Screening of pesticide residues in honeybee wax comb by LC-ESI-MS/MS. A pilot study
- Autores
- Herrera López, Sonia; Lozano, Ana; Sosa, Alexis Lionel; Hernando, M. Dolores; Rodríguez Fernández-Alba, Amadeo
- Año de publicación
- 2016
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A developed multi-residue method using microflow-LC-ESI-QqQ-MS provided a wide-scope analysis for medium-polar and polar pesticide residues (120 compounds including breakdown products). Honeybee wax comb samples were extracted using a generic QuEChERS based procedure. Acceptable recoveries at concentration levels of 5 and 50 μg kg−1 were within the 70–120% range with an associated precision RSD <20%. The LOQ values were mostly 5 μg kg−1 for almost all pesticides. Aprox. 31 of 120 LC-amenable pesticides tested (25.8%) were detected in a pilot study of 60 samples. Pesticide residues detected using the proposed method were: the breakdown products of amitraz, DMPF and DMF, an acaricide used for Varroa mite control, with a range of concentration from 5 to 464 μg kg−1 (sum of DMPF + DMF), organophosphate insecticides from 1 to 464 μg kg−1, acaricides at concentrations > 9 μg kg−1; fungicides at concentrations ranging from 1 to 23 μg kg−1. The number of positive detections due to herbicides was lower as expected and at a lower level of concentration, from 1 to 5.9 μg kg−1.
EEA Concordia
Fil: Herrera López, Sonia. Universidad de Almería. Departamento de Química y Física. Campus de Excelencia Internacional en Agroalimentación; España. European Union Reference Laboratory for Pesticide Residues in Fruit and Vegetables; España
Fil: Lozano, Ana. Universidad de Almería. Departamento de Química y Física. Campus de Excelencia Internacional en Agroalimentación; España. European Union Reference Laboratory for Pesticide Residues in Fruit and Vegetables; España
Fil: Sosa, Alexis Lionel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Concordia; Argentina
Fil: Hernando, M. Dolores. Instituto Nacional de Investigación y Tecnología Agraria y Alimentaria (INIA); España
Fil: Rodríguez Fernández-Alba, Amadeo. Universidad de Almería. Departamento de Química y Física. Campus de Excelencia Internacional en Agroalimentación; España. European Union Reference Laboratory for Pesticide Residues in Fruit and Vegetables; España - Fuente
- Chemosphere 163 : 44-53 (November 2016)
- Materia
-
Abeja Melífera
Cera de Abeja
Productos de la Colmena
Residuos de Plaguicidas
Técnicas de Trazadores
Honey Bees
Beeswax
Hive Products
Pesticide Residues
Tracer Techniques
LC-ESI-MS/MS - Nivel de accesibilidad
- acceso restringido
- Condiciones de uso
- Repositorio
.jpg)
- Institución
- Instituto Nacional de Tecnología Agropecuaria
- OAI Identificador
- oai:localhost:20.500.12123/3521
Ver los metadatos del registro completo
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Screening of pesticide residues in honeybee wax comb by LC-ESI-MS/MS. A pilot studyHerrera López, SoniaLozano, AnaSosa, Alexis LionelHernando, M. DoloresRodríguez Fernández-Alba, AmadeoAbeja MelíferaCera de AbejaProductos de la ColmenaResiduos de PlaguicidasTécnicas de TrazadoresHoney BeesBeeswaxHive ProductsPesticide ResiduesTracer TechniquesLC-ESI-MS/MSA developed multi-residue method using microflow-LC-ESI-QqQ-MS provided a wide-scope analysis for medium-polar and polar pesticide residues (120 compounds including breakdown products). Honeybee wax comb samples were extracted using a generic QuEChERS based procedure. Acceptable recoveries at concentration levels of 5 and 50 μg kg−1 were within the 70–120% range with an associated precision RSD <20%. The LOQ values were mostly 5 μg kg−1 for almost all pesticides. Aprox. 