Ru-Sn-B/TiO 2 catalysts for methyl oleate selective hydrogenation. Influence of the preparation method and the chlorine content

Autores
Sánchez, María Amparo; Mazzieri, Vanina Alejandra; Pronier, Stéphane; Vicerich, Maria Ana; Especel, Catherine; Epron, Florence; Pieck, Carlos Luis
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Background: Fatty alcohols are produced commercially by selective hydrogenation of fattyacid esters using copper and chromium catalysts. To reduce drastic reaction conditions, Ru-Sn catalysts reduced with NaBH4 have been proposed. Chlorine negatively affects the selectivity and activity of this catalytic system. To get further information on why Cl influences the selectivity negatively, we studied the influence of the preparation method on titania-supported catalysts, which leads to catalysts with different chlorine contents.Results: The activity and selectivity were greatly affected by the chlorine content whichdepends on the metal impregnation method (coimpregnation in excess of solution orcoimpregnation by incipient wetness) and the support precalcination. Chlorine affects the Ru-Sn metal interaction modifying the activity and selectivity. Catalysts with high Ru-Sninteraction are more selective to oleyl alcohol. Catalyst prepared by coimpregnation methodexhibits bigger particles than by incipient wetness method, with agglomerated Ru3Sn7 cubicphase of 50 nm surrounded by amorphous Ru-Sn.Conclusion: High interaction between Ru and Sn is preferred because segregated Ru speciesare not selective for the formation of oleyl alcohol. The electronic state of Ru° is veryimportant because small variations in the electron density leads to a decrease in the adsorption of the hydrogen, or because Ru°-H species do not have the adequate binding energy to produce the necessary ?hydride form?. Ru electronic state is modified by the chlorine that surrounds it, decreasing its ability to adsorb hydrogen.
Fil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Mazzieri, Vanina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Pronier, Stéphane. Institut de Chimie Des Milieux Et Matériaux Poitiers; Francia
Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Especel, Catherine. Institut de Chimie Des Milieux Et Matériaux de Poitiers; Francia
Fil: Epron, Florence. Institut de Chimie Des Milieux Et Matériaux de Poitiers; Francia
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Selective hydrogenation
Fatty alcohols
Ru‐Sn‐B/TiO2 catalysts
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/88487
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/88487
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Ru-Sn-B/TiO 2 catalysts for methyl oleate selective hydrogenation. Influence of the preparation method and the chlorine contentSánchez, María AmparoMazzieri, Vanina AlejandraPronier, StéphaneVicerich, Maria AnaEspecel, CatherineEpron, FlorencePieck, Carlos LuisSelective hydrogenationFatty alcoholsRu‐Sn‐B/TiO2 catalystshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Background: Fatty alcohols are produced commercially by selective hydrogenation of fattyacid esters using copper and chromium catalysts. To reduce drastic reaction conditions, Ru-Sn catalysts reduced with NaBH4 have been proposed. Chlorine negatively affects the selectivity and activity of this catalytic system. To get further information on why Cl influences the selectivity negatively, we studied the influence of the preparation method on titania-supported catalysts, which leads to catalysts with different chlorine contents.Results: The activity and selectivity were greatly affected by the chlorine content whichdepends on the metal impregnation method (coimpregnation in excess of solution orcoimpregnation by incipient wetness) and the support precalcination. Chlorine affects the Ru-Sn metal interaction modifying the activity and selectivity. Catalysts with high Ru-Sninteraction are more selective to oleyl alcohol. Catalyst prepared by coimpregnation methodexhibits bigger particles than by incipient wetness method, with agglomerated Ru3Sn7 cubicphase of 50 nm surrounded by amorphous Ru-Sn.Conclusion: High interaction between Ru and Sn is preferred because segregated Ru speciesare not selective for the formation of oleyl alcohol. The electronic state of Ru° is veryimportant because small variations in the electron density leads to a decrease in the adsorption of the hydrogen, or because Ru°-H species do not have the adequate binding energy to produce the necessary ?hydride form?. Ru electronic state is modified by the chlorine that surrounds it, decreasing its ability to adsorb hydrogen.Fil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Mazzieri, Vanina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Pronier, Stéphane. Institut de Chimie Des Milieux Et Matériaux Poitiers; FranciaFil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Especel, Catherine. Institut de Chimie Des Milieux Et Matériaux de Poitiers; FranciaFil: Epron, Florence. Institut de Chimie Des Milieux Et Matériaux de Poitiers; FranciaFil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaJohn Wiley & Sons Ltd2019-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/88487Sánchez, María Amparo; Mazzieri, Vanina Alejandra; Pronier, Stéphane; Vicerich, Maria Ana; Especel, Catherine; et al.; Ru-Sn-B/TiO 2 catalysts for methyl oleate selective hydrogenation. Influence of the preparation method and the chlorine content; John Wiley & Sons Ltd; Journal of Chemical Technology and Biotechnology; 94; 3; 3-2019; 982-9910268-2575CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://doi.wiley.com/10.1002/jctb.5849info:eu-repo/semantics/altIdentifier/doi/10.1002/jctb.5849info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:10:05Zoai:ri.conicet.gov.ar:11336/88487instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:10:06.076CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ru-Sn-B/TiO 2 catalysts for methyl oleate selective hydrogenation. Influence of the preparation method and the chlorine content
