Presence of pesticides in surface water from four sub-basins in Argentina

Autores
De Geronimo, Eduardo; Aparicio, Virginia Carolina; Barbaro, Sebastian Ernesto; Portocarrero, Rocio; Jaime, Sebastián Andrés; Costa, Jose Luis
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Argentina has 31 million hectares given over to agriculture comprising 2.2% of the world’s total area under cultivation (Stock Exchange of Rosario, Argentina). Despite the intensity of this agricultural activity, data on pesticide pollution in surface water are rather scarce. In this sense, the aim of this work is to determine the presence of pesticides in surface water of four agricultural sub-basins of Argentine. An environmental monitoring was carried out to determine the impact of twenty-nine pesticides used in agricultural activities on the surface water quality of agricultural areas within the San Vicente, Azul, Buenos Aires southeast and Mista stream sub-basins. The samples were analyzed by solid-phase extraction (SPE) using OASIS HLB 60 mg cartridges and ultra-high-pressure liquid chromatography coupled to tandem mass spectrometry (UHPLC/MSMS) that provided good analytical quality parameters. The southeast of Buenos Aires was the site with the highest frequency of pesticides detection, followed by Azul and San Vicente microbasins. The most detected pesticides, considering all surface water samples, were atrazine, tebuconazole and diethyltoluamide with maximum concentration levels of 1.4, 0.035, and 0.701 μg L−1, respectively. The results obtained for all basins studied show the presence of residual pesticides in surface waters according the different agricultural activities developed.
EEA Balcarce
Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce, Argentina
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: Barbaro, Sebastian Ernesto. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Cerro Azul; Argentina
Fil: Portocarrero, Rocio. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Famaillá; Argentina
Fil: Jaime, Sebastian Andrés. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Cuenca del Salado. Agencia De Extensión Rural Azul; Argentina
Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fuente
Chemosphere 107 : 423-431 (July 2014)
Materia
Agua Superficial
Plaguicidas
Cromatografía
Vigilancia
Surface Water
Pesticides
Chromatography
Monitoring
Pesticidas
Monitoreo
Argentina
Nivel de accesibilidad
acceso restringido
Condiciones de uso
Repositorio
INTA Digital (INTA)
Institución
Instituto Nacional de Tecnología Agropecuaria
OAI Identificador
oai:localhost:20.500.12123/4326
Acceder
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spelling Presence of pesticides in surface water from four sub-basins in ArgentinaDe Geronimo, EduardoAparicio, Virginia CarolinaBarbaro, Sebastian ErnestoPortocarrero, RocioJaime, Sebastián AndrésCosta, Jose LuisAgua SuperficialPlaguicidasCromatografíaVigilanciaSurface WaterPesticidesChromatographyMonitoringPesticidasMonitoreoArgentinaArgentina has 31 million hectares given over to agriculture comprising 2.2% of the world’s total area under cultivation (Stock Exchange of Rosario, Argentina). Despite the intensity of this agricultural activity, data on pesticide pollution in surface water are rather scarce. In this sense, the aim of this work is to determine the presence of pesticides in surface water of four agricultural sub-basins of Argentine. An environmental monitoring was carried out to determine the impact of twenty-nine pesticides used in agricultural activities on the surface water quality of agricultural areas within the San Vicente, Azul, Buenos Aires southeast and Mista stream sub-basins. The samples were analyzed by solid-phase extraction (SPE) using OASIS HLB 60 mg cartridges and ultra-high-pressure liquid chromatography coupled to tandem mass spectrometry (UHPLC/MSMS) that provided good analytical quality parameters. The southeast of Buenos Aires was the site with the highest frequency of pesticides detection, followed by Azul and San Vicente microbasins. The most detected pesticides, considering all surface water samples, were atrazine, tebuconazole and diethyltoluamide with maximum concentration levels of 1.4, 0.035, and 0.701 μg L−1, respectively. The results obtained for all basins studied show the presence of residual pesticides in surface waters according the different agricultural activities developed.EEA BalcarceFil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce, ArgentinaFil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; ArgentinaFil: Barbaro, Sebastian Ernesto. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Cerro Azul; ArgentinaFil: Portocarrero, Rocio. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Famaillá; ArgentinaFil: Jaime, Sebastian Andrés. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Cuenca del Salado. Agencia De Extensión Rural Azul; ArgentinaFil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; ArgentinaElsevier2019-01-24T13:56:43Z2019-01-24T13:56:43Z2014-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12123/4326https://www.sciencedirect.com/science/article/pii/S00456535140010520045-65351879-1298https://doi.org/10.1016/j.chemosphere.2014.01.039Chemosphere 107 : 423-431 (July 2014)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repo/semantics/restrictedAccess2025-09-29T13:44:33Zoai:localhost:20.500.12123/4326instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-09-29 13:44:34.117INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse
dc.title.none.fl_str_mv Presence of pesticides in surface water from four sub-basins in Argentina
title Presence of pesticides in surface water from four sub-basins in Argentina
spellingShingle Presence of pesticides in surface water from four sub-basins in Argentina
De Geronimo, Eduardo
Agua Superficial
Plaguicidas
Cromatografía
