Morphological stabilization and KPZ scaling by electrochemically induced co-deposition of nanostructured NiW alloy films

Autores
Orrillo, Patricio Andrés; Santalla, S. N.; Cuerno, R.; Vázquez, L.; Ribotta, Susana Beatriz; Gassa, Liliana Mabel; Mompean, F. J.; Salvarezza, Roberto Carlos; Vela, Maria Elena
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We have assessed the stabilizing role that induced co-deposition has in the growth of nanostructured NiW alloy films by electrodeposition on polished steel substrates, under pulsed galvanostatic conditions. We have compared the kinetic roughening properties of NiW films with those of Ni films deposited under the same conditions, as assessed by Atomic Force Microscopy. The surface morphologies of both systems are super-rough at short times, but differ at long times: while a cauliflower-like structure dominates for Ni, the surfaces of NiW films display a nodular morphology consistent with more stable, conformal growth, whose height fluctuations are in the Kardar-Parisi-Zhang universality class of rough two-dimensional interfaces. These differences are explained by the mechanisms controlling surface growth in each case: mass transport through the electrolyte (Ni) and attachment of the incoming species to the growing interface (NiW). Thus, the long-time conformal growth regime is characteristic of electrochemical induced co-deposition under current conditions in which surface kinetics is hindered due to a complex reaction mechanism. These results agree with a theoretical model of surface growth in diffusion-limited systems, in which the key parameter is the relative importance of mass transport with respect to the kinetics of the attachment reaction.
Fil: Orrillo, Patricio Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina
Fil: Santalla, S. N.. Universidad Carlos III de Madrid. Instituto de Salud; España
Fil: Cuerno, R.. Universidad Carlos III de Madrid. Instituto de Salud; España
Fil: Vázquez, L.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Ribotta, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina
Fil: Gassa, Liliana Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Mompean, F. J.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Salvarezza, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Vela, Maria Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Materia
Nanostructured materials
Ni W alloys
KPZ
Dynamic scaling
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/63816
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Morphological stabilization and KPZ scaling by electrochemically induced co-deposition of nanostructured NiW alloy filmsOrrillo, Patricio AndrésSantalla, S. N.Cuerno, R.Vázquez, L.Ribotta, Susana BeatrizGassa, Liliana MabelMompean, F. J.Salvarezza, Roberto CarlosVela, Maria ElenaNanostructured materialsNi W alloysKPZDynamic scalinghttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2We have assessed the stabilizing role that induced co-deposition has in the growth of nanostructured NiW alloy films by electrodeposition on polished steel substrates, under pulsed galvanostatic conditions. We have compared the kinetic roughening properties of NiW films with those of Ni films deposited under the same conditions, as assessed by Atomic Force Microscopy. The surface morphologies of both systems are super-rough at short times, but differ at long times: while a cauliflower-like structure dominates for Ni, the surfaces of NiW films display a nodular morphology consistent with more stable, conformal growth, whose height fluctuations are in the Kardar-Parisi-Zhang universality class of rough two-dimensional interfaces. These differences are explained by the mechanisms controlling surface growth in each case: mass transport through the electrolyte (Ni) and attachment of the incoming species to the growing interface (NiW). Thus, the long-time conformal growth regime is characteristic of electrochemical induced co-deposition under current conditions in which surface kinetics is hindered due to a complex reaction mechanism. These results agree with a theoretical model of surface growth in diffusion-limited systems, in which the key parameter is the relative importance of mass transport with respect to the kinetics of the attachment reaction.Fil: Orrillo, Patricio Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; ArgentinaFil: Santalla, S. N.. Universidad Carlos III de Madrid. Instituto de Salud; EspañaFil: Cuerno, R.. Universidad Carlos III de Madrid. Instituto de Salud; EspañaFil: Vázquez, L.. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Ribotta, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; ArgentinaFil: Gassa, Liliana Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Mompean, F. J.. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Salvarezza, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Vela, Maria Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaNature Publishing Group2017-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/63816Orrillo, Patricio Andrés; Santalla, S. N.; Cuerno, R.; Vázquez, L.; Ribotta, Susana Beatriz; et al.; Morphological stabilization and KPZ scaling by electrochemically induced co-deposition of nanostructured NiW alloy films; Nature Publishing Group; Scientific Reports; 7; 1; 12-2017; 1-122045-2322CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.nature.com/articles/s41598-017-18155-7info:eu-repo/semantics/altIdentifier/doi/10.1038/s41598-017-18155-7info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:42:23Zoai:ri.conicet.gov.ar:11336/63816instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:42:23.391CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Morphological stabilization and KPZ scaling by electrochemically induced co-deposition of nanostructured NiW alloy films
title Morphological stabilization and KPZ scaling by electrochemically induced co-deposition of nanostructured NiW alloy films
spellingShingle Morphological stabilization and KPZ scaling by electrochemically induced co-deposition of nanostructured NiW alloy films
Orrillo, Patricio Andrés
Nanostructured materials
Ni W alloys
KPZ
Dynamic scaling
title_short Morphological stabilization and KPZ scaling by electrochemically induced co-deposition of nanostructured NiW alloy films
title_full Morphological stabilization and KPZ scaling by electrochemically induced co-deposition of nanostructured NiW alloy films
title_fullStr Morphological stabilization and KPZ scaling by electrochemically induced co-deposition of nanostructured NiW alloy films
title_full_unstemmed Morphological stabilization and KPZ scaling by electrochemically induced co-deposition of nanostructured NiW alloy films
title_sort Morphological stabilization and KPZ scaling by electrochemically induced co-deposition of nanostructured NiW alloy films
dc.creator.none.fl_str_mv Orrillo, Patricio Andrés
Santalla, S. N.
