A Polyvinylpyrrolidone Nanofibrous Sensor Doubly Decorated with Mesoporous Graphene to Selectively Detect Acetic Acid Vapors
- Autores
- Papa, Paolo; Zampetti, Emiliano; Molinari, Fabricio Nicolás; De Cesare, Fabrizio; Di Natale, Corrado; Tranfo, Giovanna; Macagnano, Antonella
- Año de publicación
- 2024
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- An original approach has been proposed for designing a nanofibrous (NF) layer using UVcured polyvinylpyrrolidone (PVP) as a matrix, incorporating mesoporous graphene carbon (MGC) nanopowder both inside and outside the fibers, creating a sandwich-like structure. This architecture is intended to selectively adsorb and detect acetic acid vapors, which are known to cause health issues in exposed workers. The nanocomposite MGC-PVP-NFs layer was fabricated through electrospinning deposition onto interdigitated microelectrodes (IDEs) and stabilized under UV–light irradiation. To enhance the adhesion of MGC onto the surface of the nanocomposite polymeric fibers, the layer was dipped in a suspension of polyethyleneimine (PEI) and MGC. The resulting structure demonstrated promising electrical and sensing properties, including rapid responses, high sensitivity, good linearity, reversibility, repeatability, and selectivity towards acetic acid vapors. Initial testing was conducted in a laboratory using a bench electrometer, followed by validation in a portable sensing device based on consumer electronic components (by ARDUINO®). This portable system was designed to provide a compact, cost-effective solution with high sensing capabilities. Under room temperature and ambient air conditions, both laboratory and portable tests exhibited favorable linear responses, with detection limits of 0.16 and 1 ppm, respectively.
Fil: Papa, Paolo. Consiglio Nazionale delle Ricerche. Istituto sull'Inquinamento Atmosferico (CNR-IIA); Italia
Fil: Zampetti, Emiliano. Consiglio Nazionale delle Ricerche. Istituto sull'Inquinamento Atmosferico (CNR-IIA); Italia
Fil: Molinari, Fabricio Nicolás. Instituto Nacional de Tecnología Industrial. Textiles (INTI-Textiles); Argentina
Fil: Molinari, Fabricio Nicolás. Consiglio Nazionale delle Ricerche. Istituto sull'Inquinamento Atmosferico (CNR-IIA); Italia
Fil: De Cesare, Fabrizio. Consiglio Nazionale delle Ricerche. Istituto sull'Inquinamento Atmosferico (CNR-IIA); Italia
Fil: De Cesare, Fabrizio. Università degli Studi della Tuscia (UNITUS); Italia
Fil: Di Natale, Corrado. Università degli Studi di Roma Tor Vergata. Dipartimento di Ingegneria Elettronica (UniRoma2); Italia
Fil: Tranfo, Giovanna. Ministero delle infrastrutture e dei trasporti. Dipartimento di Medicina, Epidemiologia, Igiene del Lavoro ed Ambientale (DIMEILA-INAIL); Italia
Fil: Macagnano, Antonella. Consiglio Nazionale delle Ricerche. Istituto sull'Inquinamento Atmosferico (CNR-IIA); Italia - Fuente
- Sensors 2024, 24(7), 2174
- Materia
-
Sensores
Nanofibras
Vapor - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by/4.0/
- Repositorio
- Institución
- Instituto Nacional de Tecnología Industrial
- OAI Identificador
- nuevadc:2025PapaPaolo_pdf
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A Polyvinylpyrrolidone Nanofibrous Sensor Doubly Decorated with Mesoporous Graphene to Selectively Detect Acetic Acid VaporsPapa, PaoloZampetti, EmilianoMolinari, Fabricio NicolásDe Cesare, FabrizioDi Natale, CorradoTranfo, GiovannaMacagnano, AntonellaSensoresNanofibrasVaporAn original approach has been proposed for designing a nanofibrous (NF) layer using UVcured polyvinylpyrrolidone (PVP) as a matrix, incorporating mesoporous graphene carbon (MGC) nanopowder both inside and outside the fibers, creating a sandwich-like structure. This architecture is intended to selectively adsorb and detect acetic acid vapors, which are known to cause health issues in exposed workers. The nanocomposite MGC-PVP-NFs layer was fabricated through electrospinning deposition onto interdigitated microelectrodes (IDEs) and stabilized under UV–light irradiation. To enhance the adhesion of MGC onto the surface of the nanocomposite polymeric fibers, the layer was dipped in a suspension of polyethyleneimine (PEI) and MGC. The resulting structure demonstrated promising electrical and sensing properties, including rapid responses, high sensitivity, good linearity, reversibility, repeatability, and selectivity towards acetic acid vapors. Initial testing was conducted in a laboratory using a bench electrometer, followed by validation in a portable sensing device based on consumer electronic components (by ARDUINO®). This portable system was designed to provide a