Chitosan-graft-poly(n-butyl acrylate) copolymer Synthesis and characterization of a natural synthetic hybrid material

Autores
Anbinder, Pablo; Macchi, Carlos; Amalvy, Javier; Somoza, Alberto
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Two chitosan polymers with different deacetylation degree and molecular weight were subjected to graft- ing reactions with the aim to enhance the properties of these bio-based materials. Specifically, n-butyl acrylate in different proportions was grafted onto two different deacetylation degree (DD%) chitosan using radical initiation in a surfactant free emulsion system. Infrared spectroscopy was used to confirm grafting and products grafting percentage and efficiency were evaluated against acrylate/chitosan ratio and DD%. Thermal and structural properties and the behavior against water of the raw and grafted biopolymers were studied using several experimental techniques: differential scanning calorimetry, transmission electron microscopy, dynamic light scattering, water swelling, contact angle and positron annihilation lifetime spectroscopy. The influence of the grafting process on the morphological and physicochemical properties of the prepared natural/synthetic hybrid materials is discussed.
Fil: Anbinder, Pablo. IFIMAT (Instituto de Física de Materiales Tandil). UNCPBA (Universidad del Centro de la Provincia de Buenos Aires). CIFICEN (UNCPBA-CICPBA-CONICET); Argentina
Fil: Macchi, Carlos. IFIMAT (Instituto de Física de Materiales Tandil). UNCPBA (Universidad del Centro de la Provincia de Buenos Aires). CIFICEN (UNCPBA-CICPBA-CONICET); Argentina
Fil: Amalvy, Javier. UNLP (Universidad Nacional de La Plata). INIFTA (Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas). CONICET. CIDEPINT (Centro de Investigación y Desarrollo en Tecnología de Pinturas) CONICET/CICPBA. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales); Argentina
Fil: Somoza, Alberto. IFIMAT (Instituto de Física de Materiales Tandil). UNCPBA (Universidad del Centro de la Provincia de Buenos Aires). CIFICEN (UNCPBA-CICPBA-CONICET); Argentina
Peer Reviewed
Materia
Biopolymer, Chitosan, n-Butyl acrylate, Graft, Thermal and structural properties
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-nd/4.0/
Repositorio
Repositorio Institucional Abierto (UTN)
Institución
Universidad Tecnológica Nacional
OAI Identificador
oai:ria.utn.edu.ar:20.500.12272/3424
Acceder
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spelling Chitosan-graft-poly(n-butyl acrylate) copolymer Synthesis and characterization of a natural synthetic hybrid materialAnbinder, PabloMacchi, CarlosAmalvy, JavierSomoza, AlbertoBiopolymer, Chitosan, n-Butyl acrylate, Graft, Thermal and structural propertiesTwo chitosan polymers with different deacetylation degree and molecular weight were subjected to graft- ing reactions with the aim to enhance the properties of these bio-based materials. Specifically, n-butyl acrylate in different proportions was grafted onto two different deacetylation degree (DD%) chitosan using radical initiation in a surfactant free emulsion system. Infrared spectroscopy was used to confirm grafting and products grafting percentage and efficiency were evaluated against acrylate/chitosan ratio and DD%. Thermal and structural properties and the behavior against water of the raw and grafted biopolymers were studied using several experimental techniques: differential scanning calorimetry, transmission electron microscopy, dynamic light scattering, water swelling, contact angle and positron annihilation lifetime spectroscopy. The influence of the grafting process on the morphological and physicochemical properties of the prepared natural/synthetic hybrid materials is discussed.Fil: Anbinder, Pablo. IFIMAT (Instituto de Física de Materiales Tandil). UNCPBA (Universidad del Centro de la Provincia de Buenos Aires). CIFICEN (UNCPBA-CICPBA-CONICET); ArgentinaFil: Macchi, Carlos. IFIMAT (Instituto de Física de Materiales Tandil). UNCPBA (Universidad del Centro de la Provincia de Buenos Aires). CIFICEN (UNCPBA-CICPBA-CONICET); ArgentinaFil: Amalvy, Javier. UNLP (Universidad Nacional de La Plata). INIFTA (Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas). CONICET. CIDEPINT (Centro de Investigación y Desarrollo en Tecnología de Pinturas) CONICET/CICPBA. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales); ArgentinaFil: Somoza, Alberto. IFIMAT (Instituto de Física de Materiales Tandil). UNCPBA (Universidad del Centro de la Provincia de Buenos Aires). CIFICEN (UNCPBA-CICPBA-CONICET); ArgentinaPeer Reviewed2019-02-09T22:38:35Z2019-02-09T22:38:35Z2016info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfCarbohydrate Polymershttp://hdl.handle.net/20.500.12272/342410.1016/j.carbpol.2016.02.072enginfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/Elsevier Ltd.Atribución (Attribution): En cualquier explotación de la obra autorizada por la licencia será necesario reconocer la autoría (obligatoria en todos los casos). No comercial (Non Commercial): La explotación de la obra queda limitada a usos no comerciales. Sin obras derivadas (No Derivate Works): La autorización para explotar la obra no incluye la posibilidad de crear una obra derivada (traducciones, adaptaciones, etc.).Attribution-NonCommercial-NoDerivatives 4.0 Internacionalreponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacional2025-09-29T14:29:42Zoai:ria.utn.edu.ar:20.500.12272/3424instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2025-09-29 14:29:43.331Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse
dc.title.none.fl_str_mv Chitosan-graft-poly(n-butyl acrylate) copolymer Synthesis and characterization of a natural synthetic hybrid material
title Chitosan-graft-poly(n-butyl acrylate) copolymer Synthesis and characterization of a natural synthetic hybrid material
spellingShingle Chitosan-graft-poly(n-butyl acrylate) copolymer Synthesis and characterization of a natural synthetic hybrid material
Anbinder, Pablo
Biopolymer, Chitosan, n-Butyl acrylate, Graft, Thermal and structural properties
title_short Chitosan-graft-poly(n-butyl acrylate) copolymer Synthesis and characterization of a natural synthetic hybrid material
title_full Chitosan-graft-poly(n-butyl acrylate) copolymer Synthesis and characterization of a natural synthetic hybrid material
title_fullStr Chitosan-graft-poly(n-butyl acrylate) copolymer Synthesis and characterization of a natural synthetic hybrid material
title_full_unstemmed Chitosan-graft-poly(n-butyl acrylate) copolymer Synthesis and characterization of a natural synthetic hybrid material
title_sort Chitosan-graft-poly(n-butyl acrylate) copolymer Synthesis and characterization of a natural synthetic hybrid material
dc.creator.none.fl_str_mv Anbinder, Pablo
Macchi, Carlos
Amalvy, Javier
Somoza, Alberto
author Anbinder, Pablo
author_facet Anbinder, Pablo
Macchi, Carlos
Amalvy, Javier
Somoza, Alberto
author_role author
author2 Macchi, Carlos
Amalvy, Javier
Somoza, Alberto
author2_role author
author
author
dc.subject.none.fl_str_mv Biopolymer, Chitosan, n-Butyl acrylate, Graft, Thermal and structural properties
topic Biopolymer, Chitosan, n-Butyl acrylate, Graft, Thermal and structural properties
dc.description.none.fl_txt_mv Two chitosan polymers with different deacetylation degree and molecular weight were subjected to graft- ing reactions with the aim to enhance the properties of these bio-based materials. Specifically, n-butyl acrylate in different proportions was grafted onto two different deacetylation degree (DD%) chitosan using radical initiation in a surfactant free emulsion system. Infrared spectroscopy was used to confirm grafting and products grafting percentage and efficiency were evaluated against acrylate/chitosan ratio and DD%. Thermal and structural properties and the behavior against water of the raw and grafted biopolymers were studied using several experimental techniques: differential scanning calorimetry, transmission electron microscopy, dynamic light scattering, water swelling, contact angle and positron annihilation lifetime spectroscopy. The influence of the grafting process on the morphological and physicochemical properties of the prepared natural/synthetic hybrid materials is discussed.
