Malachite Green Removal by Grape Stalks Biosorption from Natural Waters and Effluents
- Autores
- Lemos, Eliana Soledad; Fiorentini Chirino, Emiliano Franco; Bonilla Petriciolet, Adrián; Escudero, Leticia Belén
- Año de publicación
- 2023
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The efficiency of the grape stalk as a biosorbent for the malachite green removal from natural waters and industrial effluents was investigated in this work. For the optimization of experimental variables, a central composite design was used, in which the effect of pH and biosorbent dose was evaluated on biosorption capacity and removal percentage. Optimal parameters of pH 5 and biosorbent dose of 0.80 g L-1 allowed a malachite green removal percentage of 87.7%. Data obtained from kinetic studies were fitted with the pseudo-second-order model. The maximum biosorption capacity was determined using the Langmuir equilibrium model, reaching a value of 214.2 mg g-1. The biosorption process was thermodynamically favorable and spontaneous at room temperature. The calculated value of biosorption enthalpy change indicated that the nature of the process was exothermic and physical. The biosorption process was applied in natural waters and industrial effluent samples, obtaining removal percentages up to 84.3%, which demonstrates the efficiency of grape stalks for the treatment of complex matrices.
Fil: Lemos, Eliana Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina
Fil: Fiorentini Chirino, Emiliano Franco. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina
Fil: Bonilla Petriciolet, Adrián. Instituto Tecnológico de Aguascalientes; México
Fil: Escudero, Leticia Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina - Materia
-
REMOVAL
MALACHITE GREEN
BIOSORPTION
NATURAL WATERS AND EFFLUENTS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/230645
Ver los metadatos del registro completo
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Malachite Green Removal by Grape Stalks Biosorption from Natural Waters and EffluentsLemos, Eliana SoledadFiorentini Chirino, Emiliano FrancoBonilla Petriciolet, AdriánEscudero, Leticia BelénREMOVALMALACHITE GREENBIOSORPTIONNATURAL WATERS AND EFFLUENTShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The efficiency of the grape stalk as a biosorbent for the malachite green removal from natural waters and industrial effluents was investigated in this work. For the optimization of experimental variables, a central composite design was used, in which the effect of pH and biosorbent dose was evaluated on biosorption capacity and removal percentage. Optimal parameters of pH 5 and biosorbent dose of 0.80 g L<sup>-1</sup> allowed a malachite green removal percentage of 87.7%. Data obtained from kinetic studies were fitted with the pseudo-second-order model. The maximum biosorption capacity was determined using the Langmuir equilibrium model, reaching a value of 214.2 mg g<sup>-1</sup>. The biosorption process was thermodynamically favorable and spontaneous at room temperature. The calculated value of biosorption enthalpy change indicated that the nature of the process was exothermic and physical. The biosorption process was applied in natural waters and industrial effluent samples, obtaining removal percentages up to 84.3%, which demonstrates the efficiency of grape stalks for the treatment of complex matrices.Fil: Lemos, Eliana Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; ArgentinaFil: Fiorentini Chirino, Emiliano Franco. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; ArgentinaFil: Bonilla Petriciolet, Adrián. Instituto Tecnológico de Aguascalientes; MéxicoFil: Escudero, Leticia Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; ArgentinaHindawi Publishing Corporation2023-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/230645Lemos, Eliana Soledad; Fiorentini Chirino, Emiliano Franco; Bonilla Petriciolet, Adrián; Escudero, Leticia Belén; Malachite Green Removal by Grape Stalks Biosorption from Natural Waters and Effluents; Hindawi Publishing Corporation; Adsorption Science & Technology; 2023; 6-2023; 1-120263-6174CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.hindawi.com/journals/ast/2023/6695937/info:eu-repo/semantics/altIdentifier/doi/10.1155/2023/6695937info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:47:30Zoai:ri.conicet.gov.ar:11336/230645instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:47:30.468CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Malachite Green Removal by Grape Stalks Biosorption from Natural Waters and Effluents |
title |
Malachite Green Removal by Grape Stalks Biosorption from Natural Waters and Effluents |
spellingShingle |
Malachite Green Removal by Grape Stalks Biosorption from Natural Waters and Effluents Lemos, Eliana Soledad REMOVAL MALACHITE GREEN BIOSORPTION NATURAL WATERS AND EFFLUENTS |
title_short |
