Heterogeneous Charge Mobility in Individual Conjugated Polyelectrolyte Nanoparticles Revealed by Two-Color Single Particle Spectroelectrochemistry Studies

Autores
Godin, Robert; Palacios, Rodrigo Emiliano; Cosa, Gonzalo
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The optoelectronic properties of conjugated polymers and conjugated polyelectrolytes (CPEs) depend on their chain conformation and packing. Correlations between emission color, charge mobility, and extent of aggregation in these materials have been previously established from bulk studies. Here we describe the preparation of stable nanoparticle suspensions of the CPE poly[5-methoxy-2-(3-sulfopropoxy)-1,4-phenylenevinylene (MPS-PPV) where changes in the solvent composition enable tuning their emission spectra and quantum yield. By employing a newly developed color-sensitive single-molecule spectroelectrochemistry (SMS-EC) technique, the effect of chain conformation on the optoelectronic properties of MPS-PPV nanoparticles is monitored at the single particle level. Within a single particle the photoluminescence and redox response is chromatically correlated reflecting on the differing contributions that coiled and deaggregated vs extended and packed segments have on their optoelectronic properties. We also observe a heterogeneous response among nanoparticles to externally applied electrochemical potentials, which further correlates with their emission color (chain packing). We rationalize our observations on differential charge injection, energy and charge transport, and ion migration as a consequence of chain conformation, packing effects, and the presence of electrochemically reducible quenching sites. Our work provides a way to unravel the intrinsic heterogeneity of CPE materials to better understand the relationship between chain conformation and optoelectronic properties.
Fil: Godin, Robert. McGill University; Canadá
Fil: Palacios, Rodrigo Emiliano. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Cosa, Gonzalo. McGill University; Canadá
Materia
CONJUGATED POLYMERS
CHARGE MOBILITY
SINGLE MOLECULE SPECTROELECTROCHEMISTRY
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/61530
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Heterogeneous Charge Mobility in Individual Conjugated Polyelectrolyte Nanoparticles Revealed by Two-Color Single Particle Spectroelectrochemistry StudiesGodin, RobertPalacios, Rodrigo EmilianoCosa, GonzaloCONJUGATED POLYMERSCHARGE MOBILITYSINGLE MOLECULE SPECTROELECTROCHEMISTRYhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The optoelectronic properties of conjugated polymers and conjugated polyelectrolytes (CPEs) depend on their chain conformation and packing. Correlations between emission color, charge mobility, and extent of aggregation in these materials have been previously established from bulk studies. Here we describe the preparation of stable nanoparticle suspensions of the CPE poly[5-methoxy-2-(3-sulfopropoxy)-1,4-phenylenevinylene (MPS-PPV) where changes in the solvent composition enable tuning their emission spectra and quantum yield. By employing a newly developed color-sensitive single-molecule spectroelectrochemistry (SMS-EC) technique, the effect of chain conformation on the optoelectronic properties of MPS-PPV nanoparticles is monitored at the single particle level. Within a single particle the photoluminescence and redox response is chromatically correlated reflecting on the differing contributions that coiled and deaggregated vs extended and packed segments have on their optoelectronic properties. We also observe a heterogeneous response among nanoparticles to externally applied electrochemical potentials, which further correlates with their emission color (chain packing). We rationalize our observations on differential charge injection, energy and charge transport, and ion migration as a consequence of chain conformation, packing effects, and the presence of electrochemically reducible quenching sites. Our work provides a way to unravel the intrinsic heterogeneity of CPE materials to better understand the relationship between chain conformation and optoelectronic properties.Fil: Godin, Robert. McGill University; CanadáFil: Palacios, Rodrigo Emiliano. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaFil: Cosa, Gonzalo. McGill University; CanadáAmerican Chemical Society2015-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/61530Godin, Robert; Palacios, Rodrigo Emiliano; Cosa, Gonzalo; Heterogeneous Charge Mobility in Individual Conjugated Polyelectrolyte Nanoparticles Revealed by Two-Color Single Particle Spectroelectrochemistry Studies; American Chemical Society; Journal of Physical Chemistry C; 119; 23; 6-2015; 12875-128861932-74471932-7455CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/acs.jpcc.5b03491info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.5b03491info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:12:24Zoai:ri.conicet.gov.ar:11336/61530instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:12:24.225CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Heterogeneous Charge Mobility in Individual Conjugated Polyelectrolyte Nanoparticles Revealed by Two-Color Single Particle Spectroelectrochemistry Studies
title Heterogeneous Charge Mobility in Individual Conjugated Polyelectrolyte Nanoparticles Revealed by Two-Color Single Particle Spectroelectrochemistry Studies
spellingShingle Heterogeneous Charge Mobility in Individual Conjugated Polyelectrolyte Nanoparticles Revealed by Two-Color Single Particle Spectroelectrochemistry Studies
Godin, Robert
CONJUGATED POLYMERS
CHARGE MOBILITY
SINGLE MOLECULE SPECTROELECTROCHEMISTRY
