Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer

Autores
Lezna, Reynaldo Oscar; Romagnoli, Roberto; Tacconi, Norma R. de; Rajeshwar, Krishnan
Año de publicación
2002
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The cobalt hexacyanoferrate system, Mh [FeB(CN)6]l, (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex situ X-ray photoelectron spectroscopy.
Centro de Investigación y Desarrollo en Tecnología de Pinturas
Materia
Química
cobalt
spectroelectrochemistry
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-nd/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/170893
Acceder
id SEDICI_2b4524076c3b8d7491ebff45f4be7803
oai_identifier_str oai:sedici.unlp.edu.ar:10915/170893
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transferLezna, Reynaldo OscarRomagnoli, RobertoTacconi, Norma R. deRajeshwar, KrishnanQuímicacobaltspectroelectrochemistryThe cobalt hexacyanoferrate system, Mh [FeB(CN)6]l, (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex situ X-ray photoelectron spectroscopy.Centro de Investigación y Desarrollo en Tecnología de Pinturas2002info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf3612-3621http://sedici.unlp.edu.ar/handle/10915/170893enginfo:eu-repo/semantics/altIdentifier/doi/10.1021/jp013991rinfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:45:26Zoai:sedici.unlp.edu.ar:10915/170893Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:45:26.339SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer
title Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer
spellingShingle Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer
Lezna, Reynaldo Oscar
Química
cobalt
spectroelectrochemistry
title_short Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer
title_full Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer
title_fullStr Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer
title_full_unstemmed Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer
title_sort Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer
dc.creator.none.fl_str_mv Lezna, Reynaldo Oscar
Romagnoli, Roberto
Tacconi, Norma R. de
Rajeshwar, Krishnan
author Lezna, Reynaldo Oscar
author_facet Lezna, Reynaldo Oscar
Romagnoli, Roberto
Tacconi, Norma R. de
Rajeshwar, Krishnan
author_role author
author2 Romagnoli, Roberto
Tacconi, Norma R. de
Rajeshwar, Krishnan
author2_role author
author
author
dc.subject.none.fl_str_mv Química
cobalt
spectroelectrochemistry
topic Química
cobalt
spectroelectrochemistry
dc.description.none.fl_txt_mv The cobalt hexacyanoferrate system, Mh [FeB(CN)6]l, (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex situ X-ray photoelectron spectroscopy.
Centro de Investigación y Desarrollo en Tecnología de Pinturas
description The cobalt hexacyanoferrate system, Mh [FeB(CN)6]l, (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex situ X-ray photoelectron spectroscopy.
publishDate 2002
dc.date.none.fl_str_mv 2002
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/170893
url http://sedici.unlp.edu.ar/handle/10915/170893
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/jp013991r
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
dc.format.none.fl_str_mv application/pdf
3612-3621
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
_version_ 1844616320288555008
score 13.070432

Publicaciones similares