Structural Transition in the Growth of Copper Terephthalate Metal–Organic Frameworks: Understanding the Effect of the Synthetic Protocol and Its Impact on Electrochemical Behavior...

Autores
Rodriguez Villa, Sara Luz; Ortega Moreno, Gabriela Andreines; Sánchez Sánchez, Manuel; Fernandez, Jose Luis; Zamaro, Juan Manuel
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Some copper-based metal–organic frameworks show promise for use as electrocatalysts because they allow for an electrode configuration in which copper species with redox and electron-conducting properties are immobilized in a three-dimensional arrangement. This work shows that the synthesis of copper terephthalates (Cu-BDCs) can lead to rigid structures of the copper hydroxyterephthalate-type or flexible structures that are isoreticular to the MOF-2 type, depending solely on the synthesis route. Here, a detailed analysis of the syntheses of the crystals is carried out employing protocols with different solvents as well as conventional or microwave-assisted solvothermal methods. All solids were fully characterized by a combination of characterization techniques, such as FE-SEM, T-XRD, TGA, and FTIR, and their electrochemical redox responses were also evaluated by cyclic voltammetry. A correlation between the Cu-BDCs structures and their electrochemical behaviors was established and a new version of an electroactive copper hy- droxyterephthalate was synthesized by a microwave method in 3 h with a dimethylformamide-free protocol. This Cu-BDC was obtained as dispersed nanoflakes with a high amount of copper sites and the capacity to be reversibly electroreduced-oxidized and showed catalytic activity in the oxygen reduction reaction (ORR).
Fil: Rodriguez Villa, Sara Luz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Ortega Moreno, Gabriela Andreines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Sánchez Sánchez, Manuel. Consejo Superior de Investigaciones Científicas; España
Fil: Fernandez, Jose Luis. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
Fil: Zamaro, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
METAL-ORGANIC FRAMEWORK
COPPER TEREPHTHALATE MOF
NANOFLAKES
MICROWAVE SYNTHESIS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/240673
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/240673
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Structural Transition in the Growth of Copper Terephthalate Metal–Organic Frameworks: Understanding the Effect of the Synthetic Protocol and Its Impact on Electrochemical BehaviorRodriguez Villa, Sara LuzOrtega Moreno, Gabriela AndreinesSánchez Sánchez, ManuelFernandez, Jose LuisZamaro, Juan ManuelMETAL-ORGANIC FRAMEWORKCOPPER TEREPHTHALATE MOFNANOFLAKESMICROWAVE SYNTHESIShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Some copper-based metal–organic frameworks show promise for use as electrocatalysts because they allow for an electrode configuration in which copper species with redox and electron-conducting properties are immobilized in a three-dimensional arrangement. This work shows that the synthesis of copper terephthalates (Cu-BDCs) can lead to rigid structures of the copper hydroxyterephthalate-type or flexible structures that are isoreticular to the MOF-2 type, depending solely on the synthesis route. Here, a detailed analysis of the syntheses of the crystals is carried out employing protocols with different solvents as well as conventional or microwave-assisted solvothermal methods. All solids were fully characterized by a combination of characterization techniques, such as FE-SEM, T-XRD, TGA, and FTIR, and their electrochemical redox responses were also evaluated by cyclic voltammetry. A correlation between the Cu-BDCs structures and their electrochemical behaviors was established and a new version of an electroactive copper hy- droxyterephthalate was synthesized by a microwave method in 3 h with a dimethylformamide-free protocol. This Cu-BDC was obtained as dispersed nanoflakes with a high amount of copper sites and the capacity to be reversibly electroreduced-oxidized and showed catalytic activity in the oxygen reduction reaction (ORR).Fil: Rodriguez Villa, Sara Luz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Ortega Moreno, Gabriela Andreines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Sánchez Sánchez, Manuel. Consejo Superior de Investigaciones Científicas; EspañaFil: Fernandez, Jose Luis. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; ArgentinaFil: Zamaro, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaMultidisciplinary Digital Publishing Institute2023-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/240673Rodriguez Villa, Sara Luz; Ortega Moreno, Gabriela Andreines; Sánchez Sánchez, Manuel; Fernandez, Jose Luis; Zamaro, Juan Manuel; Structural Transition in the Growth of Copper Terephthalate Metal–Organic Frameworks: Understanding the Effect of the Synthetic Protocol and Its Impact on Electrochemical Behavior; Multidisciplinary Digital Publishing Institute; Coatings; 13; 12; 12-2023; 2065-20832079-6412CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2079-6412/13/12/2065info:eu-repo/semantics/altIdentifier/doi/10.3390/coatings13122065info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:23:07Zoai:ri.conicet.gov.ar:11336/240673instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:23:07.663CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Structural Transition in the Growth of Copper Terephthalate Metal–Organic Frameworks: Understanding the Effect of the Synthetic Protocol and Its Impact on Electrochemical Behavior
title Structural Transition in the Growth of Copper Terephthalate Metal–Organic Frameworks: Understanding the Effect of the Synthetic Protocol and Its Impact on Electrochemical Behavior
spellingShingle Structural Transition in the Growth of Copper Terephthalate Metal–Organic Frameworks: Understanding the Effect of the Synthetic Protocol and Its Impact on Electrochemical Behavior
Rodriguez Villa, Sara Luz
METAL-ORGANIC FRAMEWORK
COPPER TEREPHTHALATE MOF
NANOFLAKES
