous solution |
| title_full_unstemmed |
Kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) in aqueous solution |
| title_sort |
Kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) in aqueous solution |
| dc.creator.none.fl_str_mv |
Ronco, Silvia Elisa Aymonino, Pedro José |
| author |
Ronco, Silvia Elisa |
| author_facet |
Ronco, Silvia Elisa Aymonino, Pedro José |
| author_role |
author |
| author2 |
Aymonino, Pedro José |
| author2_role |
author |
| dc.subject.none.fl_str_mv |
Química Ciencias Exactas photolysis aquapentacyanoferrate(III) |
| topic |
Química Ciencias Exactas photolysis aquapentacyanoferrate(III) |
| dc.description.none.fl_txt_mv |
The kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) ion in aqueous solution in the presence ofo-phenanthroline was studied spectrophotometrically. The first-order rate constant (k; ϑ) at 30° C [I=1 M(NaCl)] for the thermal reaction is (1.49±0.13)×10−6 s−1 with ΔH; ≠=(158±7)kJ mol−1 and ΔS≠=(42±4) JK−1 mol−1. The initial quantum yield for the photochemical reaction at pH=7 is independent of the light intensity and is (1.49±0.33)×10−2 mol einstein−1. Centro de Química Inorgánica |
| description |
The kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) ion in aqueous solution in the presence ofo-phenanthroline was studied spectrophotometrically. The first-order rate constant (k; ϑ) at 30° C [I=1 M(NaCl)] for the thermal reaction is (1.49±0.13)×10−6 s−1 with ΔH; ≠=(158±7)kJ mol−1 and ΔS≠=(42±4) JK−1 mol−1. The initial quantum yield for the photochemical reaction at pH=7 is independent of the light intensity and is (1.49±0.33)×10−2 mol einstein−1. |
| publishDate |
1987 |
| dc.date.none.fl_str_mv |
1987 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
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publishedVersion |
| dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/139677 |
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http://sedici.unlp.edu.ar/handle/10915/139677 |
| dc.language.none.fl_str_mv |
eng |
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eng |
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info:eu-repo/semantics/altIdentifier/issn/0340-4285 info:eu-repo/semantics/altIdentifier/issn/1572-901x info:eu-repo/semantics/altIdentifier/doi/10.1007/bf01022350 |
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info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
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openAccess |
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http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
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