31 of 120 LC-amenable pesticides tested (25.8%) were detected in a pilot study of 60 samples. Pesticide residues detected using the proposed method were: the breakdown products of amitraz, DMPF and DMF, an acaricide used for Varroa mite control, with a range of concentration from 5 to 464 μg kg−1 (sum of DMPF + DMF), organophosphate insecticides from 1 to 464 μg kg−1, acaricides at concentrations > 9 μg kg−1; fungicides at concentrations ranging from 1 to 23 μg kg−1. The number of positive detections due to herbicides was lower as expected and at a lower level of concentration, from 1 to 5.9 μg kg−1.EEA ConcordiaFil: Herrera López, Sonia. Universidad de Almería. Departamento de Química y Física. Campus de Excelencia Internacional en Agroalimentación; España. European Union Reference Laboratory for Pesticide Residues in Fruit and Vegetables; EspañaFil: Lozano, Ana. Universidad de Almería. Departamento de Química y Física. Campus de Excelencia Internacional en Agroalimentación; España. European Union Reference Laboratory for Pesticide Residues in Fruit and Vegetables; EspañaFil: Sosa, Alexis Lionel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Concordia; ArgentinaFil: Hernando, M. Dolores. Instituto Nacional de Investigación y Tecnología Agraria y Alimentaria (INIA); EspañaFil: Rodríguez Fernández-Alba, Amadeo. Universidad de Almería. Departamento de Química y Física. Campus de Excelencia Internacional en Agroalimentación; España. European Union Reference Laboratory for Pesticide Residues in Fruit and Vegetables; España2018-10-01T13:26:00Z2018-10-01T13:26:00Z2016-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttps://www.sciencedirect.com/science/article/pii/S004565351630892X?via%3Dihubhttp://hdl.handle.net/20.500.12123/35210045-65351879-1298https://doi.org/10.1016/j.chemosphere.2016.07.008Chemosphere 163 : 44-53 (November 2016)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repo/semantics/restrictedAccess2025-09-04T09:47:35Zoai:localhost:20.500.12123/3521instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-09-04 09:47:36.534INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse |
| dc.title.none.fl_str_mv |
Screening of pesticide residues in honeybee wax comb by LC-ESI-MS/MS. A pilot study |
| title |
Screening of pesticide residues in honeybee wax comb by LC-ESI-MS/MS. A pilot study |
| spellingShingle |
Screening of pesticide residues in honeybee wax comb by LC-ESI-MS/MS. A pilot study Herrera López, Sonia Abeja Melífera Cera de Abeja Productos de la Colmena Residuos de Plaguicidas Técnicas de Trazadores Honey Bees Beeswax Hive Products Pesticide Residues Tracer Techniques LC-ESI-MS/MS |
| title_short |
Screening of pesticide residues in honeybee wax comb by LC-ESI-MS/MS. A pilot study |
| title_full |
Screening of pesticide residues in honeybee wax comb by LC-ESI-MS/MS. A pilot study |
| title_fullStr |
Screening of pesticide residues in honeybee wax comb by LC-ESI-MS/MS. A pilot study |
| title_full_unstemmed |
Screening of pesticide residues in honeybee wax comb by LC-ESI-MS/MS. A pilot study |
| title_sort |
Screening of pesticide residues in honeybee wax comb by LC-ESI-MS/MS. A pilot study |
| dc.creator.none.fl_str_mv |
Herrera López, Sonia Lozano, Ana Sosa, Alexis Lionel Hernando, M. Dolores Rodríguez Fernández-Alba, Amadeo |
| author |
Herrera López, Sonia |
| author_facet |
Herrera López, Sonia Lozano, Ana Sosa, Alexis Lionel Hernando, M. Dolores Rodríguez Fernández-Alba, Amadeo |
| author_role |
author |
| author2 |
Lozano, Ana Sosa, Alexis Lionel Hernando, M. Dolores Rodríguez Fernández-Alba, Amadeo |
| author2_role |
author author author author |
| dc.subject.none.fl_str_mv |
Abeja Melífera Cera de Abeja Productos de la Colmena Residuos de Plaguicidas Técnicas de Trazadores Honey Bees Beeswax Hive Products Pesticide Residues Tracer Techniques LC-ESI-MS/MS |
| topic |
Abeja Melífera Cera de Abeja Productos de la Colmena Residuos de Plaguicidas Técnicas de Trazadores Honey Bees Beeswax Hive Products Pesticide Residues Tracer Techniques LC-ESI-MS/MS |
| dc.description.none.fl_txt_mv |