MICROWAVE SYNTHESIS
title_short Structural Transition in the Growth of Copper Terephthalate Metal–Organic Frameworks: Understanding the Effect of the Synthetic Protocol and Its Impact on Electrochemical Behavior
title_full Structural Transition in the Growth of Copper Terephthalate Metal–Organic Frameworks: Understanding the Effect of the Synthetic Protocol and Its Impact on Electrochemical Behavior
title_fullStr Structural Transition in the Growth of Copper Terephthalate Metal–Organic Frameworks: Understanding the Effect of the Synthetic Protocol and Its Impact on Electrochemical Behavior
title_full_unstemmed Structural Transition in the Growth of Copper Terephthalate Metal–Organic Frameworks: Understanding the Effect of the Synthetic Protocol and Its Impact on Electrochemical Behavior
title_sort Structural Transition in the Growth of Copper Terephthalate Metal–Organic Frameworks: Understanding the Effect of the Synthetic Protocol and Its Impact on Electrochemical Behavior
dc.creator.none.fl_str_mv Rodriguez Villa, Sara Luz
Ortega Moreno, Gabriela Andreines
Sánchez Sánchez, Manuel
Fernandez, Jose Luis
Zamaro, Juan Manuel
author Rodriguez Villa, Sara Luz
author_facet Rodriguez Villa, Sara Luz
Ortega Moreno, Gabriela Andreines
Sánchez Sánchez, Manuel
Fernandez, Jose Luis
Zamaro, Juan Manuel
author_role author
author2 Ortega Moreno, Gabriela Andreines
Sánchez Sánchez, Manuel
Fernandez, Jose Luis
Zamaro, Juan Manuel
author2_role author
author
author
author
dc.subject.none.fl_str_mv METAL-ORGANIC FRAMEWORK
COPPER TEREPHTHALATE MOF
NANOFLAKES
MICROWAVE SYNTHESIS
topic METAL-ORGANIC FRAMEWORK
COPPER TEREPHTHALATE MOF
NANOFLAKES
MICROWAVE SYNTHESIS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Some copper-based metal–organic frameworks show promise for use as electrocatalysts because they allow for an electrode configuration in which copper species with redox and electron-conducting properties are immobilized in a three-dimensional arrangement. This work shows that the synthesis of copper terephthalates (Cu-BDCs) can lead to rigid structures of the copper hydroxyterephthalate-type or flexible structures that are isoreticular to the MOF-2 type, depending solely on the synthesis route. Here, a detailed analysis of the syntheses of the crystals is carried out employing protocols with different solvents as well as conventional or microwave-assisted solvothermal methods. All solids were fully characterized by a combination of characterization techniques, such as FE-SEM, T-XRD, TGA, and FTIR, and their electrochemical redox responses were also evaluated by cyclic voltammetry. A correlation between the Cu-BDCs structures and their electrochemical behaviors was established and a new version of an electroactive copper hy- droxyterephthalate was synthesized by a microwave method in 3 h with a dimethylformamide-free protocol. This Cu-BDC was obtained as dispersed nanoflakes with a high amount of copper sites and the capacity to be reversibly electroreduced-oxidized and showed catalytic activity in the oxygen reduction reaction (ORR).
Fil: Rodriguez Villa, Sara Luz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Ortega Moreno, Gabriela Andreines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Sánchez Sánchez, Manuel. Consejo Superior de Investigaciones Científicas; España
Fil: Fernandez, Jose Luis. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
Fil: Zamaro, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description Some copper-based metal–organic frameworks show promise for use as electrocatalysts because they allow for an electrode configuration in which copper species with redox and electron-conducting properties are immobilized in a three-dimensional arrangement. This work shows that the synthesis of copper terephthalates (Cu-BDCs) can lead to rigid structures of the copper hydroxyterephthalate-type or flexible structures that are isoreticular to the MOF-2 type, depending solely on the synthesis route. Here, a detailed analysis of the syntheses of the crystals is carried out employing protocols with different solvents as well as conventional or microwave-assisted solvothermal methods. All solids were fully characterized by a combination of characterization techniques, such as FE-SEM, T-XRD, TGA, and FTIR, and their electrochemical redox responses were also evaluated by cyclic voltammetry. A correlation between the Cu-BDCs structures and their electrochemical behaviors was established and a new version of an electroactive copper hy- droxyterephthalate was synthesized by a microwave method in 3 h with a dimethylformamide-free protocol. This Cu-BDC was obtained as dispersed nanoflakes with a high amount of copper sites and the capacity to be reversibly electroreduced-oxidized and showed catalytic activity in the oxygen reduction reaction (ORR).
publishDate 2023
dc.date.none.fl_str_mv 2023-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/240673
Rodriguez Villa, Sara Luz; Ortega Moreno, Gabriela Andreines; Sánchez Sánchez, Manuel; Fernandez, Jose Luis; Zamaro, Juan Manuel; Structural Transition in the Growth of Copper Terephthalate Metal–Organic Frameworks: Understanding the Effect of the Synthetic Protocol and Its Impact on Electrochemical Behavior; Multidisciplinary Digital Publishing Institute; Coatings; 13; 12; 12-2023; 2065-2083
2079-6412
CONICET Digital
CONICET
url http://hdl.handle.net/11336/240673
identifier_str_mv Rodriguez Villa, Sara Luz; Ortega Moreno, Gabriela Andreines; Sánchez Sánchez, Manuel; Fernandez, Jose Luis; Zamaro, Juan Manuel; Structural Transition in the Growth of Copper Terephthalate Metal–Organic Frameworks: Understanding the Effect of the Synthetic Protocol and Its Impact on Electrochemical Behavior; Multidisciplinary Digital Publishing Institute; Coatings; 13; 12; 12-2023; 2065-2083
2079-6412
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2079-6412/13/12/2065
info:eu-repo/semantics/altIdentifier/doi/10.3390/coatings13122065
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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