Degradación en fase gaseosa de compuestos orgánicos oxigenados y/o pesticidas

Autores
Gibilisco, Rodrigo Gastón
Año de publicación
2016
Idioma
español castellano
Tipo de recurso
tesis doctoral
Estado
versión publicada
Colaborador/a o director/a de tesis
Teruel, Mariano Andrés
Santiago, Ana Noemi
Toselli, Beatriz Margarita
Baumgartner, María Teresa
Blesa, Miguel Angel
Descripción
Tesis (Doctor en Ciencias Químicas) - - Universidad Nacional de Córdoba. Facultad de Ciencias Químicas, 2016
Fil: Gibilisco, Rodrigo Gastón. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas; Argentina.
Fil: Teruel, Mariano Andrés. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina.
Fil: Teruel, Mariano Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Santiago, Ana Noemi. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina.
Fil: Santiago, Ana Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Toselli, Beatriz Margarita. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina.
Fil: Toselli, Beatriz Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Baumgartner, María Teresa. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina.
Fil: Baumgartner, María Teresa. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Blesa, Miguel Angel. Universidad Nacional de San Martín; Argentina.
Fil: Blesa, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina.
Oxygenated volatile organic compounds (OVOC´s) are currently being investigated as an environmental friendly alternative to replace solvents, pesticides and fuel additives. Such compounds are not only emitted by industrial activities, it is known that a large proportion of OVOC's is released also into the atmosphere from biogenic sources (BVOCs) like vegetation, biomass burning, oceans and volcanic emissions. Once in the atmosphere, these compounds can contribute to the formation of secondary organic aerosols (SOA), acid rain production, along with other environmental problems associated with the photochemical air pollution and persistent organic pollutant (POPs) formation. Consequently, detailed knowledge of their chemical behavior in the atmosphere is required to assess possible implications of their widespread application. In this aspect, the electrophilic addition reactions of atmospherically relevant species (OH radicals, Cl atoms and O3 molecules) over selected OVOC's were studied. For these purposes, a series of long chain unsaturated alcohols emitted on a large scale by plants, with potential use as biopesticides was selected. On the other hand, the product distribution of the OH-initiated degradation of a man-made unsaturated ester were studied from the experimental and theoretical point of view regarding the effect of different kind of atmospheres (presence and absence of NOx). The kinetics of the reactions and products studies were obtained by different experimental systems:  80 L collapsible Teflon reaction chamber with solid phase microextraction (SPME) and GC-FID/MS.  405 L multiple pass Pyrex reaction chamber with in situ FTIR detection.  1080 L multiple pass quartz-glass reaction chamber with in situ FTIR detection. The following rate coefficients of the reactions of a series of biogenic alcohols at room temperature and atmospheric pressure were obtained (in cm3 molecule-1 s-1): BVOC kOH × 1010 cm3 molecule-1 kCl × 1010 cm3 molecule-1 kO3 × 1017 cm3 molecule-1 (E)-2-hexen-1-ol (1.010.32) (3.490.82) (5.98 ± 0.73) (E)-3-hexen-1-ol (1.200.24) (3.420.79) (5.83 ± 0.86) (Z)-3-hexen-1-ol (1.400.33) (2.940.72) (6.04 ± 0.95) (Z)-3-hepten-1-ol (1.28±0.23) (3.800.86) (Z)-3-Octen-1-ol (1.49±0.35) (4.130.68) In addition, a product study on the reactions of OH radicals with (E)-3-hexen-1-ol and (Z)-3-hepten-1-ol in the absence of NOx were determined. Molar formation yields of (377) % for propanal and (333) % for butanal where obtained as main degradation products of (E)-3-hexen-1-ol and (Z)-3-hepten-1-ol respectively. Based on the experimental data obtained, possible reactions mechanisms were postulated and their atmospheric implications assessed. Furthermore, the reactivity of different kind of electrophiles toward the OVOCs studied was correlated with their ionization potentials to calculate rate coefficients of reactions that have not been measured yet from its experimental difficulties. On the other hand, the product distribution of the gas-phase reaction of OH radicals with methyl methacrylate (MMA) in the absence of NOx was also studied at 298 K and 1 atm of air. In the absence of NOx, methyl pyruvate was identified with a yield of 76 ± 13%. In addition, a detailed quantum chemical study of the degradation of MMA was performed by density functional theory (DFT) methods. This study allow us to propose that reaction between peroxy radical (RO2•) and hydroxyl radical (OH) became relevant at NOx- free environments. The results obtained in this work allowed us to establish the atmospheric impact of these reactions and detailed photooxidation mechanisms for the VOCs studied required to develop realistic atmospheric models to help environmental policy decisions.
