Degradation of nonylphenol ethoxylate-9 (NPE-9) by photochemical advanced oxidation technologies

Autores
De La Fuente, Luciana; Acosta, Tatiana; Babay, Paola Alejandra; Curutchet, Gustavo Andres; Candal, Roberto Jorge; Litter, Marta Irene
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The applicability of different photochemical advanced oxidation technologies (PAOTs), namely, direct UV-C photolysis, UV-C/H2O 2 and UV-A/TiO2 heterogeneous photocatalysis (HP), and photo-Fenton reactions (UV-A/H2O2/Fe2+, PF), for the degradation of 300 mg L-1 nonylphenol ethoxylate-9 (NPE-9) in water is described. Different kinetic regimes for each PAOT were found, and as a result, comparative efficiencies could be obtained only from final parameters such as NPE-9 conversion, TOC decrease, and aldehyde production after 3 h of treatment. The initial photonic efficiencies indicate, however, that UV-A processes make better use of photons than UV-C processes. Preliminary optimization of PF systems showed that the most efficient NPE-9/H 2O2/Fe2+ molar ratio was 1:1:0.5. Degradation products were partially investigated. Fortunately, toxic 4-nonylphenol was never found as a byproduct of the degradation after any of the treatments. Aldehydes were formed in all of the processes, but they appeared at a low extent in PF reactions. Therefore, PF treatments were considered to be the best degradation processes. © 2010 American Chemical Society.
Fil: De La Fuente, Luciana. Comisión Nacional de Energía Atómica; Argentina
Fil: Acosta, Tatiana. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: Babay, Paola Alejandra. Comisión Nacional de Energía Atómica; Argentina
Fil: Curutchet, Gustavo Andres. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Universidad Nacional de San Martín. Instituto de Investigación en Ingeniería Ambiental; Argentina
Fil: Candal, Roberto Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Universidad Nacional de San Martín. Instituto de Investigación en Ingeniería Ambiental; Argentina
Fil: Litter, Marta Irene. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación en Ingeniería Ambiental; Argentina
Materia
Photocatalysis
Photolysis
Kinetics
Degradation Products
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/53731
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Degradation of nonylphenol ethoxylate-9 (NPE-9) by photochemical advanced oxidation technologiesDe La Fuente, LucianaAcosta, TatianaBabay, Paola AlejandraCurutchet, Gustavo AndresCandal, Roberto JorgeLitter, Marta IrenePhotocatalysisPhotolysisKineticsDegradation Productshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The applicability of different photochemical advanced oxidation technologies (PAOTs), namely, direct UV-C photolysis, UV-C/H2O 2 and UV-A/TiO2 heterogeneous photocatalysis (HP), and photo-Fenton reactions (UV-A/H2O2/Fe2+, PF), for the degradation of 300 mg L-1 nonylphenol ethoxylate-9 (NPE-9) in water is described. Different kinetic regimes for each PAOT were found, and as a result, comparative efficiencies could be obtained only from final parameters such as NPE-9 conversion, TOC decrease, and aldehyde production after 3 h of treatment. The initial photonic efficiencies indicate, however, that UV-A processes make better use of photons than UV-C processes. Preliminary optimization of PF systems showed that the most efficient NPE-9/H 2O2/Fe2+ molar ratio was 1:1:0.5. Degradation products were partially investigated. Fortunately, toxic 4-nonylphenol was never found as a byproduct of the degradation after any of the treatments. Aldehydes were formed in all of the processes, but they appeared at a low extent in PF reactions. Therefore, PF treatments were considered to be the best degradation processes. © 2010 American Chemical Society.Fil: De La Fuente, Luciana. Comisión Nacional de Energía Atómica; ArgentinaFil: Acosta, Tatiana. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; ArgentinaFil: Babay, Paola Alejandra. Comisión Nacional de Energía Atómica; ArgentinaFil: Curutchet, Gustavo Andres. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Universidad Nacional de San Martín. Instituto de Investigación en Ingeniería Ambiental; ArgentinaFil: Candal, Roberto Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Universidad Nacional de San Martín. Instituto de Investigación en Ingeniería Ambiental; ArgentinaFil: Litter, Marta Irene. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación en Ingeniería Ambiental; ArgentinaAmerican Chemical Society2010-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/53731De La Fuente, Luciana; Acosta, Tatiana; Babay, Paola Alejandra; Curutchet, Gustavo Andres; Candal, Roberto Jorge; et al.; Degradation of nonylphenol ethoxylate-9 (NPE-9) by photochemical advanced oxidation technologies; American Chemical Society; Industrial & Engineering Chemical Research; 49; 15; 8-2010; 6909-69150888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie901785jinfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ie901785jinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:45:06Zoai:ri.conicet.gov.ar:11336/53731instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:45:07.186CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Degradation of nonylphenol ethoxylate-9 (NPE-9) by photochemical advanced oxidation technologies
title Degradation of nonylphenol ethoxylate-9 (NPE-9) by photochemical advanced oxidation technologies
