Effect of Addition of Cross-Linked Starch on the Properties of Degraded PBAT Poly(butylene adipate-co-terephthalate) Films

Autores
Grimaut, Denise Agostina; Alves da Silva, Jania Betania; Lemos, Paulo Vitor França; Cruz Correia, Paulo Romano; Santos Santana, Jamille; Cavalcanti Pessôa, Luiggi; Estevez Areco, Santiago; Fama, Lucia Mercedes; Goyanes, Silvia Nair; Rodrigues Marcelino, Henrique; de Jesus Assis, Denilson; Oliveira de Souza, Carolina
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work aimed to evaluate the properties of butylene adipate-co-terephthalate (PBAT) degraded after 1800 days of storage (DPBAT) by preparing blends (films) with crosslinked starch (Cm) through extrusion and thermocompression. Different ratios of DPBAT:Cm (70:30, 60:40, and 50:50 m/m) were prepared. The incorporation of Cm into DPBAT significantly changed the properties of the films by making them stiffer (increasing Young’s modulus by up to 50%) and increasing the thermal resistance of DPBAT. The presence of crosslinked starch in the films made them less hydrophobic (with decreased contact angle and increased moisture content), but these parameters did not vary linearly with changes in the content of crosslinked starch in the blend (DPBAT:Cm). The microscopic images show an inhomogeneous distribution of Cm granules in the DPBAT matrix. Thus, the films prepared with PBAT show a significant decrease in their mechanical parameters and heat resistance after long-term storage. However, the preparation of blends of degraded DPBAT with crosslinked starch promoted changes in the properties of the films prepared by thermocompression, which could be useful for disposable packaging.
Fil: Grimaut, Denise Agostina. Universidade Federal da Bahia; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigación de la Cadena Láctea. - Instituto Nacional de Tecnología Agropecuaria. Centro Regional Santa Fe. Estación Experimental Agropecuaria Rafaela. Instituto de Investigación de la Cadena Láctea; Argentina
Fil: Alves da Silva, Jania Betania. Universidade Federal da Bahia; Brasil. Universidade Federal da Recôncavo da Bahia; Brasil
Fil: Lemos, Paulo Vitor França. Universidade Federal da Bahia; Brasil
Fil: Cruz Correia, Paulo Romano. Universidade Federal da Bahia; Brasil
Fil: Santos Santana, Jamille. Universidade Federal da Bahia; Brasil
Fil: Cavalcanti Pessôa, Luiggi. Universidade Federal da Bahia; Brasil
Fil: Estevez Areco, Santiago. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física. Laboratorio de Polímeros y Materiales Compuestos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
Fil: Fama, Lucia Mercedes. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física. Laboratorio de Polímeros y Materiales Compuestos; Argentina
Fil: Goyanes, Silvia Nair. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física. Laboratorio de Polímeros y Materiales Compuestos; Argentina
Fil: Rodrigues Marcelino, Henrique. Universidade Federal da Bahia; Brasil
Fil: de Jesus Assis, Denilson. Universidade Federal da Bahia; Brasil
Fil: Oliveira de Souza, Carolina. Universidade Federal da Bahia; Brasil
Materia
BLENDS
CROSSLINKING
PLOY(BUTYLENE ADIPATE-CO-TEREPHTHALATE)
POTATO STARCH
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/226116
Acceder
id CONICETDig_15b34f7489f91b29d247129b3cb0028e
oai_identifier_str oai:ri.conicet.gov.ar:11336/226116
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effect of Addition of Cross-Linked Starch on the Properties of Degraded PBAT Poly(butylene adipate-co-terephthalate) FilmsGrimaut, Denise AgostinaAlves da Silva, Jania BetaniaLemos, Paulo Vitor FrançaCruz Correia, Paulo RomanoSantos Santana, JamilleCavalcanti Pessôa, LuiggiEstevez Areco, SantiagoFama, Lucia MercedesGoyanes, Silvia NairRodrigues Marcelino, Henriquede Jesus Assis, DenilsonOliveira de Souza, CarolinaBLENDSCROSSLINKINGPLOY(BUTYLENE ADIPATE-CO-TEREPHTHALATE)POTATO STARCHhttps://purl.org/becyt/ford/2.9https://purl.org/becyt/ford/2This work aimed to evaluate the properties of butylene adipate-co-terephthalate (PBAT) degraded after 1800 days of storage (DPBAT) by preparing blends (films) with crosslinked starch (Cm) through extrusion and thermocompression. Different ratios of DPBAT:Cm (70:30, 60:40, and 50:50 m/m) were prepared. The incorporation of Cm into DPBAT significantly changed the properties of the films by making them stiffer (increasing Young’s modulus by up to 50%) and increasing the thermal resistance of DPBAT. The presence of crosslinked starch in the films made them less hydrophobic (with decreased contact angle and increased moisture content), but these parameters did not vary linearly with changes in the content of crosslinked starch in the blend (DPBAT:Cm). The microscopic images show an inhomogeneous distribution of Cm granules in the DPBAT matrix. Thus, the films prepared with PBAT show a significant decrease in their mechanical parameters and heat resistance after long-term storage. However, the preparation of blends of degraded DPBAT with crosslinked starch promoted changes in the properties of the films prepared by thermocompression, which could be useful for disposable packaging.Fil: Grimaut, Denise Agostina. Universidade Federal da Bahia; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigación de la Cadena Láctea. - Instituto Nacional de Tecnología Agropecuaria. Centro Regional Santa Fe. Estación Experimental Agropecuaria Rafaela. Instituto de Investigación de la Cadena Láctea; ArgentinaFil: Alves da Silva, Jania Betania. Universidade Federal da Bahia; Brasil. Universidade Federal da Recôncavo da Bahia; BrasilFil: Lemos, Paulo Vitor França. Universidade Federal da Bahia; BrasilFil: Cruz Correia, Paulo Romano. Universidade Federal da Bahia; BrasilFil: Santos Santana, Jamille. Universidade Federal da Bahia; BrasilFil: Cavalcanti Pessôa, Luiggi. Universidade Federal da Bahia; BrasilFil: Estevez Areco, Santiago. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física. Laboratorio de Polímeros y Materiales Compuestos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; ArgentinaFil: Fama, Lucia Mercedes. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física. Laboratorio de Polímeros y Materiales Compuestos; ArgentinaFil: Goyanes, Silvia Nair. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física. Laboratorio de Polímeros y Materiales Compuestos; ArgentinaFil: Rodrigues Marcelino, Henrique. Universidade Federal da Bahia; BrasilFil: de Jesus Assis, Denilson. Universidade Federal da Bahia; BrasilFil: Oliveira de Souza, Carolina. Universidade Federal da Bahia; BrasilMultidisciplinary Digital Publishing Institute2023-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/226116Grimaut, Denise Agostina; Alves da Silva, Jania Betania ; Lemos, Paulo Vitor França; Cruz Correia, Paulo Romano ; Santos Santana, Jamille ; et al.; Effect of Addition of Cross-Linked Starch on the Properties of Degraded PBAT Poly(butylene adipate-co-terephthalate) Films; Multidisciplinary Digital Publishing Institute; Polymers; 15; 14; 7-2023; 1-152073-4360CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4360/15/14/3106info:eu-repo/semantics/altIdentifier/doi/10.3390/polym15143106info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:32:28Zoai:ri.conicet.gov.ar:11336/226116instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:32:28.729CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effect of Addition of Cross-Linked Starch on the Properties of Degraded PBAT Poly(butylene adipate-co-terephthalate) Films
title Effect of Addition of Cross-Linked Starch on the Properties of Degraded PBAT Poly(butylene adipate-co-terephthalate) Films
spellingShingle Effect of Addition of Cross-Linked Starch on the Properties of Degraded PBAT Poly(butylene adipate-co-terephthalate) Films
Grimaut, Denise Agostina
BLENDS
CROSSLINKING
PLOY(BUTYLENE ADIPATE-CO-TEREPHTHALATE)
POTATO STARCH
title_short Effect of Addition of Cross-Linked Starch on the Properties of Degraded PBAT Poly(butylene adipate-co-terephthalate) Films
title_full Effect of Addition of Cross-Linked Starch on the Properties of Degraded PBAT Poly(butylene adipate-co-terephthalate) Films
title_fullStr Effect of Addition of Cross-Linked Starch on the Properties of Degraded PBAT Poly(butylene adipate-co-terephthalate) Films
title_full_unstemmed Effect of Addition of Cross-Linked Starch on the Properties of Degraded PBAT Poly(butylene adipate-co-terephthalate) Films
title_sort Effect of Addition of Cross-Linked Starch on the Properties of Degraded PBAT Poly(butylene adipate-co-terephthalate) Films
dc.creator.none.fl_str_mv Grimaut, Denise Agostina
Alves da Silva, Jania Betania
Lemos, Paulo Vitor França
Cruz Correia, Paulo Romano
Santos Santana, Jamille
Cavalcanti Pessôa, Luiggi
Estevez Areco, Santiago
Fama, Lucia Mercedes
Goyanes, Silvia Nair
Rodrigues Marcelino, Henrique
de Jesus Assis, Denilson
Oliveira de Souza, Carolina
author Grimaut, Denise Agostina
author_facet Grimaut, Denise Agostina
Alves da Silva, Jania Betania
Lemos, Paulo Vitor França
Cruz Correia, Paulo Romano
Santos Santana, Jamille
Cavalcanti Pessôa, Luiggi
Estevez Areco, Santiago
Fama, Lucia Mercedes
Goyanes, Silvia Nair
Rodrigues Marcelino, Henrique
de Jesus Assis, Denilson
Oliveira de Souza, Carolina
author_role author
author2 Alves da Silva, Jania Betania
Lemos, Paulo Vitor França
Cruz Correia, Paulo Romano
Santos Santana, Jamille
Cavalcanti Pessôa, Luiggi
Estevez Areco, Santiago
Fama, Lucia Mercedes
Goyanes, Silvia Nair
Rodrigues Marcelino, Henrique
de Jesus Assis, Denilson
Oliveira de Souza, Carolina
author2_role author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv BLENDS
CROSSLINKING
PLOY(BUTYLENE ADIPATE-CO-TEREPHTHALATE)
POTATO STARCH
topic BLENDS
CROSSLINKING
PLOY(BUTYLENE ADIPATE-CO-TEREPHTHALATE)
POTATO STARCH
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.9
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This work aimed to evaluate the properties of butylene adipate-co-terephthalate (PBAT) degraded after 1800 days of storage (DPBAT) by preparing blends (films) with crosslinked starch (Cm) through extrusion and thermocompression. Different ratios of DPBAT:Cm (70:30, 60:40, and 50:50 m/m) were prepared. The incorporation of Cm into DPBAT significantly changed the properties of the films by making them stiffer (increasing Young’s modulus by up to 50%) and increasing the thermal resistance of DPBAT. The presence of crosslinked starch in the films made them less hydrophobic (with decreased contact angle and increased moisture content), but these parameters did not vary linearly with changes in the content of crosslinked starch in the blend (DPBAT:Cm). The microscopic images show an inhomogeneous distribution of Cm granules in the DPBAT matrix. Thus, the films prepared with PBAT show a significant decrease in their mechanical parameters and heat resistance after long-term storage. However, the preparation of blends of degraded DPBAT with crosslinked starch promoted changes in the properties of the films prepared by thermocompression, which could be useful for disposable packaging.