title_short Heterogeneous Charge Mobility in Individual Conjugated Polyelectrolyte Nanoparticles Revealed by Two-Color Single Particle Spectroelectrochemistry Studies
title_full Heterogeneous Charge Mobility in Individual Conjugated Polyelectrolyte Nanoparticles Revealed by Two-Color Single Particle Spectroelectrochemistry Studies
title_fullStr Heterogeneous Charge Mobility in Individual Conjugated Polyelectrolyte Nanoparticles Revealed by Two-Color Single Particle Spectroelectrochemistry Studies
title_full_unstemmed Heterogeneous Charge Mobility in Individual Conjugated Polyelectrolyte Nanoparticles Revealed by Two-Color Single Particle Spectroelectrochemistry Studies
title_sort Heterogeneous Charge Mobility in Individual Conjugated Polyelectrolyte Nanoparticles Revealed by Two-Color Single Particle Spectroelectrochemistry Studies
dc.creator.none.fl_str_mv Godin, Robert
Palacios, Rodrigo Emiliano
Cosa, Gonzalo
author Godin, Robert
author_facet Godin, Robert
Palacios, Rodrigo Emiliano
Cosa, Gonzalo
author_role author
author2 Palacios, Rodrigo Emiliano
Cosa, Gonzalo
author2_role author
author
dc.subject.none.fl_str_mv CONJUGATED POLYMERS
CHARGE MOBILITY
SINGLE MOLECULE SPECTROELECTROCHEMISTRY
topic CONJUGATED POLYMERS
CHARGE MOBILITY
SINGLE MOLECULE SPECTROELECTROCHEMISTRY
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The optoelectronic properties of conjugated polymers and conjugated polyelectrolytes (CPEs) depend on their chain conformation and packing. Correlations between emission color, charge mobility, and extent of aggregation in these materials have been previously established from bulk studies. Here we describe the preparation of stable nanoparticle suspensions of the CPE poly[5-methoxy-2-(3-sulfopropoxy)-1,4-phenylenevinylene (MPS-PPV) where changes in the solvent composition enable tuning their emission spectra and quantum yield. By employing a newly developed color-sensitive single-molecule spectroelectrochemistry (SMS-EC) technique, the effect of chain conformation on the optoelectronic properties of MPS-PPV nanoparticles is monitored at the single particle level. Within a single particle the photoluminescence and redox response is chromatically correlated reflecting on the differing contributions that coiled and deaggregated vs extended and packed segments have on their optoelectronic properties. We also observe a heterogeneous response among nanoparticles to externally applied electrochemical potentials, which further correlates with their emission color (chain packing). We rationalize our observations on differential charge injection, energy and charge transport, and ion migration as a consequence of chain conformation, packing effects, and the presence of electrochemically reducible quenching sites. Our work provides a way to unravel the intrinsic heterogeneity of CPE materials to better understand the relationship between chain conformation and optoelectronic properties.
Fil: Godin, Robert. McGill University; Canadá
Fil: Palacios, Rodrigo Emiliano. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Cosa, Gonzalo. McGill University; Canadá
description The optoelectronic properties of conjugated polymers and conjugated polyelectrolytes (CPEs) depend on their chain conformation and packing. Correlations between emission color, charge mobility, and extent of aggregation in these materials have been previously established from bulk studies. Here we describe the preparation of stable nanoparticle suspensions of the CPE poly[5-methoxy-2-(3-sulfopropoxy)-1,4-phenylenevinylene (MPS-PPV) where changes in the solvent composition enable tuning their emission spectra and quantum yield. By employing a newly developed color-sensitive single-molecule spectroelectrochemistry (SMS-EC) technique, the effect of chain conformation on the optoelectronic properties of MPS-PPV nanoparticles is monitored at the single particle level. Within a single particle the photoluminescence and redox response is chromatically correlated reflecting on the differing contributions that coiled and deaggregated vs extended and packed segments have on their optoelectronic properties. We also observe a heterogeneous response among nanoparticles to externally applied electrochemical potentials, which further correlates with their emission color (chain packing). We rationalize our observations on differential charge injection, energy and charge transport, and ion migration as a consequence of chain conformation, packing effects, and the presence of electrochemically reducible quenching sites. Our work provides a way to unravel the intrinsic heterogeneity of CPE materials to better understand the relationship between chain conformation and optoelectronic properties.
publishDate 2015
dc.date.none.fl_str_mv 2015-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/61530
Godin, Robert; Palacios, Rodrigo Emiliano; Cosa, Gonzalo; Heterogeneous Charge Mobility in Individual Conjugated Polyelectrolyte Nanoparticles Revealed by Two-Color Single Particle Spectroelectrochemistry Studies; American Chemical Society; Journal of Physical Chemistry C; 119; 23; 6-2015; 12875-12886
1932-7447
1932-7455
CONICET Digital
CONICET
url http://hdl.handle.net/11336/61530
identifier_str_mv Godin, Robert; Palacios, Rodrigo Emiliano; Cosa, Gonzalo; Heterogeneous Charge Mobility in Individual Conjugated Polyelectrolyte Nanoparticles Revealed by Two-Color Single Particle Spectroelectrochemistry Studies; American Chemical Society; Journal of Physical Chemistry C; 119; 23; 6-2015; 12875-12886
1932-7447
1932-7455
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/acs.jpcc.5b03491
info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.5b03491
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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