Fil: Gibilisco, Rodrigo Gastón. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas; Argentina.
Fil: Teruel, Mariano Andrés. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina.
Fil: Teruel, Mariano Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Santiago, Ana Noemi. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina.
Fil: Santiago, Ana Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Toselli, Beatriz Margarita. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina.
Fil: Toselli, Beatriz Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Baumgartner, María Teresa. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina.
Fil: Baumgartner, María Teresa. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Blesa, Miguel Angel. Universidad Nacional de San Martín; Argentina.
Fil: Blesa, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina.
Materia
Contaminación ambiental
Química de la atmósfera
Atmósferas
Cinética química
Cromatografía de gases
Compuestos orgánicos volátiles
Plaguicidas
Residuos de plaguicidas
Oxígeno
Interfases
Nivel de accesibilidad
acceso abierto
Condiciones de uso
Repositorio
Repositorio Digital Universitario (UNC)
Institución
Universidad Nacional de Córdoba
OAI Identificador
oai:rdu.unc.edu.ar:11086/16139

id RDUUNC_7c43407f97a79b40f6a4e7e0267942f8
oai_identifier_str oai:rdu.unc.edu.ar:11086/16139
network_acronym_str RDUUNC
repository_id_str 2572
network_name_str Repositorio Digital Universitario (UNC)
spelling Degradación en fase gaseosa de compuestos orgánicos oxigenados y/o pesticidasGibilisco, Rodrigo GastónContaminación ambientalQuímica de la atmósferaAtmósferasCinética químicaCromatografía de gasesCompuestos orgánicos volátilesPlaguicidasResiduos de plaguicidasOxígenoInterfasesTesis (Doctor en Ciencias Químicas) - - Universidad Nacional de Córdoba. Facultad de Ciencias Químicas, 2016Fil: Gibilisco, Rodrigo Gastón. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas; Argentina.Fil: Teruel, Mariano Andrés. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina.Fil: Teruel, Mariano Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.Fil: Santiago, Ana Noemi. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina.Fil: Santiago, Ana Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.Fil: Toselli, Beatriz Margarita. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina.Fil: Toselli, Beatriz Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.Fil: Baumgartner, María Teresa. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina.Fil: Baumgartner, María Teresa. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.Fil: Blesa, Miguel Angel. Universidad Nacional de San Martín; Argentina.Fil: Blesa, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina.Oxygenated volatile organic compounds (OVOC´s) are currently being investigated as an environmental friendly alternative to replace solvents, pesticides and fuel additives. Such compounds are not only emitted by industrial activities, it is known that a large proportion of OVOC's is released also into the atmosphere from biogenic sources (BVOCs) like vegetation, biomass burning, oceans and volcanic emissions. Once in the atmosphere, these compounds can contribute to the formation of secondary organic aerosols (SOA), acid rain production, along with other environmental problems associated with the photochemical air pollution and persistent organic pollutant (POPs) formation. Consequently, detailed knowledge of their chemical behavior in the atmosphere is required to assess possible implications of their widespread application. In this