Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins

Autores
Aparicio, Virginia Carolina; De Geronimo, Eduardo; Marino, Damian Jose Gabriel; Primost, Jezabel Elena; Carriquiriborde, Pedro; Costa, Jose Luis
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Argentinian agricultural production is fundamentally based on a technological package that combines no-till and glyphosate in the cultivation of transgenic crops. Transgenic crops (soybean, maize and cotton) occupy 23 million hectares. This means that glyphosate is the most employed herbicide in the country, where 180–200 million liters are applied every year. The aim of this work is to study the environmental fate of glyphosate and its major degradation product, aminomethylphosphonic acid (AMPA), in surface water and soil of agricultural basins. Sixteen agricultural sites and forty-four streams in the agricultural basins were sampled three times during 2012. The samples were analyzed by UPLC-MS/MS ESI(+/−). In cultivated soils, glyphosate was detected in concentrations between 35 and 1502 μg kg−1, while AMPA concentration ranged from 299 to 2256 μg kg−1. In the surface water studied, the presence of glyphosate and AMPA was detected in about 15% and 12% of the samples analyzed, respectively. In suspended particulate matter, glyphosate was found in 67% while AMPA was present in 20% of the samples. In streams sediment glyphosate and AMPA were also detected in 66% and 88.5% of the samples respectively. This study is, to our knowledge, the first dealing with glyphosate fate in agricultural soils in Argentina. In the present study, it was demonstrated that glyphosate and AMPA are present in soils under agricultural activity. It was also found that in stream samples the presence of glyphosate and AMPA is relatively more frequent in suspended particulate matter and sediment than in water.
EEA Balcarce
Fil: Aparicio, Virginia. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce, Argentina.
Fil: Marino, Damian Jose Gabriel. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Química. Centro de Investigaciones del Medio Ambiente; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Cientifico Tecnológico La Plata; Argentina
Fil: Primost, Jezabel Elena. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Química. Centro de Investigaciones del Medio Ambiente; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Cientifico Tecnológico La Plata; Argentina
Fil: Carriquiriborde, Pedro. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Química. Centro de Investigaciones del Medio Ambiente; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata; Argentina
Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fuente
Chemosphere 93 (9) : 1866-1873 (November 2013)
Materia
Glifosato
Medio Ambiente
Agua Superficial
Suelo
Sedimento
Glyphosate
Environment
Surface Water
Soil
Sediment
Acido aminometilfosfonico
Aminomethylphosphonic Acid
Nivel de accesibilidad
acceso restringido
Condiciones de uso
Repositorio
INTA Digital (INTA)
Institución
Instituto Nacional de Tecnología Agropecuaria
OAI Identificador
oai:localhost:20.500.12123/4777
Acceder
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oai_identifier_str oai:localhost:20.500.12123/4777
network_acronym_str INTADig
repository_id_str l
network_name_str INTA Digital (INTA)
spelling Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basinsAparicio, Virginia CarolinaDe Geronimo, EduardoMarino, Damian Jose GabrielPrimost, Jezabel ElenaCarriquiriborde, PedroCosta, Jose LuisGlifosatoMedio AmbienteAgua SuperficialSueloSedimentoGlyphosateEnvironmentSurface WaterSoilSedimentAcido aminometilfosfonicoAminomethylphosphonic AcidArgentinian agricultural production is fundamentally based on a technological package that combines no-till and glyphosate in the cultivation of transgenic crops. Transgenic crops (soybean, maize and cotton) occupy 23 million hectares. This means that glyphosate is the most employed herbicide in the country, where 180–200 million liters are applied every year. The aim of this work is to study the environmental fate of glyphosate and its major degradation product, aminomethylphosphonic acid (AMPA), in surface water and soil of agricultural basins. Sixteen agricultural sites and forty-four streams in the agricultural basins were sampled three times during 2012. The samples were analyzed by UPLC-MS/MS ESI(+/−). In cultivated soils, glyphosate was detected in concentrations between 35 and 1502 μg kg−1, while AMPA concentration ranged from 299 to 2256 μg kg−1. In the surface water studied, the presence of glyphosate and AMPA was detected in about 15% and 12% of the samples analyzed, respectively. In suspended particulate matter, glyphosate was found in 67% while AMPA was present in 20% of the samples. In streams sediment glyphosate and AMPA were also detected in 66% and 88.5% of the samples respectively. This study is, to our knowledge, the first dealing with glyphosate fate in agricultural soils in Argentina. In the present study, it was demonstrated that glyphosate and AMPA are present in soils under agricultural activity. It was also found that in stream samples the presence of glyphosate and AMPA is relatively more frequent in suspended particulate matter and sediment than in water.EEA BalcarceFil: Aparicio, Virginia. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; ArgentinaFil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce, Argentina.Fil: Marino, Damian Jose Gabriel. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Química. Centro de Investigaciones del Medio Ambiente; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Cientifico Tecnológico La Plata; ArgentinaFil: Primost, Jezabel Elena. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Química. Centro de Investigaciones del Medio Ambiente; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Cientifico Tecnológico La Plata; ArgentinaFil: Carriquiriborde, Pedro. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Química. Centro de Investigaciones del Medio Ambiente; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata; ArgentinaFil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; ArgentinaElsevier2019-03-28T17:04:29Z2019-03-28T17:04:29Z2013-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttps://www.sciencedirect.com/science/article/pii/S0045653513008837http://hdl.handle.net/20.500.12123/47770045-6535https://doi.org/10.1016/j.chemosphere.2013.06.041Chemosphere 93 (9) : 1866-1873 (November 2013)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repo/semantics/restrictedAccess2025-09-11T10:22:59Zoai:localhost:20.500.12123/4777instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-09-11 10:23:00.101INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse
dc.title.none.fl_str_mv Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
title Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
spellingShingle Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
Aparicio, Virginia Carolina
Glifosato
Medio Ambiente
Agua Superficial
Suelo
Sedimento
Glyphosate
Environment
Surface Water
Soil
Sediment
Acido aminometilfosfonico
Aminomethylphosphonic Acid
title_short Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
title_full Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
title_fullStr Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
title_full_unstemmed Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
title_sort Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
dc.creator.none.fl_str_mv Aparicio, Virginia Carolina
De Geronimo, Eduardo
Marino, Damian Jose Gabriel
Primost, Jezabel Elena
Carriquiriborde, Pedro
Costa, Jose Luis
author Aparicio, Virginia Carolina
author_facet Aparicio, Virginia Carolina
De Geronimo, Eduardo
Marino, Damian Jose Gabriel
Primost, Jezabel Elena
Carriquiriborde, Pedro
Costa, Jose Luis
author_role author
author2 De Geronimo, Eduardo
Marino, Damian Jose Gabriel
Primost, Jezabel Elena
Carriquiriborde, Pedro
Costa, Jose Luis
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Glifosato
Medio Ambiente
Agua Superficial
Suelo
Sedimento
Glyphosate
Environment
Surface Water
Soil
Sediment
Acido aminometilfosfonico
Aminomethylphosphonic Acid
topic Glifosato
Medio Ambiente
Agua Superficial
Suelo
Sedimento
Glyphosate
Environment
Surface Water
Soil
Sediment
Acido aminometilfosfonico
Aminomethylphosphonic Acid
dc.description.none.fl_txt_mv Argentinian agricultural production is fundamentally based on a technological package that combines no-till and glyphosate in the cultivation of transgenic crops. Transgenic crops (soybean, maize and cotton) occupy 23 million hectares. This means that glyphosate is the most employed herbicide in the country, where 180–200 million liters are applied every year. The aim of this work is to study the environmental fate of glyphosate and its major degradation product, aminomethylphosphonic acid (AMPA), in surface water and soil of agricultural basins. Sixteen agricultural sites and forty-four streams in the agricultural basins were sampled three times during 2012. The samples were analyzed by UPLC-MS/MS ESI(+/−). In cultivated soils, glyphosate was detected in concentrations between 35 and 1502 μg kg−1, while AMPA concentration ranged from 299 to 2256 μg kg−1. In the surface water studied, the presence of glyphosate and AMPA was detected in about 15% and 12% of the samples analyzed, respectively. In suspended particulate matter, glyphosate was found in 67% while AMPA was present in 20% of the samples. In streams sediment glyphosate and AMPA were also detected in 66% and 88.5% of the samples respectively. This study is, to our knowledge, the first dealing with glyphosate fate in agricultural soils in Argentina. In the present study, it was demonstrated that glyphosate and AMPA are present in soils under agricultural activity. It was also found that in stream samples the presence of glyphosate and AMPA is relatively more frequent in suspended particulate matter and sediment than in water.
