Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production

Autores
Van Opstal, Natalia Veronica; Gabioud, Emmanuel Adrian; Seehaus, Mariela; Pighini, Ramiro Joaquin; Repetti, Maria Rosa; Wilson, Marcelo German; Wingeyer, Ana Beatriz; Cuatrin, Alejandra; Regaldo, Luciana Maria; Gagneten, Ana Maria; Sasal, Maria Carolina
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The Espinal region (Entre Ríos, Argentina) has sufered land use changes caused by expansion of the agricultural frontier. This expansion has led to an increased use of pesticides. This study is aimed at better understanding the spatial distribu tion of pesticides in surface water of the Estacas stream, a representative basin of the Espinal region, associated with crop production. The location and proportion of area with soybean, maize, and wheat crops in each catchment area of the basin were estimated, and surface water samples were taken to perform a pesticide screening during a period of one year. Soybean represented approximately 71% of the total cultivated area of the basin, whereas maize and wheat accounted for 15% and 14%, respectively. The analysis of 125 analytes showed the presence of 19 pesticides. The pesticide load maps showed that atrazine was detected in an area of relatively low catchment compared to other pesticides as glyphosate, which is applied in all the agricultural felds of the basin. The load of metolachlor and S-metolachlor covered a large area of the basin. The highest recorded concentrations of these pesticides were 86 μg L−1 of atrazine, 24 μg L−1 of metolachlor, 19 μg L−1 of glyphosate, and 15 μg L−1 of S-metolachlor. The results allow better understanding the environmental distribution of pesticides associ ated with pest control in the crops of the basin studied, the doses and times of application, and the variation in the rainfall in the basin. This study provides relevant information about how aquatic ecosystems in agricultural basins receive the difuse contribution of pesticides, representing potential sources of water pollution. Also, the results allow supporting the design of agricultural practices and politics to improve land-use planning for the development of sustainable basins.
EEA Paraná
Fil: Van Opstal, Natalia Veronica. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Gabioud, Emmanuel Adrian. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Seehaus, Mariela. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Pighini, Ramiro Joaquin. Consejo Nacional de Investigaciones Científcas y Técnicas (CONICET), Santa Fe; Argentina
Fil: Wilson, Marcelo German. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Wingeyer, Ana Beatriz. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Cuatrin, Alejandra. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Regaldo, Luciana Maria. Consejo Nacional de Investigaciones Científcas y Técnicas (CONICET), Santa Fe; Argentina
Fil: Regaldo, Luciana Maria. Universidad Nacional del Litoral. Facultad de Humanidades y Ciencias (FHUC). Departamento de Ciencias Naturales. Laboratorio de Ecotoxicología; Argentina
Fil: Gagneten, Ana Maria. Universidad Nacional del Litoral. Facultad de Humanidades y Ciencias (FHUC). Departamento de Ciencias Naturales. Laboratorio de Ecotoxicología; Argentina
Fil: Sasal, Maria Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fuente
Environmental science and pollution research (20 January 2023)
Materia
Pesticides
Watersheds
Surface Water
Environmental Monitoring
Plaguicidas
Cuencas Hidrográficas
Agua Superficial
Vigilancia Ambiental
Entre Ríos
Arroyo Estacas
Estacas Stream
Nivel de accesibilidad
acceso restringido
Condiciones de uso
Repositorio
INTA Digital (INTA)
Institución
Instituto Nacional de Tecnología Agropecuaria
OAI Identificador
oai:localhost:20.500.12123/13921

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network_name_str INTA Digital (INTA)