aspect, the electrophilic addition reactions of atmospherically relevant species (OH radicals, Cl atoms and O3 molecules) over selected OVOC's were studied. For these purposes, a series of long chain unsaturated alcohols emitted on a large scale by plants, with potential use as biopesticides was selected. On the other hand, the product distribution of the OH-initiated degradation of a man-made unsaturated ester were studied from the experimental and theoretical point of view regarding the effect of different kind of atmospheres (presence and absence of NOx). The kinetics of the reactions and products studies were obtained by different experimental systems:  80 L collapsible Teflon reaction chamber with solid phase microextraction (SPME) and GC-FID/MS.  405 L multiple pass Pyrex reaction chamber with in situ FTIR detection.  1080 L multiple pass quartz-glass reaction chamber with in situ FTIR detection. The following rate coefficients of the reactions of a series of biogenic alcohols at room temperature and atmospheric pressure were obtained (in cm3 molecule-1 s-1): BVOC kOH × 1010 cm3 molecule-1 kCl × 1010 cm3 molecule-1 kO3 × 1017 cm3 molecule-1 (E)-2-hexen-1-ol (1.010.32) (3.490.82) (5.98 ± 0.73) (E)-3-hexen-1-ol (1.200.24) (3.420.79) (5.83 ± 0.86) (Z)-3-hexen-1-ol (1.400.33) (2.940.72) (6.04 ± 0.95) (Z)-3-hepten-1-ol (1.28±0.23) (3.800.86) (Z)-3-Octen-1-ol (1.49±0.35) (4.130.68) In addition, a product study on the reactions of OH radicals with (E)-3-hexen-1-ol and (Z)-3-hepten-1-ol in the absence of NOx were determined. Molar formation yields of (377) % for propanal and (333) % for butanal where obtained as main degradation products of (E)-3-hexen-1-ol and (Z)-3-hepten-1-ol respectively. Based on the experimental data obtained, possible reactions mechanisms were postulated and their atmospheric implications assessed. Furthermore, the reactivity of different kind of electrophiles toward the OVOCs studied was correlated with their ionization potentials to calculate rate coefficients of reactions that have not been measured yet from its experimental difficulties. On the other hand, the product distribution of the gas-phase reaction of OH radicals with methyl methacrylate (MMA) in the absence of NOx was also studied at 298 K and 1 atm of air. In the absence of NOx, methyl pyruvate was identified with a yield of 76 ± 13%. In addition, a detailed quantum chemical study of the degradation of MMA was performed by density functional theory (DFT) methods. This study allow us to propose that reaction between peroxy radical (RO2•) and hydroxyl radical (OH) became relevant at NOx- free environments. The results obtained in this work allowed us to establish the atmospheric impact of these reactions and detailed photooxidation mechanisms for the VOCs studied required to develop realistic atmospheric models to help environmental policy decisions.Fil: Gibilisco, Rodrigo Gastón. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas; Argentina.Fil: Teruel, Mariano Andrés. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina.Fil: Teruel, Mariano Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.Fil: Santiago, Ana Noemi. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina.Fil: Santiago, Ana Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.Fil: Toselli, Beatriz Margarita. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina.Fil: Toselli, Beatriz Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.Fil: Baumgartner, María Teresa. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina.Fil: Baumgartner, María Teresa. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.Fil: Blesa, Miguel Angel. Universidad Nacional de San Martín; Argentina.Fil: Blesa, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina.Teruel, Mariano AndrésSantiago, Ana NoemiToselli, Beatriz MargaritaBaumgartner, María TeresaBlesa, Miguel Angel2016info:eu-repo/semantics/doctoralThesisinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_db06info:ar-repo/semantics/tesisDoctoralapplication/pdfhttp://hdl.handle.net/11086/16139spainfo:eu-repo/semantics/openAccessreponame:Repositorio Digital Universitario (UNC)instname:Universidad Nacional de Córdobainstacron:UNC2025-10-16T09:28:38Zoai:rdu.unc.edu.ar:11086/16139Institucionalhttps://rdu.unc.edu.ar/Universidad públicaNo correspondehttp://rdu.unc.edu.ar/oai/snrdoca.unc@gmail.comArgentinaNo correspondeNo correspondeNo correspondeopendoar:25722025-10-16 09:28:39.148Repositorio Digital Universitario (UNC) - Universidad Nacional de Córdobafalse
dc.title.none.fl_str_mv Degradación en fase gaseosa de compuestos orgánicos oxigenados y/o pesticidas
title Degradación en fase gaseosa de compuestos orgánicos oxigenados y/o pesticidas
spellingShingle Degradación en fase gaseosa de compuestos orgánicos oxigenados y/o pesticidas
Gibilisco, Rodrigo Gastón
Contaminación ambiental
Química de la atmósfera
Atmósferas
Cinética química
Cromatografía de gases
Compuestos orgánicos volátiles
Plaguicidas
Residuos de plaguicidas
Oxígeno
Interfases
title_short Degradación en fase gaseosa de compuestos orgánicos oxigenados y/o pesticidas
title_full Degradación en fase gaseosa de compuestos orgánicos oxigenados y/o pesticidas
title_fullStr Degradación en fase gaseosa de compuestos orgánicos oxigenados y/o pesticidas
title_full_unstemmed Degradación en fase gaseosa de compuestos orgánicos oxigenados y/o pesticidas
title_sort Degradación en fase gaseosa de compuestos orgánicos oxigenados y/o pesticidas
dc.creator.none.fl_str_mv Gibilisco, Rodrigo Gastón
author Gibilisco, Rodrigo Gastón
author_facet Gibilisco, Rodrigo Gastón
author_role author
dc.contributor.none.fl_str_mv Teruel, Mariano Andrés
Santiago, Ana Noemi
Toselli, Beatriz Margarita
Baumgartner, María Teresa
Blesa, Miguel Angel
dc.subject.none.fl_str_mv Contaminación ambiental
Química de la atmósfera
Atmósferas
Cinética química
Cromatografía de gases
Compuestos orgánicos volátiles
Plaguicidas
Residuos de plaguicidas
Oxígeno
Interfases
topic Contaminación ambiental
Química de la atmósfera
Atmósferas
Cinética química
Cromatografía de gases
Compuestos orgánicos volátiles
Plaguicidas
Residuos de plaguicidas
Oxígeno
Interfases
dc.description.none.fl_txt_mv Tesis (Doctor en Ciencias Químicas) - - Universidad Nacional de Córdoba. Facultad de Ciencias Químicas, 2016
Fil: Gibilisco, Rodrigo Gastón. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas; Argentina.
Fil: Teruel, Mariano Andrés. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina.
Fil: Teruel, Mariano Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Santiago, Ana Noemi. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina.
Fil: Santiago, Ana Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Toselli, Beatriz Margarita. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina.
Fil: Toselli, Beatriz Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Baumgartner, María Teresa. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina.
Fil: Baumgartner, María Teresa. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Blesa, Miguel Angel. Universidad Nacional de San Martín; Argentina.
Fil: Blesa, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina.