compact, cost-effective solution with high sensing capabilities. Under room temperature and ambient air conditions, both laboratory and portable tests exhibited favorable linear responses, with detection limits of 0.16 and 1 ppm, respectively.Fil: Papa, Paolo. Consiglio Nazionale delle Ricerche. Istituto sull'Inquinamento Atmosferico (CNR-IIA); ItaliaFil: Zampetti, Emiliano. Consiglio Nazionale delle Ricerche. Istituto sull'Inquinamento Atmosferico (CNR-IIA); ItaliaFil: Molinari, Fabricio Nicolás. Instituto Nacional de Tecnología Industrial. Textiles (INTI-Textiles); ArgentinaFil: Molinari, Fabricio Nicolás. Consiglio Nazionale delle Ricerche. Istituto sull'Inquinamento Atmosferico (CNR-IIA); ItaliaFil: De Cesare, Fabrizio. Consiglio Nazionale delle Ricerche. Istituto sull'Inquinamento Atmosferico (CNR-IIA); ItaliaFil: De Cesare, Fabrizio. Università degli Studi della Tuscia (UNITUS); ItaliaFil: Di Natale, Corrado. Università degli Studi di Roma Tor Vergata. Dipartimento di Ingegneria Elettronica (UniRoma2); ItaliaFil: Tranfo, Giovanna. Ministero delle infrastrutture e dei trasporti. Dipartimento di Medicina, Epidemiologia, Igiene del Lavoro ed Ambientale (DIMEILA-INAIL); ItaliaFil: Macagnano, Antonella. Consiglio Nazionale delle Ricerche. Istituto sull'Inquinamento Atmosferico (CNR-IIA); ItaliaMDPI2024info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf2025PapaPaolo.pdfhttps://app.inti.gob.ar/greenstone3/sites/localsite/collect/nuevadc/index/assoc/2025Papa/Paolo_pd.dir/doc.pdfSensors 2024, 24(7), 2174reponame:Repositorio Institucional del Instituto Nacional de Tecnología Industrial (INTI)instname:Instituto Nacional de Tecnología Industrialenginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/4.0/openAccess2025-09-29T15:02:07Znuevadc:2025PapaPaolo_pdfinstacron:INTIInstitucionalhttps://app.inti.gob.ar/greenstone3/biblioOrganismo científico-tecnológicohttps://argentina.gob.ar/intihttps://app.inti.gob.ar/greenstone3/oaiserver?verb=Identifypfalcato@inti.gob.arArgentinaopendoar:2025-09-29 15:02:08.239Repositorio Institucional del Instituto Nacional de Tecnología Industrial (INTI) - Instituto Nacional de Tecnología Industrialfalse |
dc.title.none.fl_str_mv |
A Polyvinylpyrrolidone Nanofibrous Sensor Doubly Decorated with Mesoporous Graphene to Selectively Detect Acetic Acid Vapors |
title |
A Polyvinylpyrrolidone Nanofibrous Sensor Doubly Decorated with Mesoporous Graphene to Selectively Detect Acetic Acid Vapors |
spellingShingle |
A Polyvinylpyrrolidone Nanofibrous Sensor Doubly Decorated with Mesoporous Graphene to Selectively Detect Acetic Acid Vapors Papa, Paolo Sensores Nanofibras Vapor |
title_short |
A Polyvinylpyrrolidone Nanofibrous Sensor Doubly Decorated with Mesoporous Graphene to Selectively Detect Acetic Acid Vapors |
title_full |
A Polyvinylpyrrolidone Nanofibrous Sensor Doubly Decorated with Mesoporous Graphene to Selectively Detect Acetic Acid Vapors |
title_fullStr |
A Polyvinylpyrrolidone Nanofibrous Sensor Doubly Decorated with Mesoporous Graphene to Selectively Detect Acetic Acid Vapors |
title_full_unstemmed |
A Polyvinylpyrrolidone Nanofibrous Sensor Doubly Decorated with Mesoporous Graphene to Selectively Detect Acetic Acid Vapors |
title_sort |
A Polyvinylpyrrolidone Nanofibrous Sensor Doubly Decorated with Mesoporous Graphene to Selectively Detect Acetic Acid Vapors |
dc.creator.none.fl_str_mv |
Papa, Paolo Zampetti, Emiliano Molinari, Fabricio Nicolás De Cesare, Fabrizio Di Natale, Corrado Tranfo, Giovanna Macagnano, Antonella |
author |
Papa, Paolo |
author_facet |
Papa, Paolo Zampetti, Emiliano Molinari, Fabricio Nicolás De Cesare, Fabrizio Di Natale, Corrado Tranfo, Giovanna Macagnano, Antonella |
author_role |
author |
author2 |
Zampetti, Emiliano Molinari, Fabricio Nicolás De Cesare, Fabrizio Di Natale, Corrado Tranfo, Giovanna Macagnano, Antonella |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
Sensores Nanofibras Vapor |
topic |
Sensores Nanofibras Vapor |
dc.description.none.fl_txt_mv |
