Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production
- Autores
- Van Opstal, Natalia Veronica; Gabioud, Emmanuel Adrian; Seehaus, Mariela; Pighini, Ramiro Joaquin; Repetti, Maria Rosa; Wilson, Marcelo German; Wingeyer, Ana Beatriz; Cuatrin, Alejandra; Regaldo, Luciana Maria; Gagneten, Ana Maria; Sasal, Maria Carolina
- Año de publicación
- 2023
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The Espinal region (Entre Ríos, Argentina) has sufered land use changes caused by expansion of the agricultural frontier. This expansion has led to an increased use of pesticides. This study is aimed at better understanding the spatial distribu tion of pesticides in surface water of the Estacas stream, a representative basin of the Espinal region, associated with crop production. The location and proportion of area with soybean, maize, and wheat crops in each catchment area of the basin were estimated, and surface water samples were taken to perform a pesticide screening during a period of one year. Soybean represented approximately 71% of the total cultivated area of the basin, whereas maize and wheat accounted for 15% and 14%, respectively. The analysis of 125 analytes showed the presence of 19 pesticides. The pesticide load maps showed that atrazine was detected in an area of relatively low catchment compared to other pesticides as glyphosate, which is applied in all the agricultural felds of the basin. The load of metolachlor and S-metolachlor covered a large area of the basin. The highest recorded concentrations of these pesticides were 86 μg L−1 of atrazine, 24 μg L−1 of metolachlor, 19 μg L−1 of glyphosate, and 15 μg L−1 of S-metolachlor. The results allow better understanding the environmental distribution of pesticides associ ated with pest control in the crops of the basin studied, the doses and times of application, and the variation in the rainfall in the basin. This study provides relevant information about how aquatic ecosystems in agricultural basins receive the difuse contribution of pesticides, representing potential sources of water pollution. Also, the results allow supporting the design of agricultural practices and politics to improve land-use planning for the development of sustainable basins.
EEA Paraná
Fil: Van Opstal, Natalia Veronica. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Gabioud, Emmanuel Adrian. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Seehaus, Mariela. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Pighini, Ramiro Joaquin. Consejo Nacional de Investigaciones Científcas y Técnicas (CONICET), Santa Fe; Argentina
Fil: Wilson, Marcelo German. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Wingeyer, Ana Beatriz. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Cuatrin, Alejandra. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Regaldo, Luciana Maria. Consejo Nacional de Investigaciones Científcas y Técnicas (CONICET), Santa Fe; Argentina
Fil: Regaldo, Luciana Maria. Universidad Nacional del Litoral. Facultad de Humanidades y Ciencias (FHUC). Departamento de Ciencias Naturales. Laboratorio de Ecotoxicología; Argentina
Fil: Gagneten, Ana Maria. Universidad Nacional del Litoral. Facultad de Humanidades y Ciencias (FHUC). Departamento de Ciencias Naturales. Laboratorio de Ecotoxicología; Argentina
Fil: Sasal, Maria Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina - Fuente
- Environmental science and pollution research (20 January 2023)
- Materia
-
Pesticides
Watersheds
Surface Water
Environmental Monitoring
Plaguicidas
Cuencas Hidrográficas
Agua Superficial
Vigilancia Ambiental
Entre Ríos
Arroyo Estacas
Estacas Stream - Nivel de accesibilidad
- acceso restringido
- Condiciones de uso
- Repositorio
- Institución
- Instituto Nacional de Tecnología Agropecuaria
- OAI Identificador
- oai:localhost:20.500.12123/13921
Ver los metadatos del registro completo
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Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop productionVan Opstal, Natalia VeronicaGabioud, Emmanuel AdrianSeehaus, MarielaPighini, Ramiro JoaquinRepetti, Maria RosaWilson, Marcelo GermanWingeyer, Ana BeatrizCuatrin, AlejandraRegaldo, Luciana MariaGagneten, Ana MariaSasal, Maria CarolinaPesticidesWatershedsSurface WaterEnvironmental MonitoringPlaguicidasCuencas HidrográficasAgua SuperficialVigilancia AmbientalEntre RíosArroyo EstacasEstacas StreamThe Espinal region (Entre Ríos, Argentina) has sufered land use changes caused by expansion of the agricultural frontier. This expansion has led to an increased use of pesticides. This study is aimed at better understanding the spatial distribu