Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins

Autores
Aparicio, Virginia Carolina; de Gerónimo, Eduardo; Marino, Damian Jose Gabriel; Primost, Jezabel Elena; Carriquiriborde, Pedro; Costa, Jose Luis
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Argentinian agricultural production is fundamentally based on a technological package that combines notill and glyphosate in the cultivation of transgenic crops. Transgenic crops (soybean, maize and cotton)occupy 23 million hectares. This means that glyphosate is the most employed herbicide in the country,where 180-200 million liters are applied every year. The aim of this work is to study the environmental fate of glyphosate and its major degradation product, aminomethylphosphonic acid (AMPA), in surface water and soil of agricultural basins. Sixteen agricultural sites and forty-four streams in the agricultural basins were sampled three times during 2012. The samples were analyzed by UPLC-MS/MS ESI(+/). In cultivated soils, glyphosate was detected in concentrations between 35 and 1502 microg/Kg, while AMPA concentration ranged from 299 to 2256 microg/Kg. In the surface water studied, the presence of glyphosate and AMPA was detected in about 15% and 12% of the samples analyzed, respectively. In suspended particulate matter, glyphosate was found in 67% while AMPA was present in 20% of the samples. In streams sediment glyphosate and AMPA were also detected in 66% and 88.5% of the samples respectively. This study is, to our knowledge, the first dealing with glyphosate fate in agricultural soils in Argentina.In the present study, it was demonstrated that glyphosate and AMPA are present in soils under agricultural activity. It was also found that in stream samples the presence of glyphosate and AMPA is relatively more frequent in suspended particulate matter and sediment than in water
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria; Argentina
Fil: de Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria; Argentina
Fil: Marino, Damian Jose Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Centro de Investigaciones del Mar y la Atmósfera; Argentina
Fil: Primost, Jezabel Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Centro de Investigaciones del Mar y la Atmósfera; Argentina
Fil: Carriquiriborde, Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Centro de Investigaciones del Mar y la Atmósfera; Argentina
Fil: Costa, Jose Luis. Instituto Nacional de Tecnología Agropecuaria; Argentina
Materia
Glyphosate
Ampa
Soil
Surface Water
Sediment
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5138
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/5138
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basinsAparicio, Virginia Carolinade Gerónimo, EduardoMarino, Damian Jose GabrielPrimost, Jezabel ElenaCarriquiriborde, PedroCosta, Jose LuisGlyphosateAmpaSoilSurface WaterSedimenthttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1Argentinian agricultural production is fundamentally based on a technological package that combines notill and glyphosate in the cultivation of transgenic crops. Transgenic crops (soybean, maize and cotton)occupy 23 million hectares. This means that glyphosate is the most employed herbicide in the country,where 180-200 million liters are applied every year. The aim of this work is to study the environmental fate of glyphosate and its major degradation product, aminomethylphosphonic acid (AMPA), in surface water and soil of agricultural basins. Sixteen agricultural sites and forty-four streams in the agricultural basins were sampled three times during 2012. The samples were analyzed by UPLC-MS/MS ESI(+/). In cultivated soils, glyphosate was detected in concentrations between 35 and 1502 microg/Kg, while AMPA concentration ranged from 299 to 2256 microg/Kg. In the surface water studied, the presence of glyphosate and AMPA was detected in about 15% and 12% of the samples analyzed, respectively. In suspended particulate matter, glyphosate was found in 67% while AMPA was present in 20% of the samples. In streams sediment glyphosate and AMPA were also detected in 66% and 88.5% of the samples respectively. This study is, to our knowledge, the first dealing with glyphosate fate in agricultural soils in Argentina.In the present study, it was demonstrated that glyphosate and AMPA are present in soils under agricultural activity. It was also found that in stream samples the presence of glyphosate and AMPA is relatively more frequent in suspended particulate matter and sediment than in waterFil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria; ArgentinaFil: de Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria; ArgentinaFil: Marino, Damian Jose Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Centro de Investigaciones del Mar y la Atmósfera; ArgentinaFil: Primost, Jezabel Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Centro de Investigaciones del Mar y la Atmósfera; ArgentinaFil: Carriquiriborde, Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Centro de Investigaciones del Mar y la Atmósfera; ArgentinaFil: Costa, Jose Luis. Instituto Nacional de Tecnología Agropecuaria; ArgentinaElsevier2013-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5138Aparicio, Virginia Carolina; de Gerónimo, Eduardo; Marino, Damian Jose Gabriel; Primost, Jezabel Elena; Carriquiriborde, Pedro; et al.; Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins; Elsevier; Chemosphere; 93; 9; 7-2013; 1866–18730045-6535enginfo:eu-repo/semantics/altIdentifier/pmid/23849835info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0045653513008837#info:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemosphere.2013.06.041info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:57:37Zoai:ri.conicet.gov.ar:11336/5138instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:57:37.621CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
title Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
spellingShingle Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