Oxygenated volatile organic compounds (OVOC´s) are currently being investigated as an environmental friendly alternative to replace solvents, pesticides and fuel additives. Such compounds are not only emitted by industrial activities, it is known that a large proportion of OVOC's is released also into the atmosphere from biogenic sources (BVOCs) like vegetation, biomass burning, oceans and volcanic emissions. Once in the atmosphere, these compounds can contribute to the formation of secondary organic aerosols (SOA), acid rain production, along with other environmental problems associated with the photochemical air pollution and persistent organic pollutant (POPs) formation. Consequently, detailed knowledge of their chemical behavior in the atmosphere is required to assess possible implications of their widespread application. In this aspect, the electrophilic addition reactions of atmospherically relevant species (OH radicals, Cl atoms and O3 molecules) over selected OVOC's were studied. For these purposes, a series of long chain unsaturated alcohols emitted on a large scale by plants, with potential use as biopesticides was selected. On the other hand, the product distribution of the OH-initiated degradation of a man-made unsaturated ester were studied from the experimental and theoretical point of view regarding the effect of different kind of atmospheres (presence and absence of NOx). The kinetics of the reactions and products studies were obtained by different experimental systems:  80 L collapsible Teflon reaction chamber with solid phase microextraction (SPME) and GC-FID/MS.  405 L multiple pass Pyrex reaction chamber with in situ FTIR detection.  1080 L multiple pass quartz-glass reaction chamber with in situ FTIR detection. The following rate coefficients of the reactions of a series of biogenic alcohols at room temperature and atmospheric pressure were obtained (in cm3 molecule-1 s-1): BVOC kOH × 1010 cm3 molecule-1 kCl × 1010 cm3 molecule-1 kO3 × 1017 cm3 molecule-1 (E)-2-hexen-1-ol (1.010.32) (3.490.82) (5.98 ± 0.73) (E)-3-hexen-1-ol (1.200.24) (3.420.79) (5.83 ± 0.86) (Z)-3-hexen-1-ol (1.400.33) (2.940.72) (6.04 ± 0.95) (Z)-3-hepten-1-ol (1.28±0.23) (3.800.86) (Z)-3-Octen-1-ol (1.49±0.35) (4.130.68) In addition, a product study on the reactions of OH radicals with (E)-3-hexen-1-ol and (Z)-3-hepten-1-ol in the absence of NOx were determined. Molar formation yields of (377) % for propanal and (333) % for butanal where obtained as main degradation products of (E)-3-hexen-1-ol and (Z)-3-hepten-1-ol respectively. Based on the experimental data obtained, possible reactions mechanisms were postulated and their atmospheric implications assessed. Furthermore, the reactivity of different kind of electrophiles toward the OVOCs studied was correlated with their ionization potentials to calculate rate coefficients of reactions that have not been measured yet from its experimental difficulties. On the other hand, the product distribution of the gas-phase reaction of OH radicals with methyl methacrylate (MMA) in the absence of NOx was also studied at 298 K and 1 atm of air. In the absence of NOx, methyl pyruvate was identified with a yield of 76 ± 13%. In addition, a detailed quantum chemical study of the degradation of MMA was performed by density functional theory (DFT) methods. This study allow us to propose that reaction between peroxy radical (RO2•) and hydroxyl radical (OH) became relevant at NOx- free environments. The results obtained in this work allowed us to establish the atmospheric impact of these reactions and detailed photooxidation mechanisms for the VOCs studied required to develop realistic atmospheric models to help environmental policy decisions.
Fil: Gibilisco, Rodrigo Gastón. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas; Argentina.
Fil: Teruel, Mariano Andrés. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina.
Fil: Teruel, Mariano Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Santiago, Ana Noemi. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina.
Fil: Santiago, Ana Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Toselli, Beatriz Margarita. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina.
Fil: Toselli, Beatriz Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Baumgartner, María Teresa. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina.
Fil: Baumgartner, María Teresa. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina.
Fil: Blesa, Miguel Angel. Universidad Nacional de San Martín; Argentina.
Fil: Blesa, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina.
description Tesis (Doctor en Ciencias Químicas) - - Universidad Nacional de Córdoba. Facultad de Ciencias Químicas, 2016
publishDate 2016
dc.date.none.fl_str_mv 2016
dc.type.none.fl_str_mv info:eu-repo/semantics/doctoralThesis
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_db06
info:ar-repo/semantics/tesisDoctoral
format doctoralThesis
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11086/16139
url http://hdl.handle.net/11086/16139
dc.language.none.fl_str_mv spa
language spa
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositorio Digital Universitario (UNC)
instname:Universidad Nacional de Córdoba
instacron:UNC
reponame_str Repositorio Digital Universitario (UNC)
collection Repositorio Digital Universitario (UNC)
instname_str Universidad Nacional de Córdoba
instacron_str UNC
institution UNC
repository.name.fl_str_mv Repositorio Digital Universitario (UNC) - Universidad Nacional de Córdoba
repository.mail.fl_str_mv oca.unc@gmail.com
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score 12.712165