spelling Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop productionVan Opstal, Natalia VeronicaGabioud, Emmanuel AdrianSeehaus, MarielaPighini, Ramiro JoaquinRepetti, Maria RosaWilson, Marcelo GermanWingeyer, Ana BeatrizCuatrin, AlejandraRegaldo, Luciana MariaGagneten, Ana MariaSasal, Maria CarolinaPesticidesWatershedsSurface WaterEnvironmental MonitoringPlaguicidasCuencas HidrográficasAgua SuperficialVigilancia AmbientalEntre RíosArroyo EstacasEstacas StreamThe Espinal region (Entre Ríos, Argentina) has sufered land use changes caused by expansion of the agricultural frontier. This expansion has led to an increased use of pesticides. This study is aimed at better understanding the spatial distribu tion of pesticides in surface water of the Estacas stream, a representative basin of the Espinal region, associated with crop production. The location and proportion of area with soybean, maize, and wheat crops in each catchment area of the basin were estimated, and surface water samples were taken to perform a pesticide screening during a period of one year. Soybean represented approximately 71% of the total cultivated area of the basin, whereas maize and wheat accounted for 15% and 14%, respectively. The analysis of 125 analytes showed the presence of 19 pesticides. The pesticide load maps showed that atrazine was detected in an area of relatively low catchment compared to other pesticides as glyphosate, which is applied in all the agricultural felds of the basin. The load of metolachlor and S-metolachlor covered a large area of the basin. The highest recorded concentrations of these pesticides were 86 μg L−1 of atrazine, 24 μg L−1 of metolachlor, 19 μg L−1 of glyphosate, and 15 μg L−1 of S-metolachlor. The results allow better understanding the environmental distribution of pesticides associ ated with pest control in the crops of the basin studied, the doses and times of application, and the variation in the rainfall in the basin. This study provides relevant information about how aquatic ecosystems in agricultural basins receive the difuse contribution of pesticides, representing potential sources of water pollution. Also, the results allow supporting the design of agricultural practices and politics to improve land-use planning for the development of sustainable basins.EEA ParanáFil: Van Opstal, Natalia Veronica. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; ArgentinaFil: Gabioud, Emmanuel Adrian. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; ArgentinaFil: Seehaus, Mariela. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; ArgentinaFil: Pighini, Ramiro Joaquin. Consejo Nacional de Investigaciones Científcas y Técnicas (CONICET), Santa Fe; ArgentinaFil: Wilson, Marcelo German. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; ArgentinaFil: Wingeyer, Ana Beatriz. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; ArgentinaFil: Cuatrin, Alejandra. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; ArgentinaFil: Regaldo, Luciana Maria. Consejo Nacional de Investigaciones Científcas y Técnicas (CONICET), Santa Fe; ArgentinaFil: Regaldo, Luciana Maria. Universidad Nacional del Litoral. Facultad de Humanidades y Ciencias (FHUC). Departamento de Ciencias Naturales. Laboratorio de Ecotoxicología; ArgentinaFil: Gagneten, Ana Maria. Universidad Nacional del Litoral. Facultad de Humanidades y Ciencias (FHUC). Departamento de Ciencias Naturales. Laboratorio de Ecotoxicología; ArgentinaFil: Sasal, Maria Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; ArgentinaSpringer2023-01-23T14:12:08Z2023-01-23T14:12:08Z2023-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12123/13921https://awsjournal.org/article/glyphosate-resistant-gr-soybean-and-corn-in-brazil-past-present-and-future/Van Opstal, N.V., Gabioud, E.A., Seehaus, M.S. et al. Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production. Environ Sci Pollut Res (2023). https://doi.org/10.1007/s11356-023-25373-21614-7499https://doi.org/10.51694/AdvWeedSci/2022;40:seventy-five004Environmental science and pollution research (20 January 2023)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repograntAgreement/INTA/2019-PD-E2-I039-002/2019-PD-E2-I039-002/AR./REMEDIACIÓN DE SUELOS Y AGUAS Y RESTAURACIÓN ECOLÓGICA DE SISTEMAS DEGRADADOS POR USO AGROPECUARIO, AGROINDUSTRIAL Y ACTIVIDADES EXTRACTIVASinfo:eu-repograntAgreement/INTA/2019-PE-E2-I046-001/2019-PE-E2-I046-001/AR./Evaluación de la dinámica de la sostenibilidad de territorios y sistemas de producción. Indicadoresinfo:eu-repograntAgreement/INTA/2019-PE-E2-I041-001/2019-PE-E2-I041-001/AR./Aportes para la gestión integrada de los recursos hídricos (GIRH) en cuencas del Sistema Agroalimentario ArgentinoEntre Ríos .......... (province) (World, South America, Argentina)1001237info:eu-repo/semantics/restrictedAccess2025-10-16T09:31:04Zoai:localhost:20.500.12123/13921instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-10-16 09:31:05.201INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse
dc.title.none.fl_str_mv Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production
title Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production
spellingShingle Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production
Van Opstal, Natalia Veronica
Pesticides
Watersheds
Surface Water
Environmental Monitoring
Plaguicidas
Cuencas Hidrográficas
Agua Superficial
Vigilancia Ambiental
Entre Ríos
Arroyo Estacas
Estacas Stream
title_short Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production
title_full Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production
title_fullStr Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production
title_full_unstemmed Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production
title_sort Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production
dc.creator.none.fl_str_mv Van Opstal, Natalia Veronica
Gabioud, Emmanuel Adrian
Seehaus, Mariela
Pighini, Ramiro Joaquin
Repetti, Maria Rosa
Wilson, Marcelo German
Wingeyer, Ana Beatriz
Cuatrin, Alejandra
Regaldo, Luciana Maria
Gagneten, Ana Maria
Sasal, Maria Carolina
author Van Opstal, Natalia Veronica
author_facet Van Opstal, Natalia Veronica
Gabioud, Emmanuel Adrian
Seehaus, Mariela
Pighini, Ramiro Joaquin
Repetti, Maria Rosa
Wilson, Marcelo German
Wingeyer, Ana Beatriz
Cuatrin, Alejandra
Regaldo, Luciana Maria
Gagneten, Ana Maria
Sasal, Maria Carolina
author_role author
author2 Gabioud, Emmanuel Adrian
Seehaus, Mariela
Pighini, Ramiro Joaquin
Repetti, Maria Rosa
Wilson, Marcelo German
Wingeyer, Ana Beatriz
Cuatrin, Alejandra
Regaldo, Luciana Maria
Gagneten, Ana Maria
Sasal, Maria Carolina
author2_role author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Pesticides
Watersheds
Surface Water
Environmental Monitoring
Plaguicidas
Cuencas Hidrográficas
Agua Superficial
Vigilancia Ambiental
Entre Ríos
Arroyo Estacas
Estacas Stream
topic Pesticides
Watersheds
Surface Water
Environmental Monitoring
Plaguicidas
Cuencas Hidrográficas
Agua Superficial
Vigilancia Ambiental
Entre Ríos
Arroyo Estacas
Estacas Stream
dc.description.none.fl_txt_mv The Espinal region (Entre Ríos, Argentina) has sufered land use changes caused by expansion of the agricultural frontier. This expansion has led to an increased use of pesticides. This study is aimed at better understanding the spatial distribu tion of pesticides in surface water of the Estacas stream, a representative basin of the Espinal region, associated with crop production. The location and proportion of area with soybean, maize, and wheat crops in each catchment area of the basin were estimated, and surface water samples were taken to perform a pesticide screening during a period of one year. Soybean represented approximately 71% of the total cultivated area of the basin, whereas maize and wheat accounted for 15% and 14%, respectively. The analysis of 125 analytes showed the presence of 19 pesticides. The pesticide load maps showed that atrazine was detected in an area of relatively low catchment compared to other pesticides as glyphosate, which is applied in all the agricultural felds of the basin. The load of metolachlor and S-metolachlor covered a large area of the basin. The highest recorded concentrations of these pesticides were 86 μg L−1 of atrazine, 24 μg L−1 of metolachlor, 19 μg L−1 of glyphosate, and 15 μg L−1 of S-metolachlor. The results allow better understanding the environmental distribution of pesticides associ ated with pest control in the crops of the basin studied, the doses and times of application, and the variation in the rainfall in the basin. This study provides relevant information about how aquatic ecosystems in agricultural basins receive the difuse contribution of pesticides, representing potential sources of water pollution. Also, the results allow supporting the design of agricultural practices and politics to improve land-use planning for the development of sustainable basins.