Malachite Green Removal by Grape Stalks Biosorption from Natural Waters and Effluents |
title_full |
Malachite Green Removal by Grape Stalks Biosorption from Natural Waters and Effluents |
title_fullStr |
Malachite Green Removal by Grape Stalks Biosorption from Natural Waters and Effluents |
title_full_unstemmed |
Malachite Green Removal by Grape Stalks Biosorption from Natural Waters and Effluents |
title_sort |
Malachite Green Removal by Grape Stalks Biosorption from Natural Waters and Effluents |
dc.creator.none.fl_str_mv |
Lemos, Eliana Soledad Fiorentini Chirino, Emiliano Franco Bonilla Petriciolet, Adrián Escudero, Leticia Belén |
author |
Lemos, Eliana Soledad |
author_facet |
Lemos, Eliana Soledad Fiorentini Chirino, Emiliano Franco Bonilla Petriciolet, Adrián Escudero, Leticia Belén |
author_role |
author |
author2 |
Fiorentini Chirino, Emiliano Franco Bonilla Petriciolet, Adrián Escudero, Leticia Belén |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
REMOVAL MALACHITE GREEN BIOSORPTION NATURAL WATERS AND EFFLUENTS |
topic |
REMOVAL MALACHITE GREEN BIOSORPTION NATURAL WATERS AND EFFLUENTS |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The efficiency of the grape stalk as a biosorbent for the malachite green removal from natural waters and industrial effluents was investigated in this work. For the optimization of experimental variables, a central composite design was used, in which the effect of pH and biosorbent dose was evaluated on biosorption capacity and removal percentage. Optimal parameters of pH 5 and biosorbent dose of 0.80 g L<sup>-1</sup> allowed a malachite green removal percentage of 87.7%. Data obtained from kinetic studies were fitted with the pseudo-second-order model. The maximum biosorption capacity was determined using the Langmuir equilibrium model, reaching a value of 214.2 mg g<sup>-1</sup>. The biosorption process was thermodynamically favorable and spontaneous at room temperature. The calculated value of biosorption enthalpy change indicated that the nature of the process was exothermic and physical. The biosorption process was applied in natural waters and industrial effluent samples, obtaining removal percentages up to 84.3%, which demonstrates the efficiency of grape stalks for the treatment of complex matrices. Fil: Lemos, Eliana Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina Fil: Fiorentini Chirino, Emiliano Franco. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina Fil: Bonilla Petriciolet, Adrián. Instituto Tecnológico de Aguascalientes; México Fil: Escudero, Leticia Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina |
description |
The efficiency of the grape stalk as a biosorbent for the malachite green removal from natural waters and industrial effluents was investigated in this work. For the optimization of experimental variables, a central composite design was used, in which the effect of pH and biosorbent dose was evaluated on biosorption capacity and removal percentage. Optimal parameters of pH 5 and biosorbent dose of 0.80 g L<sup>-1</sup> allowed a malachite green removal percentage of 87.7%. Data obtained from kinetic studies were fitted with the pseudo-second-order model. The maximum biosorption capacity was determined using the Langmuir equilibrium model, reaching a value of 214.2 mg g<sup>-1</sup>. The biosorption process was thermodynamically favorable and spontaneous at room temperature. The calculated value of biosorption enthalpy change indicated that the nature of the process was exothermic and physical. The biosorption process was applied in natural waters and industrial effluent samples, obtaining removal percentages up to 84.3%, which demonstrates the efficiency of grape stalks for the treatment of complex matrices. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023-06 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/230645 Lemos, Eliana Soledad; Fiorentini Chirino, Emiliano Franco; Bonilla Petriciolet, Adrián; Escudero, Leticia Belén; Malachite Green Removal by Grape Stalks Biosorption from Natural Waters and Effluents; Hindawi Publishing Corporation; Adsorption Science & Technology; 2023; 6-2023; 1-12 0263-6174 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/230645 |
identifier_str_mv |
Lemos, Eliana Soledad; Fiorentini Chirino, Emiliano Franco; Bonilla Petriciolet, Adrián; Escudero, Leticia Belén; Malachite Green Removal by Grape Stalks Biosorption from Natural Waters and Effluents; Hindawi Publishing Corporation; Adsorption Science & Technology; 2023; 6-2023; 1-12 0263-6174 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.hindawi.com/journals/ast/2023/6695937/ info:eu-repo/semantics/altIdentifier/doi/10.1155/2023/6695937 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Hindawi Publishing Corporation |
publisher.none.fl_str_mv |
Hindawi Publishing Corporation |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613479939440640 |
score |
13.070432 |