Cuerno, R.
Vázquez, L.
Ribotta, Susana Beatriz
Gassa, Liliana Mabel
Mompean, F. J.
Salvarezza, Roberto Carlos
Vela, Maria Elena
author Orrillo, Patricio Andrés
author_facet Orrillo, Patricio Andrés
Santalla, S. N.
Cuerno, R.
Vázquez, L.
Ribotta, Susana Beatriz
Gassa, Liliana Mabel
Mompean, F. J.
Salvarezza, Roberto Carlos
Vela, Maria Elena
author_role author
author2 Santalla, S. N.
Cuerno, R.
Vázquez, L.
Ribotta, Susana Beatriz
Gassa, Liliana Mabel
Mompean, F. J.
Salvarezza, Roberto Carlos
Vela, Maria Elena
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Nanostructured materials
Ni W alloys
KPZ
Dynamic scaling
topic Nanostructured materials
Ni W alloys
KPZ
Dynamic scaling
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv We have assessed the stabilizing role that induced co-deposition has in the growth of nanostructured NiW alloy films by electrodeposition on polished steel substrates, under pulsed galvanostatic conditions. We have compared the kinetic roughening properties of NiW films with those of Ni films deposited under the same conditions, as assessed by Atomic Force Microscopy. The surface morphologies of both systems are super-rough at short times, but differ at long times: while a cauliflower-like structure dominates for Ni, the surfaces of NiW films display a nodular morphology consistent with more stable, conformal growth, whose height fluctuations are in the Kardar-Parisi-Zhang universality class of rough two-dimensional interfaces. These differences are explained by the mechanisms controlling surface growth in each case: mass transport through the electrolyte (Ni) and attachment of the incoming species to the growing interface (NiW). Thus, the long-time conformal growth regime is characteristic of electrochemical induced co-deposition under current conditions in which surface kinetics is hindered due to a complex reaction mechanism. These results agree with a theoretical model of surface growth in diffusion-limited systems, in which the key parameter is the relative importance of mass transport with respect to the kinetics of the attachment reaction.
Fil: Orrillo, Patricio Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina
Fil: Santalla, S. N.. Universidad Carlos III de Madrid. Instituto de Salud; España
Fil: Cuerno, R.. Universidad Carlos III de Madrid. Instituto de Salud; España
Fil: Vázquez, L.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Ribotta, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina
Fil: Gassa, Liliana Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Mompean, F. J.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Salvarezza, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Vela, Maria Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
description We have assessed the stabilizing role that induced co-deposition has in the growth of nanostructured NiW alloy films by electrodeposition on polished steel substrates, under pulsed galvanostatic conditions. We have compared the kinetic roughening properties of NiW films with those of Ni films deposited under the same conditions, as assessed by Atomic Force Microscopy. The surface morphologies of both systems are super-rough at short times, but differ at long times: while a cauliflower-like structure dominates for Ni, the surfaces of NiW films display a nodular morphology consistent with more stable, conformal growth, whose height fluctuations are in the Kardar-Parisi-Zhang universality class of rough two-dimensional interfaces. These differences are explained by the mechanisms controlling surface growth in each case: mass transport through the electrolyte (Ni) and attachment of the incoming species to the growing interface (NiW). Thus, the long-time conformal growth regime is characteristic of electrochemical induced co-deposition under current conditions in which surface kinetics is hindered due to a complex reaction mechanism. These results agree with a theoretical model of surface growth in diffusion-limited systems, in which the key parameter is the relative importance of mass transport with respect to the kinetics of the attachment reaction.
publishDate 2017
dc.date.none.fl_str_mv 2017-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/63816
Orrillo, Patricio Andrés; Santalla, S. N.; Cuerno, R.; Vázquez, L.; Ribotta, Susana Beatriz; et al.; Morphological stabilization and KPZ scaling by electrochemically induced co-deposition of nanostructured NiW alloy films; Nature Publishing Group; Scientific Reports; 7; 1; 12-2017; 1-12
2045-2322
CONICET Digital
CONICET
url http://hdl.handle.net/11336/63816
identifier_str_mv Orrillo, Patricio Andrés; Santalla, S. N.; Cuerno, R.; Vázquez, L.; Ribotta, Susana Beatriz; et al.; Morphological stabilization and KPZ scaling by electrochemically induced co-deposition of nanostructured NiW alloy films; Nature Publishing Group; Scientific Reports; 7; 1; 12-2017; 1-12
2045-2322
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.nature.com/articles/s41598-017-18155-7
info:eu-repo/semantics/altIdentifier/doi/10.1038/s41598-017-18155-7
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Nature Publishing Group
publisher.none.fl_str_mv Nature Publishing Group
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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