EEA Balcarce
Fil: Aparicio, Virginia. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce, Argentina.
Fil: Marino, Damian Jose Gabriel. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Química. Centro de Investigaciones del Medio Ambiente; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Cientifico Tecnológico La Plata; Argentina
Fil: Primost, Jezabel Elena. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Química. Centro de Investigaciones del Medio Ambiente; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Cientifico Tecnológico La Plata; Argentina
Fil: Carriquiriborde, Pedro. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Química. Centro de Investigaciones del Medio Ambiente; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata; Argentina
Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
description Argentinian agricultural production is fundamentally based on a technological package that combines no-till and glyphosate in the cultivation of transgenic crops. Transgenic crops (soybean, maize and cotton) occupy 23 million hectares. This means that glyphosate is the most employed herbicide in the country, where 180–200 million liters are applied every year. The aim of this work is to study the environmental fate of glyphosate and its major degradation product, aminomethylphosphonic acid (AMPA), in surface water and soil of agricultural basins. Sixteen agricultural sites and forty-four streams in the agricultural basins were sampled three times during 2012. The samples were analyzed by UPLC-MS/MS ESI(+/−). In cultivated soils, glyphosate was detected in concentrations between 35 and 1502 μg kg−1, while AMPA concentration ranged from 299 to 2256 μg kg−1. In the surface water studied, the presence of glyphosate and AMPA was detected in about 15% and 12% of the samples analyzed, respectively. In suspended particulate matter, glyphosate was found in 67% while AMPA was present in 20% of the samples. In streams sediment glyphosate and AMPA were also detected in 66% and 88.5% of the samples respectively. This study is, to our knowledge, the first dealing with glyphosate fate in agricultural soils in Argentina. In the present study, it was demonstrated that glyphosate and AMPA are present in soils under agricultural activity. It was also found that in stream samples the presence of glyphosate and AMPA is relatively more frequent in suspended particulate matter and sediment than in water.
publishDate 2013
dc.date.none.fl_str_mv 2013-11
2019-03-28T17:04:29Z
2019-03-28T17:04:29Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://www.sciencedirect.com/science/article/pii/S0045653513008837
http://hdl.handle.net/20.500.12123/4777
0045-6535
https://doi.org/10.1016/j.chemosphere.2013.06.041
url https://www.sciencedirect.com/science/article/pii/S0045653513008837
http://hdl.handle.net/20.500.12123/4777
https://doi.org/10.1016/j.chemosphere.2013.06.041
identifier_str_mv 0045-6535
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/restrictedAccess
eu_rights_str_mv restrictedAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv Chemosphere 93 (9) : 1866-1873 (November 2013)
reponame:INTA Digital (INTA)
instname:Instituto Nacional de Tecnología Agropecuaria
reponame_str INTA Digital (INTA)
collection INTA Digital (INTA)
instname_str Instituto Nacional de Tecnología Agropecuaria
repository.name.fl_str_mv INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria
repository.mail.fl_str_mv tripaldi.nicolas@inta.gob.ar
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score 12.993085

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