tion of pesticides in surface water of the Estacas stream, a representative basin of the Espinal region, associated with crop production. The location and proportion of area with soybean, maize, and wheat crops in each catchment area of the basin were estimated, and surface water samples were taken to perform a pesticide screening during a period of one year. Soybean represented approximately 71% of the total cultivated area of the basin, whereas maize and wheat accounted for 15% and 14%, respectively. The analysis of 125 analytes showed the presence of 19 pesticides. The pesticide load maps showed that atrazine was detected in an area of relatively low catchment compared to other pesticides as glyphosate, which is applied in all the agricultural felds of the basin. The load of metolachlor and S-metolachlor covered a large area of the basin. The highest recorded concentrations of these pesticides were 86 μg L−1 of atrazine, 24 μg L−1 of metolachlor, 19 μg L−1 of glyphosate, and 15 μg L−1 of S-metolachlor. The results allow better understanding the environmental distribution of pesticides associ ated with pest control in the crops of the basin studied, the doses and times of application, and the variation in the rainfall in the basin. This study provides relevant information about how aquatic ecosystems in agricultural basins receive the difuse contribution of pesticides, representing potential sources of water pollution. Also, the results allow supporting the design of agricultural practices and politics to improve land-use planning for the development of sustainable basins.EEA ParanáFil: Van Opstal, Natalia Veronica. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; ArgentinaFil: Gabioud, Emmanuel Adrian. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; ArgentinaFil: Seehaus, Mariela. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; ArgentinaFil: Pighini, Ramiro Joaquin. Consejo Nacional de Investigaciones Científcas y Técnicas (CONICET), Santa Fe; ArgentinaFil: Wilson, Marcelo German. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; ArgentinaFil: Wingeyer, Ana Beatriz. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; ArgentinaFil: Cuatrin, Alejandra. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; ArgentinaFil: Regaldo, Luciana Maria. Consejo Nacional de Investigaciones Científcas y Técnicas (CONICET), Santa Fe; ArgentinaFil: Regaldo, Luciana Maria. Universidad Nacional del Litoral. Facultad de Humanidades y Ciencias (FHUC). Departamento de Ciencias Naturales. Laboratorio de Ecotoxicología; ArgentinaFil: Gagneten, Ana Maria. Universidad Nacional del Litoral. Facultad de Humanidades y Ciencias (FHUC). Departamento de Ciencias Naturales. Laboratorio de Ecotoxicología; ArgentinaFil: Sasal, Maria Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; ArgentinaSpringer2023-01-23T14:12:08Z2023-01-23T14:12:08Z2023-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12123/13921https://awsjournal.org/article/glyphosate-resistant-gr-soybean-and-corn-in-brazil-past-present-and-future/Van Opstal, N.V., Gabioud, E.A., Seehaus, M.S. et al. Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production. Environ Sci Pollut Res (2023). https://doi.org/10.1007/s11356-023-25373-21614-7499https://doi.org/10.51694/AdvWeedSci/2022;40:seventy-five004Environmental science and pollution research (20 January 2023)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repograntAgreement/INTA/2019-PD-E2-I039-002/2019-PD-E2-I039-002/AR./REMEDIACIÓN DE SUELOS Y AGUAS Y RESTAURACIÓN ECOLÓGICA DE SISTEMAS DEGRADADOS POR USO AGROPECUARIO, AGROINDUSTRIAL Y ACTIVIDADES EXTRACTIVASinfo:eu-repograntAgreement/INTA/2019-PE-E2-I046-001/2019-PE-E2-I046-001/AR./Evaluación de la dinámica de la sostenibilidad de territorios y sistemas de producción. Indicadoresinfo:eu-repograntAgreement/INTA/2019-PE-E2-I041-001/2019-PE-E2-I041-001/AR./Aportes para la gestión integrada de los recursos hídricos (GIRH) en cuencas del Sistema Agroalimentario ArgentinoEntre Ríos .......... (province) (World, South America, Argentina)1001237info:eu-repo/semantics/restrictedAccess2025-10-16T09:31:04Zoai:localhost:20.500.12123/13921instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-10-16 09:31:05.201INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse |
dc.title.none.fl_str_mv |
Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production |
title |
Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production |
spellingShingle |
Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production Van Opstal, Natalia Veronica Pesticides Watersheds Surface Water Environmental Monitoring Plaguicidas Cuencas Hidrográficas Agua Superficial Vigilancia Ambiental Entre Ríos Arroyo Estacas Estacas Stream |
