Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex

Autores
Izquierdo, D.; Ferraresi Curotto, Verónica; Heras, A.; Pis Diez, Reinaldo; González Baró, Ana Cecilia; Colina, A.
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A new bidimensional spectroelectrochemistry setup for UV-Vis absorption measurements has been developed. The new device has been used to follow electrochemical reactions using two different arrangements: 1) a near-normal configuration that supplies information about the processes taking place both on the electrode surface and in the solution adjacent to it, and 2) a long-optical-pathway configuration based on a mobile slit that controls the position of a light beam passing parallel and adjacent to the electrode surface providing information only about the processes taking place in solution during the electrochemical reaction. The new setup has been validated using o-tolidine, a typical reference system for spectroelectrochemistry. The electrochemical mechanism of oxidation/reduction of Cu(o-Va)2(H2O)2 complex (o-Va = o-Vanillin = 2-hydroxy-3-methoxybenzaldehyde) has been studied using bidimensional UV-Vis absorption spectroelectrochemistry. This Cu(II) complex exhibits antimutagenic, anticarcinogenic and superoxide dismutase mimic properties.
Centro de Química Inorgánica
Materia
Química
spectroelectrochemistry
electrochemistry
copper
reaction mechanism
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/152749
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/152749
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complexIzquierdo, D.Ferraresi Curotto, VerónicaHeras, A.Pis Diez, ReinaldoGonzález Baró, Ana CeciliaColina, A.Químicaspectroelectrochemistryelectrochemistrycopperreaction mechanismA new bidimensional spectroelectrochemistry setup for UV-Vis absorption measurements has been developed. The new device has been used to follow electrochemical reactions using two different arrangements: 1) a near-normal configuration that supplies information about the processes taking place both on the electrode surface and in the solution adjacent to it, and 2) a long-optical-pathway configuration based on a mobile slit that controls the position of a light beam passing parallel and adjacent to the electrode surface providing information only about the processes taking place in solution during the electrochemical reaction. The new setup has been validated using o-tolidine, a typical reference system for spectroelectrochemistry. The electrochemical mechanism of oxidation/reduction of Cu(o-Va)2(H2O)2 complex (o-Va = o-Vanillin = 2-hydroxy-3-methoxybenzaldehyde) has been studied using bidimensional UV-Vis absorption spectroelectrochemistry. This Cu(II) complex exhibits antimutagenic, anticarcinogenic and superoxide dismutase mimic properties.Centro de Química Inorgánica2017info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf79-87http://sedici.unlp.edu.ar/handle/10915/152749enginfo:eu-repo/semantics/altIdentifier/issn/0013-4686info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2017.05.105info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-15T11:31:19Zoai:sedici.unlp.edu.ar:10915/152749Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-15 11:31:19.923SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex
title Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex
spellingShingle Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex
Izquierdo, D.
Química
spectroelectrochemistry
electrochemistry
copper
reaction mechanism
title_short Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex
title_full Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex
title_fullStr Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex
title_full_unstemmed Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex
title_sort Bidimensional Spectroelectrochemistry: application of a new device in the study of a o-vanillin-copper(II) complex
dc.creator.none.fl_str_mv Izquierdo, D.
Ferraresi Curotto, Verónica
Heras, A.
Pis Diez, Reinaldo
González Baró, Ana Cecilia
Colina, A.
author Izquierdo, D.
author_facet Izquierdo, D.
Ferraresi Curotto, Verónica
Heras, A.
Pis Diez, Reinaldo
González Baró, Ana Cecilia
Colina, A.
author_role author
author2 Ferraresi Curotto, Verónica
Heras, A.
Pis Diez, Reinaldo
González Baró, Ana Cecilia
Colina, A.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Química
spectroelectrochemistry
electrochemistry
copper
reaction mechanism
topic Química
spectroelectrochemistry
electrochemistry
copper
reaction mechanism
dc.description.none.fl_txt_mv A new bidimensional spectroelectrochemistry setup for UV-Vis absorption measurements has been developed. The new device has been used to follow electrochemical reactions using two different arrangements: 1) a near-normal configuration that supplies information about the processes taking place both on the electrode surface and in the solution adjacent to it, and 2) a long-optical-pathway configuration based on a mobile slit that controls the position of a light beam passing parallel and adjacent to the electrode surface providing information only about the processes taking place in solution during the electrochemical reaction. The new setup has been validated using o-tolidine, a typical reference system for spectroelectrochemistry. The electrochemical mechanism of oxidation/reduction of Cu(o-Va)2(H2O)2 complex (o-Va = o-Vanillin = 2-hydroxy-3-methoxybenzaldehyde) has been studied using bidimensional UV-Vis absorption spectroelectrochemistry. This Cu(II) complex exhibits antimutagenic, anticarcinogenic and superoxide dismutase mimic properties.
Centro de Química Inorgánica
description A new bidimensional spectroelectrochemistry setup for UV-Vis absorption measurements has been developed. The new device has been used to follow electrochemical reactions using two different arrangements: 1) a near-normal configuration that supplies information about the processes taking place both on the electrode surface and in the solution adjacent to it, and 2) a long-optical-pathway configuration based on a mobile slit that controls the position of a light beam passing parallel and adjacent to the electrode surface providing information only about the processes taking place in solution during the electrochemical reaction. The new setup has been validated using o-tolidine, a typical reference system for spectroelectrochemistry. The electrochemical mechanism of oxidation/reduction of Cu(o-Va)2(H2O)2 complex (o-Va = o-Vanillin = 2-hydroxy-3-methoxybenzaldehyde) has been studied using bidimensional UV-Vis absorption spectroelectrochemistry. This Cu(II) complex exhibits antimutagenic, anticarcinogenic and superoxide dismutase mimic properties.
publishDate 2017
dc.date.none.fl_str_mv 2017
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/152749
url http://sedici.unlp.edu.ar/handle/10915/152749
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0013-4686
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2017.05.105
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
79-87
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.22299

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