A developed multi-residue method using microflow-LC-ESI-QqQ-MS provided a wide-scope analysis for medium-polar and polar pesticide residues (120 compounds including breakdown products). Honeybee wax comb samples were extracted using a generic QuEChERS based procedure. Acceptable recoveries at concentration levels of 5 and 50 μg kg−1 were within the 70–120% range with an associated precision RSD <20%. The LOQ values were mostly 5 μg kg−1 for almost all pesticides. Aprox. 31 of 120 LC-amenable pesticides tested (25.8%) were detected in a pilot study of 60 samples. Pesticide residues detected using the proposed method were: the breakdown products of amitraz, DMPF and DMF, an acaricide used for Varroa mite control, with a range of concentration from 5 to 464 μg kg−1 (sum of DMPF + DMF), organophosphate insecticides from 1 to 464 μg kg−1, acaricides at concentrations > 9 μg kg−1; fungicides at concentrations ranging from 1 to 23 μg kg−1. The number of positive detections due to herbicides was lower as expected and at a lower level of concentration, from 1 to 5.9 μg kg−1. EEA Concordia Fil: Herrera López, Sonia. Universidad de Almería. Departamento de Química y Física. Campus de Excelencia Internacional en Agroalimentación; España. European Union Reference Laboratory for Pesticide Residues in Fruit and Vegetables; España Fil: Lozano, Ana. Universidad de Almería. Departamento de Química y Física. Campus de Excelencia Internacional en Agroalimentación; España. European Union Reference Laboratory for Pesticide Residues in Fruit and Vegetables; España Fil: Sosa, Alexis Lionel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Concordia; Argentina Fil: Hernando, M. Dolores. Instituto Nacional de Investigación y Tecnología Agraria y Alimentaria (INIA); España Fil: Rodríguez Fernández-Alba, Amadeo. Universidad de Almería. Departamento de Química y Física. Campus de Excelencia Internacional en Agroalimentación; España. European Union Reference Laboratory for Pesticide Residues in Fruit and Vegetables; España |
| description |
A developed multi-residue method using microflow-LC-ESI-QqQ-MS provided a wide-scope analysis for medium-polar and polar pesticide residues (120 compounds including breakdown products). Honeybee wax comb samples were extracted using a generic QuEChERS based procedure. Acceptable recoveries at concentration levels of 5 and 50 μg kg−1 were within the 70–120% range with an associated precision RSD <20%. The LOQ values were mostly 5 μg kg−1 for almost all pesticides. Aprox. 31 of 120 LC-amenable pesticides tested (25.8%) were detected in a pilot study of 60 samples. Pesticide residues detected using the proposed method were: the breakdown products of amitraz, DMPF and DMF, an acaricide used for Varroa mite control, with a range of concentration from 5 to 464 μg kg−1 (sum of DMPF + DMF), organophosphate insecticides from 1 to 464 μg kg−1, acaricides at concentrations > 9 μg kg−1; fungicides at concentrations ranging from 1 to 23 μg kg−1. The number of positive detections due to herbicides was lower as expected and at a lower level of concentration, from 1 to 5.9 μg kg−1. |
| publishDate |
2016 |
| dc.date.none.fl_str_mv |
2016-11 2018-10-01T13:26:00Z 2018-10-01T13:26:00Z |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
https://www.sciencedirect.com/science/article/pii/S004565351630892X?via%3Dihub http://hdl.handle.net/20.500.12123/3521 0045-6535 1879-1298 https://doi.org/10.1016/j.chemosphere.2016.07.008 |
| url |
https://www.sciencedirect.com/science/article/pii/S004565351630892X?via%3Dihub http://hdl.handle.net/20.500.12123/3521 https://doi.org/10.1016/j.chemosphere.2016.07.008 |
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0045-6535 1879-1298 |
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eng |
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eng |
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restrictedAccess |
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application/pdf |
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Chemosphere 163 : 44-53 (November 2016) reponame:INTA Digital (INTA) instname:Instituto Nacional de Tecnología Agropecuaria |
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INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria |
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