title_short |
Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production |
title_full |
Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production |
title_fullStr |
Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production |
title_full_unstemmed |
Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production |
title_sort |
Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production |
dc.creator.none.fl_str_mv |
Van Opstal, Natalia Veronica Gabioud, Emmanuel Adrian Seehaus, Mariela Pighini, Ramiro Joaquin Repetti, Maria Rosa Wilson, Marcelo German Wingeyer, Ana Beatriz Cuatrin, Alejandra Regaldo, Luciana Maria Gagneten, Ana Maria Sasal, Maria Carolina |
author |
Van Opstal, Natalia Veronica |
author_facet |
Van Opstal, Natalia Veronica Gabioud, Emmanuel Adrian Seehaus, Mariela Pighini, Ramiro Joaquin Repetti, Maria Rosa Wilson, Marcelo German Wingeyer, Ana Beatriz Cuatrin, Alejandra Regaldo, Luciana Maria Gagneten, Ana Maria Sasal, Maria Carolina |
author_role |
author |
author2 |
Gabioud, Emmanuel Adrian Seehaus, Mariela Pighini, Ramiro Joaquin Repetti, Maria Rosa Wilson, Marcelo German Wingeyer, Ana Beatriz Cuatrin, Alejandra Regaldo, Luciana Maria Gagneten, Ana Maria Sasal, Maria Carolina |
author2_role |
author author author author author author author author author author |
dc.subject.none.fl_str_mv |
Pesticides Watersheds Surface Water Environmental Monitoring Plaguicidas Cuencas Hidrográficas Agua Superficial Vigilancia Ambiental Entre Ríos Arroyo Estacas Estacas Stream |
topic |
Pesticides Watersheds Surface Water Environmental Monitoring Plaguicidas Cuencas Hidrográficas Agua Superficial Vigilancia Ambiental Entre Ríos Arroyo Estacas Estacas Stream |
dc.description.none.fl_txt_mv |
The Espinal region (Entre Ríos, Argentina) has sufered land use changes caused by expansion of the agricultural frontier. This expansion has led to an increased use of pesticides. This study is aimed at better understanding the spatial distribu tion of pesticides in surface water of the Estacas stream, a representative basin of the Espinal region, associated with crop production. The location and proportion of area with soybean, maize, and wheat crops in each catchment area of the basin were estimated, and surface water samples were taken to perform a pesticide screening during a period of one year. Soybean represented approximately 71% of the total cultivated area of the basin, whereas maize and wheat accounted for 15% and 14%, respectively. The analysis of 125 analytes showed the presence of 19 pesticides. The pesticide load maps showed that atrazine was detected in an area of relatively low catchment compared to other pesticides as glyphosate, which is applied in all the agricultural felds of the basin. The load of metolachlor and S-metolachlor covered a large area of the basin. The highest recorded concentrations of these pesticides were 86 μg L−1 of atrazine, 24 μg L−1 of metolachlor, 19 μg L−1 of glyphosate, and 15 μg L−1 of S-metolachlor. The results allow better understanding the environmental distribution of pesticides associ ated with pest control in the crops of the basin studied, the doses and times of application, and the variation in the rainfall in the basin. This study provides relevant information about how aquatic ecosystems in agricultural basins receive the difuse contribution of pesticides, representing potential sources of water pollution. Also, the results allow supporting the design of agricultural practices and politics to improve land-use planning for the development of sustainable basins. EEA Paraná Fil: Van Opstal, Natalia Veronica. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina Fil: Gabioud, Emmanuel Adrian. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina Fil: Seehaus, Mariela. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina Fil: Pighini, Ramiro Joaquin. Consejo Nacional de Investigaciones Científcas y Técnicas (CONICET), Santa Fe; Argentina Fil: Wilson, Marcelo German. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina Fil: Wingeyer, Ana Beatriz. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina Fil: Cuatrin, Alejandra. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina Fil: Regaldo, Luciana Maria. Consejo Nacional de Investigaciones Científcas y Técnicas (CONICET), Santa Fe; Argentina Fil: Regaldo, Luciana Maria. Universidad Nacional del Litoral. Facultad de Humanidades y Ciencias (FHUC). Departamento de Ciencias Naturales. Laboratorio de Ecotoxicología; Argentina Fil: Gagneten, Ana Maria. Universidad Nacional del Litoral. Facultad de Humanidades y Ciencias (FHUC). Departamento de Ciencias Naturales. Laboratorio de Ecotoxicología; Argentina Fil: Sasal, Maria Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina |
description |
The Espinal region (Entre Ríos, Argentina) has sufered land use changes caused by expansion of the agricultural frontier. This expansion has led to an increased use of pesticides. This study is aimed at better understanding the spatial distribu tion of pesticides in surface water of the Estacas stream, a representative basin of the Espinal region, associated with crop production. The location and proportion of area with soybean, maize, and wheat crops in each catchment area of the basin were estimated, and surface water samples were taken to perform a pesticide screening during a period of one year. Soybean represented approximately 71% of the total cultivated area of the basin, whereas maize and wheat accounted for 15% and 14%, respectively. The analysis of 125 analytes showed the presence of 19 pesticides. The pesticide load maps showed that atrazine was detected in an area of relatively low catchment compared to other pesticides as glyphosate, which is applied in all the agricultural felds of the basin. The load of metolachlor and S-metolachlor covered a large area of the basin. The highest recorded concentrations of these pesticides were 86 μg L−1 of atrazine, 24 μg L−1 of metolachlor, 19 μg L−1 of glyphosate, and 15 μg L−1 of S-metolachlor. The results allow better understanding the environmental distribution of pesticides associ ated with pest control in the crops of the basin studied, the doses and times of application, and the variation in the rainfall in the basin. This study provides relevant information about how aquatic ecosystems in agricultural basins receive the difuse contribution of pesticides, representing potential sources of water pollution. Also, the results allow supporting the design of agricultural practices and politics to improve land-use planning for the development of sustainable basins. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023-01-23T14:12:08Z 2023-01-23T14:12:08Z 2023-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/20.500.12123/13921 https://awsjournal.org/article/glyphosate-resistant-gr-soybean-and-corn-in-brazil-past-present-and-future/ Van Opstal, N.V., Gabioud, E.A., Seehaus, M.S. et al. Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production. Environ Sci Pollut Res (2023). https://doi.org/10.1007/s11356-023-25373-2 1614-7499 https://doi.org/10.51694/AdvWeedSci/2022;40:seventy-five004 |
url |
http://hdl.handle.net/20.500.12123/13921 https://awsjournal.org/article/glyphosate-resistant-gr-soybean-and-corn-in-brazil-past-present-and-future/ https://doi.org/10.51694/AdvWeedSci/2022;40:seventy-five004 |
identifier_str_mv |
Van Opstal, N.V., Gabioud, E.A., Seehaus, M.S. et al. Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production. Environ Sci Pollut Res (2023). https://doi.org/10.1007/s11356-023-25373-2 1614-7499 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repograntAgreement/INTA/2019-PD-E2-I039-002/2019-PD-E2-I039-002/AR./REMEDIACIÓN DE SUELOS Y AGUAS Y RESTAURACIÓN ECOLÓGICA DE SISTEMAS DEGRADADOS POR USO AGROPECUARIO, AGROINDUSTRIAL Y ACTIVIDADES EXTRACTIVAS info:eu-repograntAgreement/INTA/2019-PE-E2-I046-001/2019-PE-E2-I046-001/AR./Evaluación de la dinámica de la sostenibilidad de territorios y sistemas de producción. Indicadores info:eu-repograntAgreement/INTA/2019-PE-E2-I041-001/2019-PE-E2-I041-001/AR./Aportes para la gestión integrada de los recursos hídricos (GIRH) en cuencas del Sistema Agroalimentario Argentino |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/restrictedAccess |
eu_rights_str_mv |
restrictedAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.coverage.none.fl_str_mv |
Entre Ríos .......... (province) (World, South America, Argentina) 1001237 |
dc.publisher.none.fl_str_mv |
Springer |
publisher.none.fl_str_mv |
Springer |
dc.source.none.fl_str_mv |
Environmental science and pollution research (20 January 2023) reponame:INTA Digital (INTA) instname:Instituto Nacional de Tecnología Agropecuaria |
reponame_str |
INTA Digital (INTA) |
collection |
INTA Digital (INTA) |
instname_str |
Instituto Nacional de Tecnología Agropecuaria |
repository.name.fl_str_mv |
INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria |
repository.mail.fl_str_mv |
tripaldi.nicolas@inta.gob.ar |
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1846143556748574720 |
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12.712165 |