spellingShingle Degradation of nonylphenol ethoxylate-9 (NPE-9) by photochemical advanced oxidation technologies
De La Fuente, Luciana
Photocatalysis
Photolysis
Kinetics
Degradation Products
title_short Degradation of nonylphenol ethoxylate-9 (NPE-9) by photochemical advanced oxidation technologies
title_full Degradation of nonylphenol ethoxylate-9 (NPE-9) by photochemical advanced oxidation technologies
title_fullStr Degradation of nonylphenol ethoxylate-9 (NPE-9) by photochemical advanced oxidation technologies
title_full_unstemmed Degradation of nonylphenol ethoxylate-9 (NPE-9) by photochemical advanced oxidation technologies
title_sort Degradation of nonylphenol ethoxylate-9 (NPE-9) by photochemical advanced oxidation technologies
dc.creator.none.fl_str_mv De La Fuente, Luciana
Acosta, Tatiana
Babay, Paola Alejandra
Curutchet, Gustavo Andres
Candal, Roberto Jorge
Litter, Marta Irene
author De La Fuente, Luciana
author_facet De La Fuente, Luciana
Acosta, Tatiana
Babay, Paola Alejandra
Curutchet, Gustavo Andres
Candal, Roberto Jorge
Litter, Marta Irene
author_role author
author2 Acosta, Tatiana
Babay, Paola Alejandra
Curutchet, Gustavo Andres
Candal, Roberto Jorge
Litter, Marta Irene
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Photocatalysis
Photolysis
Kinetics
Degradation Products
topic Photocatalysis
Photolysis
Kinetics
Degradation Products
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The applicability of different photochemical advanced oxidation technologies (PAOTs), namely, direct UV-C photolysis, UV-C/H2O 2 and UV-A/TiO2 heterogeneous photocatalysis (HP), and photo-Fenton reactions (UV-A/H2O2/Fe2+, PF), for the degradation of 300 mg L-1 nonylphenol ethoxylate-9 (NPE-9) in water is described. Different kinetic regimes for each PAOT were found, and as a result, comparative efficiencies could be obtained only from final parameters such as NPE-9 conversion, TOC decrease, and aldehyde production after 3 h of treatment. The initial photonic efficiencies indicate, however, that UV-A processes make better use of photons than UV-C processes. Preliminary optimization of PF systems showed that the most efficient NPE-9/H 2O2/Fe2+ molar ratio was 1:1:0.5. Degradation products were partially investigated. Fortunately, toxic 4-nonylphenol was never found as a byproduct of the degradation after any of the treatments. Aldehydes were formed in all of the processes, but they appeared at a low extent in PF reactions. Therefore, PF treatments were considered to be the best degradation processes. © 2010 American Chemical Society.
Fil: De La Fuente, Luciana. Comisión Nacional de Energía Atómica; Argentina
Fil: Acosta, Tatiana. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: Babay, Paola Alejandra. Comisión Nacional de Energía Atómica; Argentina
Fil: Curutchet, Gustavo Andres. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Universidad Nacional de San Martín. Instituto de Investigación en Ingeniería Ambiental; Argentina
Fil: Candal, Roberto Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Universidad Nacional de San Martín. Instituto de Investigación en Ingeniería Ambiental; Argentina
Fil: Litter, Marta Irene. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación en Ingeniería Ambiental; Argentina
description The applicability of different photochemical advanced oxidation technologies (PAOTs), namely, direct UV-C photolysis, UV-C/H2O 2 and UV-A/TiO2 heterogeneous photocatalysis (HP), and photo-Fenton reactions (UV-A/H2O2/Fe2+, PF), for the degradation of 300 mg L-1 nonylphenol ethoxylate-9 (NPE-9) in water is described. Different kinetic regimes for each PAOT were found, and as a result, comparative efficiencies could be obtained only from final parameters such as NPE-9 conversion, TOC decrease, and aldehyde production after 3 h of treatment. The initial photonic efficiencies indicate, however, that UV-A processes make better use of photons than UV-C processes. Preliminary optimization of PF systems showed that the most efficient NPE-9/H 2O2/Fe2+ molar ratio was 1:1:0.5. Degradation products were partially investigated. Fortunately, toxic 4-nonylphenol was never found as a byproduct of the degradation after any of the treatments. Aldehydes were formed in all of the processes, but they appeared at a low extent in PF reactions. Therefore, PF treatments were considered to be the best degradation processes. © 2010 American Chemical Society.
publishDate 2010
dc.date.none.fl_str_mv 2010-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/53731
De La Fuente, Luciana; Acosta, Tatiana; Babay, Paola Alejandra; Curutchet, Gustavo Andres; Candal, Roberto Jorge; et al.; Degradation of nonylphenol ethoxylate-9 (NPE-9) by photochemical advanced oxidation technologies; American Chemical Society; Industrial & Engineering Chemical Research; 49; 15; 8-2010; 6909-6915
0888-5885
CONICET Digital
CONICET
url http://hdl.handle.net/11336/53731
identifier_str_mv De La Fuente, Luciana; Acosta, Tatiana; Babay, Paola Alejandra; Curutchet, Gustavo Andres; Candal, Roberto Jorge; et al.; Degradation of nonylphenol ethoxylate-9 (NPE-9) by photochemical advanced oxidation technologies; American Chemical Society; Industrial & Engineering Chemical Research; 49; 15; 8-2010; 6909-6915
0888-5885
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ie901785j
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ie901785j
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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