Fil: Grimaut, Denise Agostina. Universidade Federal da Bahia; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigación de la Cadena Láctea. - Instituto Nacional de Tecnología Agropecuaria. Centro Regional Santa Fe. Estación Experimental Agropecuaria Rafaela. Instituto de Investigación de la Cadena Láctea; Argentina
Fil: Alves da Silva, Jania Betania. Universidade Federal da Bahia; Brasil. Universidade Federal da Recôncavo da Bahia; Brasil
Fil: Lemos, Paulo Vitor França. Universidade Federal da Bahia; Brasil
Fil: Cruz Correia, Paulo Romano. Universidade Federal da Bahia; Brasil
Fil: Santos Santana, Jamille. Universidade Federal da Bahia; Brasil
Fil: Cavalcanti Pessôa, Luiggi. Universidade Federal da Bahia; Brasil
Fil: Estevez Areco, Santiago. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física. Laboratorio de Polímeros y Materiales Compuestos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
Fil: Fama, Lucia Mercedes. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física. Laboratorio de Polímeros y Materiales Compuestos; Argentina
Fil: Goyanes, Silvia Nair. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física. Laboratorio de Polímeros y Materiales Compuestos; Argentina
Fil: Rodrigues Marcelino, Henrique. Universidade Federal da Bahia; Brasil
Fil: de Jesus Assis, Denilson. Universidade Federal da Bahia; Brasil
Fil: Oliveira de Souza, Carolina. Universidade Federal da Bahia; Brasil
description This work aimed to evaluate the properties of butylene adipate-co-terephthalate (PBAT) degraded after 1800 days of storage (DPBAT) by preparing blends (films) with crosslinked starch (Cm) through extrusion and thermocompression. Different ratios of DPBAT:Cm (70:30, 60:40, and 50:50 m/m) were prepared. The incorporation of Cm into DPBAT significantly changed the properties of the films by making them stiffer (increasing Young’s modulus by up to 50%) and increasing the thermal resistance of DPBAT. The presence of crosslinked starch in the films made them less hydrophobic (with decreased contact angle and increased moisture content), but these parameters did not vary linearly with changes in the content of crosslinked starch in the blend (DPBAT:Cm). The microscopic images show an inhomogeneous distribution of Cm granules in the DPBAT matrix. Thus, the films prepared with PBAT show a significant decrease in their mechanical parameters and heat resistance after long-term storage. However, the preparation of blends of degraded DPBAT with crosslinked starch promoted changes in the properties of the films prepared by thermocompression, which could be useful for disposable packaging.
publishDate 2023
dc.date.none.fl_str_mv 2023-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/226116
Grimaut, Denise Agostina; Alves da Silva, Jania Betania ; Lemos, Paulo Vitor França; Cruz Correia, Paulo Romano ; Santos Santana, Jamille ; et al.; Effect of Addition of Cross-Linked Starch on the Properties of Degraded PBAT Poly(butylene adipate-co-terephthalate) Films; Multidisciplinary Digital Publishing Institute; Polymers; 15; 14; 7-2023; 1-15
2073-4360
CONICET Digital
CONICET
url http://hdl.handle.net/11336/226116
identifier_str_mv Grimaut, Denise Agostina; Alves da Silva, Jania Betania ; Lemos, Paulo Vitor França; Cruz Correia, Paulo Romano ; Santos Santana, Jamille ; et al.; Effect of Addition of Cross-Linked Starch on the Properties of Degraded PBAT Poly(butylene adipate-co-terephthalate) Films; Multidisciplinary Digital Publishing Institute; Polymers; 15; 14; 7-2023; 1-15
2073-4360
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4360/15/14/3106
info:eu-repo/semantics/altIdentifier/doi/10.3390/polym15143106
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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