Fil: Anbinder, Pablo. IFIMAT (Instituto de Física de Materiales Tandil). UNCPBA (Universidad del Centro de la Provincia de Buenos Aires). CIFICEN (UNCPBA-CICPBA-CONICET); Argentina
Fil: Macchi, Carlos. IFIMAT (Instituto de Física de Materiales Tandil). UNCPBA (Universidad del Centro de la Provincia de Buenos Aires). CIFICEN (UNCPBA-CICPBA-CONICET); Argentina
Fil: Amalvy, Javier. UNLP (Universidad Nacional de La Plata). INIFTA (Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas). CONICET. CIDEPINT (Centro de Investigación y Desarrollo en Tecnología de Pinturas) CONICET/CICPBA. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales); Argentina
Fil: Somoza, Alberto. IFIMAT (Instituto de Física de Materiales Tandil). UNCPBA (Universidad del Centro de la Provincia de Buenos Aires). CIFICEN (UNCPBA-CICPBA-CONICET); Argentina
Peer Reviewed
description Two chitosan polymers with different deacetylation degree and molecular weight were subjected to graft- ing reactions with the aim to enhance the properties of these bio-based materials. Specifically, n-butyl acrylate in different proportions was grafted onto two different deacetylation degree (DD%) chitosan using radical initiation in a surfactant free emulsion system. Infrared spectroscopy was used to confirm grafting and products grafting percentage and efficiency were evaluated against acrylate/chitosan ratio and DD%. Thermal and structural properties and the behavior against water of the raw and grafted biopolymers were studied using several experimental techniques: differential scanning calorimetry, transmission electron microscopy, dynamic light scattering, water swelling, contact angle and positron annihilation lifetime spectroscopy. The influence of the grafting process on the morphological and physicochemical properties of the prepared natural/synthetic hybrid materials is discussed.
publishDate 2016
dc.date.none.fl_str_mv 2016
2019-02-09T22:38:35Z
2019-02-09T22:38:35Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv Carbohydrate Polymers
http://hdl.handle.net/20.500.12272/3424
10.1016/j.carbpol.2016.02.072
identifier_str_mv Carbohydrate Polymers
10.1016/j.carbpol.2016.02.072
url http://hdl.handle.net/20.500.12272/3424
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
Elsevier Ltd.
Atribución (Attribution): En cualquier explotación de la obra autorizada por la licencia será necesario reconocer la autoría (obligatoria en todos los casos). No comercial (Non Commercial): La explotación de la obra queda limitada a usos no comerciales. Sin obras derivadas (No Derivate Works): La autorización para explotar la obra no incluye la posibilidad de crear una obra derivada (traducciones, adaptaciones, etc.).
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
Elsevier Ltd.
Atribución (Attribution): En cualquier explotación de la obra autorizada por la licencia será necesario reconocer la autoría (obligatoria en todos los casos). No comercial (Non Commercial): La explotación de la obra queda limitada a usos no comerciales. Sin obras derivadas (No Derivate Works): La autorización para explotar la obra no incluye la posibilidad de crear una obra derivada (traducciones, adaptaciones, etc.).
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.source.none.fl_str_mv reponame:Repositorio Institucional Abierto (UTN)
instname:Universidad Tecnológica Nacional
reponame_str Repositorio Institucional Abierto (UTN)
collection Repositorio Institucional Abierto (UTN)
instname_str Universidad Tecnológica Nacional
repository.name.fl_str_mv Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional
repository.mail.fl_str_mv gestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.ar
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score 12.559606

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