Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex
- Autores
- Izquierdo, D.; Ferraresi Curotto, Verónica; Heras, A.; Pis Diez, Reinaldo; González Baró, Ana Cecilia; Colina, A.
- Año de publicación
- 2017
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A new bidimensional spectroelectrochemistry setup for UV-Vis absorption measurements has been developed. The new device has been used to follow electrochemical reactions using two different arrangements: 1) a near-normal configuration that supplies information about the processes taking place both on the electrode surface and in the solution adjacent to it, and 2) a long-optical-pathway configuration based on a mobile slit that controls the position of a light beam passing parallel and adjacent to the electrode surface providing information only about the processes taking place in solution during the electrochemical reaction. The new setup has been validated using o-tolidine, a typical reference system for spectroelectrochemistry. The electrochemical mechanism of oxidation/reduction of Cu(o-Va)2(H2O)2 complex (o-Va = o-Vanillin = 2-hydroxy-3-methoxybenzaldehyde) has been studied using bidimensional UV-Vis absorption spectroelectrochemistry. This Cu(II) complex exhibits antimutagenic, anticarcinogenic and superoxide dismutase mimic properties.
Centro de Química Inorgánica - Materia
-
Química
spectroelectrochemistry
electrochemistry
copper
reaction mechanism - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/152749
Ver los metadatos del registro completo
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Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complexIzquierdo, D.Ferraresi Curotto, VerónicaHeras, A.Pis Diez, ReinaldoGonzález Baró, Ana CeciliaColina, A.Químicaspectroelectrochemistryelectrochemistrycopperreaction mechanismA new bidimensional spectroelectrochemistry setup for UV-Vis absorption measurements has been developed. The new device has been used to follow electrochemical reactions using two different arrangements: 1) a near-normal configuration that supplies information about the processes taking place both on the electrode surface and in the solution adjacent to it, and 2) a long-optical-pathway configuration based on a mobile slit that controls the position of a light beam passing parallel and adjacent to the electrode surface providing information only about the processes taking place in solution during the electrochemical reaction. The new setup has been validated using o-tolidine, a typical reference system for spectroelectrochemistry. The electrochemical mechanism of oxidation/reduction of Cu(o-Va)2(H2O)2 complex (o-Va = o-Vanillin = 2-hydroxy-3-methoxybenzaldehyde) has been studied using bidimensional UV-Vis absorption spectroelectrochemistry. This Cu(II) complex exhibits antimutagenic, anticarcinogenic and superoxide dismutase mimic properties.Centro de Química Inorgánica2017info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf79-87http://sedici.unlp.edu.ar/handle/10915/152749enginfo:eu-repo/semantics/altIdentifier/issn/0013-4686info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2017.05.105info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:39:32Zoai:sedici.unlp.edu.ar:10915/152749Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:39:32.677SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex |
title |
Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex |
spellingShingle |
Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex Izquierdo, D. Química spectroelectrochemistry electrochemistry copper reaction mechanism |
title_short |
Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex |
title_full |
Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex |
title_fullStr |
Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex |
title_full_unstemmed |
Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex |
title_sort |
Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex |
dc.creator.none.fl_str_mv |
Izquierdo, D. Ferraresi Curotto, Verónica Heras, A. Pis Diez, Reinaldo González Baró, Ana Cecilia Colina, A. |
author |
Izquierdo, D. |
author_facet |
Izquierdo, D. Ferraresi Curotto, Verónica Heras, A. Pis Diez, Reinaldo González Baró, Ana Cecilia Colina, A. |
author_role |
author |
author2 |
Ferraresi Curotto, Verónica Heras, A. Pis Diez, Reinaldo González Baró, Ana Cecilia Colina, A. |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
Química spectroelectrochemistry electrochemistry copper reaction mechanism |
topic |
Química spectroelectrochemistry electrochemistry copper reaction mechanism |
dc.description.none.fl_txt_mv |
A new bidimensional spectroelectrochemistry setup for UV-Vis absorption measurements has been developed. The new device has been used to follow electrochemical reactions using two different arrangements: 1) a near-normal configuration that supplies information about the processes taking place both on the electrode surface and in the solution adjacent to it, and 2) a long-optical-pathway configuration based on a mobile slit that controls the position of a light beam passing parallel and adjacent to the electrode surface providing information only about the processes taking place in solution during the electrochemical reaction. The new setup has been validated using o-tolidine, a typical reference system for spectroelectrochemistry. The electrochemical mechanism of oxidation/reduction of Cu(o-Va)2(H2O)2 complex (o-Va = o-Vanillin = 2-hydroxy-3-methoxybenzaldehyde) has been studied using bidimensional UV-Vis absorption spectroelectrochemistry. This Cu(II) complex exhibits antimutagenic, anticarcinogenic and superoxide dismutase mimic properties. Centro de Química Inorgánica |
description |
A new bidimensional spectroelectrochemistry setup for UV-Vis absorption measurements has been developed. The new device has been used to follow electrochemical reactions using two different arrangements: 1) a near-normal configuration that supplies information about the processes taking place both on the electrode surface and in the solution adjacent to it, and 2) a long-optical-pathway configuration based on a mobile slit that controls the position of a light beam passing parallel and adjacent to the electrode surface providing information only about the processes taking place in solution during the electrochemical reaction. The new setup has been validated using o-tolidine, a typical reference system for spectroelectrochemistry. The electrochemical mechanism of oxidation/reduction of Cu(o-Va)2(H2O)2 complex (o-Va = o-Vanillin = 2-hydroxy-3-methoxybenzaldehyde) has been studied using bidimensional UV-Vis absorption spectroelectrochemistry. This Cu(II) complex exhibits antimutagenic, anticarcinogenic and superoxide dismutase mimic properties. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/152749 |
url |
http://sedici.unlp.edu.ar/handle/10915/152749 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/0013-4686 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2017.05.105 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
dc.format.none.fl_str_mv |
application/pdf 79-87 |
dc.source.none.fl_str_mv |
reponame:SEDICI (UNLP) instname:Universidad Nacional de La Plata instacron:UNLP |
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Universidad Nacional de La Plata |
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SEDICI (UNLP) - Universidad Nacional de La Plata |
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alira@sedici.unlp.edu.ar |
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