EEA Paraná
Fil: Van Opstal, Natalia Veronica. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Gabioud, Emmanuel Adrian. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Seehaus, Mariela. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Pighini, Ramiro Joaquin. Consejo Nacional de Investigaciones Científcas y Técnicas (CONICET), Santa Fe; Argentina
Fil: Wilson, Marcelo German. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Wingeyer, Ana Beatriz. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Cuatrin, Alejandra. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
Fil: Regaldo, Luciana Maria. Consejo Nacional de Investigaciones Científcas y Técnicas (CONICET), Santa Fe; Argentina
Fil: Regaldo, Luciana Maria. Universidad Nacional del Litoral. Facultad de Humanidades y Ciencias (FHUC). Departamento de Ciencias Naturales. Laboratorio de Ecotoxicología; Argentina
Fil: Gagneten, Ana Maria. Universidad Nacional del Litoral. Facultad de Humanidades y Ciencias (FHUC). Departamento de Ciencias Naturales. Laboratorio de Ecotoxicología; Argentina
Fil: Sasal, Maria Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná. Departamento de Recursos Naturales y Gestión Ambiental; Argentina
description The Espinal region (Entre Ríos, Argentina) has sufered land use changes caused by expansion of the agricultural frontier. This expansion has led to an increased use of pesticides. This study is aimed at better understanding the spatial distribu tion of pesticides in surface water of the Estacas stream, a representative basin of the Espinal region, associated with crop production. The location and proportion of area with soybean, maize, and wheat crops in each catchment area of the basin were estimated, and surface water samples were taken to perform a pesticide screening during a period of one year. Soybean represented approximately 71% of the total cultivated area of the basin, whereas maize and wheat accounted for 15% and 14%, respectively. The analysis of 125 analytes showed the presence of 19 pesticides. The pesticide load maps showed that atrazine was detected in an area of relatively low catchment compared to other pesticides as glyphosate, which is applied in all the agricultural felds of the basin. The load of metolachlor and S-metolachlor covered a large area of the basin. The highest recorded concentrations of these pesticides were 86 μg L−1 of atrazine, 24 μg L−1 of metolachlor, 19 μg L−1 of glyphosate, and 15 μg L−1 of S-metolachlor. The results allow better understanding the environmental distribution of pesticides associ ated with pest control in the crops of the basin studied, the doses and times of application, and the variation in the rainfall in the basin. This study provides relevant information about how aquatic ecosystems in agricultural basins receive the difuse contribution of pesticides, representing potential sources of water pollution. Also, the results allow supporting the design of agricultural practices and politics to improve land-use planning for the development of sustainable basins.
publishDate 2023
dc.date.none.fl_str_mv 2023-01-23T14:12:08Z
2023-01-23T14:12:08Z
2023-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12123/13921
https://awsjournal.org/article/glyphosate-resistant-gr-soybean-and-corn-in-brazil-past-present-and-future/
Van Opstal, N.V., Gabioud, E.A., Seehaus, M.S. et al. Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production. Environ Sci Pollut Res (2023). https://doi.org/10.1007/s11356-023-25373-2
1614-7499
https://doi.org/10.51694/AdvWeedSci/2022;40:seventy-five004
url http://hdl.handle.net/20.500.12123/13921
https://awsjournal.org/article/glyphosate-resistant-gr-soybean-and-corn-in-brazil-past-present-and-future/
https://doi.org/10.51694/AdvWeedSci/2022;40:seventy-five004
identifier_str_mv Van Opstal, N.V., Gabioud, E.A., Seehaus, M.S. et al. Spatial distribution of pesticides in surface water of the Estacas stream (Argentine Espinal region) associated with crop production. Environ Sci Pollut Res (2023). https://doi.org/10.1007/s11356-023-25373-2
1614-7499
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repograntAgreement/INTA/2019-PD-E2-I039-002/2019-PD-E2-I039-002/AR./REMEDIACIÓN DE SUELOS Y AGUAS Y RESTAURACIÓN ECOLÓGICA DE SISTEMAS DEGRADADOS POR USO AGROPECUARIO, AGROINDUSTRIAL Y ACTIVIDADES EXTRACTIVAS
info:eu-repograntAgreement/INTA/2019-PE-E2-I046-001/2019-PE-E2-I046-001/AR./Evaluación de la dinámica de la sostenibilidad de territorios y sistemas de producción. Indicadores
info:eu-repograntAgreement/INTA/2019-PE-E2-I041-001/2019-PE-E2-I041-001/AR./Aportes para la gestión integrada de los recursos hídricos (GIRH) en cuencas del Sistema Agroalimentario Argentino
dc.rights.none.fl_str_mv info:eu-repo/semantics/restrictedAccess
eu_rights_str_mv restrictedAccess
dc.format.none.fl_str_mv application/pdf
dc.coverage.none.fl_str_mv Entre Ríos .......... (province) (World, South America, Argentina)
1001237
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv Environmental science and pollution research (20 January 2023)
reponame:INTA Digital (INTA)
instname:Instituto Nacional de Tecnología Agropecuaria
reponame_str INTA Digital (INTA)
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instname_str Instituto Nacional de Tecnología Agropecuaria
repository.name.fl_str_mv INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria
repository.mail.fl_str_mv tripaldi.nicolas@inta.gob.ar
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