Vigilancia
Surface Water
Pesticides
Chromatography
Monitoring
Pesticidas
Monitoreo
Argentina
title_short Presence of pesticides in surface water from four sub-basins in Argentina
title_full Presence of pesticides in surface water from four sub-basins in Argentina
title_fullStr Presence of pesticides in surface water from four sub-basins in Argentina
title_full_unstemmed Presence of pesticides in surface water from four sub-basins in Argentina
title_sort Presence of pesticides in surface water from four sub-basins in Argentina
dc.creator.none.fl_str_mv De Geronimo, Eduardo
Aparicio, Virginia Carolina
Barbaro, Sebastian Ernesto
Portocarrero, Rocio
Jaime, Sebastián Andrés
Costa, Jose Luis
author De Geronimo, Eduardo
author_facet De Geronimo, Eduardo
Aparicio, Virginia Carolina
Barbaro, Sebastian Ernesto
Portocarrero, Rocio
Jaime, Sebastián Andrés
Costa, Jose Luis
author_role author
author2 Aparicio, Virginia Carolina
Barbaro, Sebastian Ernesto
Portocarrero, Rocio
Jaime, Sebastián Andrés
Costa, Jose Luis
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Agua Superficial
Plaguicidas
Cromatografía
Vigilancia
Surface Water
Pesticides
Chromatography
Monitoring
Pesticidas
Monitoreo
Argentina
topic Agua Superficial
Plaguicidas
Cromatografía
Vigilancia
Surface Water
Pesticides
Chromatography
Monitoring
Pesticidas
Monitoreo
Argentina
dc.description.none.fl_txt_mv Argentina has 31 million hectares given over to agriculture comprising 2.2% of the world’s total area under cultivation (Stock Exchange of Rosario, Argentina). Despite the intensity of this agricultural activity, data on pesticide pollution in surface water are rather scarce. In this sense, the aim of this work is to determine the presence of pesticides in surface water of four agricultural sub-basins of Argentine. An environmental monitoring was carried out to determine the impact of twenty-nine pesticides used in agricultural activities on the surface water quality of agricultural areas within the San Vicente, Azul, Buenos Aires southeast and Mista stream sub-basins. The samples were analyzed by solid-phase extraction (SPE) using OASIS HLB 60 mg cartridges and ultra-high-pressure liquid chromatography coupled to tandem mass spectrometry (UHPLC/MSMS) that provided good analytical quality parameters. The southeast of Buenos Aires was the site with the highest frequency of pesticides detection, followed by Azul and San Vicente microbasins. The most detected pesticides, considering all surface water samples, were atrazine, tebuconazole and diethyltoluamide with maximum concentration levels of 1.4, 0.035, and 0.701 μg L−1, respectively. The results obtained for all basins studied show the presence of residual pesticides in surface waters according the different agricultural activities developed.
EEA Balcarce
Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce, Argentina
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: Barbaro, Sebastian Ernesto. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Cerro Azul; Argentina
Fil: Portocarrero, Rocio. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Famaillá; Argentina
Fil: Jaime, Sebastian Andrés. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Cuenca del Salado. Agencia De Extensión Rural Azul; Argentina
Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
description Argentina has 31 million hectares given over to agriculture comprising 2.2% of the world’s total area under cultivation (Stock Exchange of Rosario, Argentina). Despite the intensity of this agricultural activity, data on pesticide pollution in surface water are rather scarce. In this sense, the aim of this work is to determine the presence of pesticides in surface water of four agricultural sub-basins of Argentine. An environmental monitoring was carried out to determine the impact of twenty-nine pesticides used in agricultural activities on the surface water quality of agricultural areas within the San Vicente, Azul, Buenos Aires southeast and Mista stream sub-basins. The samples were analyzed by solid-phase extraction (SPE) using OASIS HLB 60 mg cartridges and ultra-high-pressure liquid chromatography coupled to tandem mass spectrometry (UHPLC/MSMS) that provided good analytical quality parameters. The southeast of Buenos Aires was the site with the highest frequency of pesticides detection, followed by Azul and San Vicente microbasins. The most detected pesticides, considering all surface water samples, were atrazine, tebuconazole and diethyltoluamide with maximum concentration levels of 1.4, 0.035, and 0.701 μg L−1, respectively. The results obtained for all basins studied show the presence of residual pesticides in surface waters according the different agricultural activities developed.
publishDate 2014
dc.date.none.fl_str_mv 2014-07
2019-01-24T13:56:43Z
2019-01-24T13:56:43Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12123/4326
https://www.sciencedirect.com/science/article/pii/S0045653514001052
0045-6535
1879-1298
https://doi.org/10.1016/j.chemosphere.2014.01.039
url http://hdl.handle.net/20.500.12123/4326
https://www.sciencedirect.com/science/article/pii/S0045653514001052
https://doi.org/10.1016/j.chemosphere.2014.01.039
identifier_str_mv 0045-6535
1879-1298
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/restrictedAccess
eu_rights_str_mv restrictedAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv Chemosphere 107 : 423-431 (July 2014)
reponame:INTA Digital (INTA)
instname:Instituto Nacional de Tecnología Agropecuaria
reponame_str INTA Digital (INTA)
collection INTA Digital (INTA)
instname_str Instituto Nacional de Tecnología Agropecuaria
repository.name.fl_str_mv INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria
repository.mail.fl_str_mv tripaldi.nicolas@inta.gob.ar
_version_ 1844619130157662208
score 12.559606

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