Influence of the operating conditions and kinetic analysis of the selective hydrogenation of oleic acid on Ru-Sn-B/Al2O3 catalysts

Autores
Sánchez, María Amparo; Pouilloux, Yannick; Mazzieri, Vanina Alejandra; Pieck, Carlos Luis
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The influence of the operating conditions on the selectivity and activity of Ru-Sn-B/Al2O3 catalysts for the hydrogenation of oleic acid to oleyl alcohol was studied. It was found that the Ru-Sn-B/Al 2O3 catalyst is selective to oleyl alcohol while Ru or Ru-B/Al2O3 catalysts are not selective to produce oleyl alcohol. The electronic and catalytic properties of Ru are modified by the strong interaction between Sn and B. The incorporation of Sn leads to catalysts capable of producing oleyl alcohol. The experiments of oleic acid hydrogenation showed that an increase in reaction temperature leads to an increase in activity while the selectivity to oleyl alcohol goes through a maximum. This is because the reactions of hydrogenation of CC double bond have lower activation energies than hydrogenolytic reactions. The increase in operating pressure has a positive effect on conversion and a more important effect on selectivity. A very simple first order kinetic model is proposed and reasonably represents the results obtained. This model can be useful to compare catalyst performance more rationally.
Fil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Pouilloux, Yannick. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Mazzieri, Vanina Alejandra. Université de Poitiers; Francia
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Oleic Acid
Oleyl Alcohol
Ru-Sn-B/Al2o3
Selective Hydrogenation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/78596
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/78596
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Influence of the operating conditions and kinetic analysis of the selective hydrogenation of oleic acid on Ru-Sn-B/Al2O3 catalystsSánchez, María AmparoPouilloux, YannickMazzieri, Vanina AlejandraPieck, Carlos LuisOleic AcidOleyl AlcoholRu-Sn-B/Al2o3Selective Hydrogenationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The influence of the operating conditions on the selectivity and activity of Ru-Sn-B/Al2O3 catalysts for the hydrogenation of oleic acid to oleyl alcohol was studied. It was found that the Ru-Sn-B/Al 2O3 catalyst is selective to oleyl alcohol while Ru or Ru-B/Al2O3 catalysts are not selective to produce oleyl alcohol. The electronic and catalytic properties of Ru are modified by the strong interaction between Sn and B. The incorporation of Sn leads to catalysts capable of producing oleyl alcohol. The experiments of oleic acid hydrogenation showed that an increase in reaction temperature leads to an increase in activity while the selectivity to oleyl alcohol goes through a maximum. This is because the reactions of hydrogenation of CC double bond have lower activation energies than hydrogenolytic reactions. The increase in operating pressure has a positive effect on conversion and a more important effect on selectivity. A very simple first order kinetic model is proposed and reasonably represents the results obtained. This model can be useful to compare catalyst performance more rationally.Fil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Pouilloux, Yannick. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Mazzieri, Vanina Alejandra. Université de Poitiers; FranciaFil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2013-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/78596Sánchez, María Amparo; Pouilloux, Yannick; Mazzieri, Vanina Alejandra; Pieck, Carlos Luis; Influence of the operating conditions and kinetic analysis of the selective hydrogenation of oleic acid on Ru-Sn-B/Al2O3 catalysts; Elsevier Science; Applied Catalysis A: General; 467; 10-2013; 552-5580926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2013.08.014info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:17:20Zoai:ri.conicet.gov.ar:11336/78596instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:17:20.549CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Influence of the operating conditions and kinetic analysis of the selective hydrogenation of oleic acid on Ru-Sn-B/Al2O3 catalysts
title Influence of the operating conditions and kinetic analysis of the selective hydrogenation of oleic acid on Ru-Sn-B/Al2O3 catalysts
spellingShingle Influence of the operating conditions and kinetic analysis of the selective hydrogenation of oleic acid on Ru-Sn-B/Al2O3 catalysts
Sánchez, María Amparo
Oleic Acid
Oleyl Alcohol
Ru-Sn-B/Al2o3
Selective Hydrogenation