Aparicio, Virginia Carolina
Glyphosate
Ampa
Soil
Surface Water
Sediment
title_short Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
title_full Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
title_fullStr Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
title_full_unstemmed Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
title_sort Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins
dc.creator.none.fl_str_mv Aparicio, Virginia Carolina
de Gerónimo, Eduardo
Marino, Damian Jose Gabriel
Primost, Jezabel Elena
Carriquiriborde, Pedro
Costa, Jose Luis
author Aparicio, Virginia Carolina
author_facet Aparicio, Virginia Carolina
de Gerónimo, Eduardo
Marino, Damian Jose Gabriel
Primost, Jezabel Elena
Carriquiriborde, Pedro
Costa, Jose Luis
author_role author
author2 de Gerónimo, Eduardo
Marino, Damian Jose Gabriel
Primost, Jezabel Elena
Carriquiriborde, Pedro
Costa, Jose Luis
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Glyphosate
Ampa
Soil
Surface Water
Sediment
topic Glyphosate
Ampa
Soil
Surface Water
Sediment
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Argentinian agricultural production is fundamentally based on a technological package that combines notill and glyphosate in the cultivation of transgenic crops. Transgenic crops (soybean, maize and cotton)occupy 23 million hectares. This means that glyphosate is the most employed herbicide in the country,where 180-200 million liters are applied every year. The aim of this work is to study the environmental fate of glyphosate and its major degradation product, aminomethylphosphonic acid (AMPA), in surface water and soil of agricultural basins. Sixteen agricultural sites and forty-four streams in the agricultural basins were sampled three times during 2012. The samples were analyzed by UPLC-MS/MS ESI(+/). In cultivated soils, glyphosate was detected in concentrations between 35 and 1502 microg/Kg, while AMPA concentration ranged from 299 to 2256 microg/Kg. In the surface water studied, the presence of glyphosate and AMPA was detected in about 15% and 12% of the samples analyzed, respectively. In suspended particulate matter, glyphosate was found in 67% while AMPA was present in 20% of the samples. In streams sediment glyphosate and AMPA were also detected in 66% and 88.5% of the samples respectively. This study is, to our knowledge, the first dealing with glyphosate fate in agricultural soils in Argentina.In the present study, it was demonstrated that glyphosate and AMPA are present in soils under agricultural activity. It was also found that in stream samples the presence of glyphosate and AMPA is relatively more frequent in suspended particulate matter and sediment than in water
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria; Argentina
Fil: de Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria; Argentina
Fil: Marino, Damian Jose Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Centro de Investigaciones del Mar y la Atmósfera; Argentina
Fil: Primost, Jezabel Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Centro de Investigaciones del Mar y la Atmósfera; Argentina
Fil: Carriquiriborde, Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Centro de Investigaciones del Mar y la Atmósfera; Argentina
Fil: Costa, Jose Luis. Instituto Nacional de Tecnología Agropecuaria; Argentina
description Argentinian agricultural production is fundamentally based on a technological package that combines notill and glyphosate in the cultivation of transgenic crops. Transgenic crops (soybean, maize and cotton)occupy 23 million hectares. This means that glyphosate is the most employed herbicide in the country,where 180-200 million liters are applied every year. The aim of this work is to study the environmental fate of glyphosate and its major degradation product, aminomethylphosphonic acid (AMPA), in surface water and soil of agricultural basins. Sixteen agricultural sites and forty-four streams in the agricultural basins were sampled three times during 2012. The samples were analyzed by UPLC-MS/MS ESI(+/). In cultivated soils, glyphosate was detected in concentrations between 35 and 1502 microg/Kg, while AMPA concentration ranged from 299 to 2256 microg/Kg. In the surface water studied, the presence of glyphosate and AMPA was detected in about 15% and 12% of the samples analyzed, respectively. In suspended particulate matter, glyphosate was found in 67% while AMPA was present in 20% of the samples. In streams sediment glyphosate and AMPA were also detected in 66% and 88.5% of the samples respectively. This study is, to our knowledge, the first dealing with glyphosate fate in agricultural soils in Argentina.In the present study, it was demonstrated that glyphosate and AMPA are present in soils under agricultural activity. It was also found that in stream samples the presence of glyphosate and AMPA is relatively more frequent in suspended particulate matter and sediment than in water
publishDate 2013
dc.date.none.fl_str_mv 2013-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5138
Aparicio, Virginia Carolina; de Gerónimo, Eduardo; Marino, Damian Jose Gabriel; Primost, Jezabel Elena; Carriquiriborde, Pedro; et al.; Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins; Elsevier; Chemosphere; 93; 9; 7-2013; 1866–1873
0045-6535
url http://hdl.handle.net/11336/5138
identifier_str_mv Aparicio, Virginia Carolina; de Gerónimo, Eduardo; Marino, Damian Jose Gabriel; Primost, Jezabel Elena; Carriquiriborde, Pedro; et al.; Environmental fate of glyphosate and aminomethylphosphonic acid in surface waters and soil of agricultural basins; Elsevier; Chemosphere; 93; 9; 7-2013; 1866–1873
0045-6535
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/pmid/23849835
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0045653513008837#
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemosphere.2013.06.041
info:eu-repo/semantics/altIdentifier/doi/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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