An original approach has been proposed for designing a nanofibrous (NF) layer using UVcured polyvinylpyrrolidone (PVP) as a matrix, incorporating mesoporous graphene carbon (MGC) nanopowder both inside and outside the fibers, creating a sandwich-like structure. This architecture is intended to selectively adsorb and detect acetic acid vapors, which are known to cause health issues in exposed workers. The nanocomposite MGC-PVP-NFs layer was fabricated through electrospinning deposition onto interdigitated microelectrodes (IDEs) and stabilized under UV–light irradiation. To enhance the adhesion of MGC onto the surface of the nanocomposite polymeric fibers, the layer was dipped in a suspension of polyethyleneimine (PEI) and MGC. The resulting structure demonstrated promising electrical and sensing properties, including rapid responses, high sensitivity, good linearity, reversibility, repeatability, and selectivity towards acetic acid vapors. Initial testing was conducted in a laboratory using a bench electrometer, followed by validation in a portable sensing device based on consumer electronic components (by ARDUINO®). This portable system was designed to provide a compact, cost-effective solution with high sensing capabilities. Under room temperature and ambient air conditions, both laboratory and portable tests exhibited favorable linear responses, with detection limits of 0.16 and 1 ppm, respectively. Fil: Papa, Paolo. Consiglio Nazionale delle Ricerche. Istituto sull'Inquinamento Atmosferico (CNR-IIA); Italia Fil: Zampetti, Emiliano. Consiglio Nazionale delle Ricerche. Istituto sull'Inquinamento Atmosferico (CNR-IIA); Italia Fil: Molinari, Fabricio Nicolás. Instituto Nacional de Tecnología Industrial. Textiles (INTI-Textiles); Argentina Fil: Molinari, Fabricio Nicolás. Consiglio Nazionale delle Ricerche. Istituto sull'Inquinamento Atmosferico (CNR-IIA); Italia Fil: De Cesare, Fabrizio. Consiglio Nazionale delle Ricerche. Istituto sull'Inquinamento Atmosferico (CNR-IIA); Italia Fil: De Cesare, Fabrizio. Università degli Studi della Tuscia (UNITUS); Italia Fil: Di Natale, Corrado. Università degli Studi di Roma Tor Vergata. Dipartimento di Ingegneria Elettronica (UniRoma2); Italia Fil: Tranfo, Giovanna. Ministero delle infrastrutture e dei trasporti. Dipartimento di Medicina, Epidemiologia, Igiene del Lavoro ed Ambientale (DIMEILA-INAIL); Italia Fil: Macagnano, Antonella. Consiglio Nazionale delle Ricerche. Istituto sull'Inquinamento Atmosferico (CNR-IIA); Italia |
description |
An original approach has been proposed for designing a nanofibrous (NF) layer using UVcured polyvinylpyrrolidone (PVP) as a matrix, incorporating mesoporous graphene carbon (MGC) nanopowder both inside and outside the fibers, creating a sandwich-like structure. This architecture is intended to selectively adsorb and detect acetic acid vapors, which are known to cause health issues in exposed workers. The nanocomposite MGC-PVP-NFs layer was fabricated through electrospinning deposition onto interdigitated microelectrodes (IDEs) and stabilized under UV–light irradiation. To enhance the adhesion of MGC onto the surface of the nanocomposite polymeric fibers, the layer was dipped in a suspension of polyethyleneimine (PEI) and MGC. The resulting structure demonstrated promising electrical and sensing properties, including rapid responses, high sensitivity, good linearity, reversibility, repeatability, and selectivity towards acetic acid vapors. Initial testing was conducted in a laboratory using a bench electrometer, followed by validation in a portable sensing device based on consumer electronic components (by ARDUINO®). This portable system was designed to provide a compact, cost-effective solution with high sensing capabilities. Under room temperature and ambient air conditions, both laboratory and portable tests exhibited favorable linear responses, with detection limits of 0.16 and 1 ppm, respectively. |
publishDate |
2024 |
dc.date.none.fl_str_mv |
2024 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
2025PapaPaolo.pdf https://app.inti.gob.ar/greenstone3/sites/localsite/collect/nuevadc/index/assoc/2025Papa/Paolo_pd.dir/doc.pdf |
identifier_str_mv |
2025PapaPaolo.pdf |
url |
https://app.inti.gob.ar/greenstone3/sites/localsite/collect/nuevadc/index/assoc/2025Papa/Paolo_pd.dir/doc.pdf |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by/4.0/ openAccess |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by/4.0/ openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
MDPI |
publisher.none.fl_str_mv |
MDPI |
dc.source.none.fl_str_mv |
Sensors 2024, 24(7), 2174 reponame:Repositorio Institucional del Instituto Nacional de Tecnología Industrial (INTI) instname:Instituto Nacional de Tecnología Industrial |
reponame_str |
Repositorio Institucional del Instituto Nacional de Tecnología Industrial (INTI) |
collection |
Repositorio Institucional del Instituto Nacional de Tecnología Industrial (INTI) |
instname_str |
Instituto Nacional de Tecnología Industrial |
repository.name.fl_str_mv |
Repositorio Institucional del Instituto Nacional de Tecnología Industrial (INTI) - Instituto Nacional de Tecnología Industrial |
repository.mail.fl_str_mv |
pfalcato@inti.gob.ar |
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12.559606 |