title_short Influence of the operating conditions and kinetic analysis of the selective hydrogenation of oleic acid on Ru-Sn-B/Al2O3 catalysts
title_full Influence of the operating conditions and kinetic analysis of the selective hydrogenation of oleic acid on Ru-Sn-B/Al2O3 catalysts
title_fullStr Influence of the operating conditions and kinetic analysis of the selective hydrogenation of oleic acid on Ru-Sn-B/Al2O3 catalysts
title_full_unstemmed Influence of the operating conditions and kinetic analysis of the selective hydrogenation of oleic acid on Ru-Sn-B/Al2O3 catalysts
title_sort Influence of the operating conditions and kinetic analysis of the selective hydrogenation of oleic acid on Ru-Sn-B/Al2O3 catalysts
dc.creator.none.fl_str_mv Sánchez, María Amparo
Pouilloux, Yannick
Mazzieri, Vanina Alejandra
Pieck, Carlos Luis
author Sánchez, María Amparo
author_facet Sánchez, María Amparo
Pouilloux, Yannick
Mazzieri, Vanina Alejandra
Pieck, Carlos Luis
author_role author
author2 Pouilloux, Yannick
Mazzieri, Vanina Alejandra
Pieck, Carlos Luis
author2_role author
author
author
dc.subject.none.fl_str_mv Oleic Acid
Oleyl Alcohol
Ru-Sn-B/Al2o3
Selective Hydrogenation
topic Oleic Acid
Oleyl Alcohol
Ru-Sn-B/Al2o3
Selective Hydrogenation
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The influence of the operating conditions on the selectivity and activity of Ru-Sn-B/Al2O3 catalysts for the hydrogenation of oleic acid to oleyl alcohol was studied. It was found that the Ru-Sn-B/Al 2O3 catalyst is selective to oleyl alcohol while Ru or Ru-B/Al2O3 catalysts are not selective to produce oleyl alcohol. The electronic and catalytic properties of Ru are modified by the strong interaction between Sn and B. The incorporation of Sn leads to catalysts capable of producing oleyl alcohol. The experiments of oleic acid hydrogenation showed that an increase in reaction temperature leads to an increase in activity while the selectivity to oleyl alcohol goes through a maximum. This is because the reactions of hydrogenation of CC double bond have lower activation energies than hydrogenolytic reactions. The increase in operating pressure has a positive effect on conversion and a more important effect on selectivity. A very simple first order kinetic model is proposed and reasonably represents the results obtained. This model can be useful to compare catalyst performance more rationally.
Fil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Pouilloux, Yannick. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Mazzieri, Vanina Alejandra. Université de Poitiers; Francia
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description The influence of the operating conditions on the selectivity and activity of Ru-Sn-B/Al2O3 catalysts for the hydrogenation of oleic acid to oleyl alcohol was studied. It was found that the Ru-Sn-B/Al 2O3 catalyst is selective to oleyl alcohol while Ru or Ru-B/Al2O3 catalysts are not selective to produce oleyl alcohol. The electronic and catalytic properties of Ru are modified by the strong interaction between Sn and B. The incorporation of Sn leads to catalysts capable of producing oleyl alcohol. The experiments of oleic acid hydrogenation showed that an increase in reaction temperature leads to an increase in activity while the selectivity to oleyl alcohol goes through a maximum. This is because the reactions of hydrogenation of CC double bond have lower activation energies than hydrogenolytic reactions. The increase in operating pressure has a positive effect on conversion and a more important effect on selectivity. A very simple first order kinetic model is proposed and reasonably represents the results obtained. This model can be useful to compare catalyst performance more rationally.
publishDate 2013
dc.date.none.fl_str_mv 2013-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/78596
Sánchez, María Amparo; Pouilloux, Yannick; Mazzieri, Vanina Alejandra; Pieck, Carlos Luis; Influence of the operating conditions and kinetic analysis of the selective hydrogenation of oleic acid on Ru-Sn-B/Al2O3 catalysts; Elsevier Science; Applied Catalysis A: General; 467; 10-2013; 552-558
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/78596
identifier_str_mv Sánchez, María Amparo; Pouilloux, Yannick; Mazzieri, Vanina Alejandra; Pieck, Carlos Luis; Influence of the operating conditions and kinetic analysis of the selective hydrogenation of oleic acid on Ru-Sn-B/Al2O3 catalysts; Elsevier Science; Applied Catalysis A: General; 467; 10-2013; 552-558
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2013.08.014
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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