title Ru-Sn-B/TiO 2 catalysts for methyl oleate selective hydrogenation. Influence of the preparation method and the chlorine content
spellingShingle Ru-Sn-B/TiO 2 catalysts for methyl oleate selective hydrogenation. Influence of the preparation method and the chlorine content
Sánchez, María Amparo
Selective hydrogenation
Fatty alcohols
Ru‐Sn‐B/TiO2 catalysts
title_short Ru-Sn-B/TiO 2 catalysts for methyl oleate selective hydrogenation. Influence of the preparation method and the chlorine content
title_full Ru-Sn-B/TiO 2 catalysts for methyl oleate selective hydrogenation. Influence of the preparation method and the chlorine content
title_fullStr Ru-Sn-B/TiO 2 catalysts for methyl oleate selective hydrogenation. Influence of the preparation method and the chlorine content
title_full_unstemmed Ru-Sn-B/TiO 2 catalysts for methyl oleate selective hydrogenation. Influence of the preparation method and the chlorine content
title_sort Ru-Sn-B/TiO 2 catalysts for methyl oleate selective hydrogenation. Influence of the preparation method and the chlorine content
dc.creator.none.fl_str_mv Sánchez, María Amparo
Mazzieri, Vanina Alejandra
Pronier, Stéphane
Vicerich, Maria Ana
Especel, Catherine
Epron, Florence
Pieck, Carlos Luis
author Sánchez, María Amparo
author_facet Sánchez, María Amparo
Mazzieri, Vanina Alejandra
Pronier, Stéphane
Vicerich, Maria Ana
Especel, Catherine
Epron, Florence
Pieck, Carlos Luis
author_role author
author2 Mazzieri, Vanina Alejandra
Pronier, Stéphane
Vicerich, Maria Ana
Especel, Catherine
Epron, Florence
Pieck, Carlos Luis
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Selective hydrogenation
Fatty alcohols
Ru‐Sn‐B/TiO2 catalysts
topic Selective hydrogenation
Fatty alcohols
Ru‐Sn‐B/TiO2 catalysts
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Background: Fatty alcohols are produced commercially by selective hydrogenation of fattyacid esters using copper and chromium catalysts. To reduce drastic reaction conditions, Ru-Sn catalysts reduced with NaBH4 have been proposed. Chlorine negatively affects the selectivity and activity of this catalytic system. To get further information on why Cl influences the selectivity negatively, we studied the influence of the preparation method on titania-supported catalysts, which leads to catalysts with different chlorine contents.Results: The activity and selectivity were greatly affected by the chlorine content whichdepends on the metal impregnation method (coimpregnation in excess of solution orcoimpregnation by incipient wetness) and the support precalcination. Chlorine affects the Ru-Sn metal interaction modifying the activity and selectivity. Catalysts with high Ru-Sninteraction are more selective to oleyl alcohol. Catalyst prepared by coimpregnation methodexhibits bigger particles than by incipient wetness method, with agglomerated Ru3Sn7 cubicphase of 50 nm surrounded by amorphous Ru-Sn.Conclusion: High interaction between Ru and Sn is preferred because segregated Ru speciesare not selective for the formation of oleyl alcohol. The electronic state of Ru° is veryimportant because small variations in the electron density leads to a decrease in the adsorption of the hydrogen, or because Ru°-H species do not have the adequate binding energy to produce the necessary ?hydride form?. Ru electronic state is modified by the chlorine that surrounds it, decreasing its ability to adsorb hydrogen.
Fil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Mazzieri, Vanina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Pronier, Stéphane. Institut de Chimie Des Milieux Et Matériaux Poitiers; Francia
Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Especel, Catherine. Institut de Chimie Des Milieux Et Matériaux de Poitiers; Francia
Fil: Epron, Florence. Institut de Chimie Des Milieux Et Matériaux de Poitiers; Francia
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description Background: Fatty alcohols are produced commercially by selective hydrogenation of fattyacid esters using copper and chromium catalysts. To reduce drastic reaction conditions, Ru-Sn catalysts reduced with NaBH4 have been proposed. Chlorine negatively affects the selectivity and activity of this catalytic system. To get further information on why Cl influences the selectivity negatively, we studied the influence of the preparation method on titania-supported catalysts, which leads to catalysts with different chlorine contents.Results: The activity and selectivity were greatly affected by the chlorine content whichdepends on the metal impregnation method (coimpregnation in excess of solution orcoimpregnation by incipient wetness) and the support precalcination. Chlorine affects the Ru-Sn metal interaction modifying the activity and selectivity. Catalysts with high Ru-Sninteraction are more selective to oleyl alcohol. Catalyst prepared by coimpregnation methodexhibits bigger particles than by incipient wetness method, with agglomerated Ru3Sn7 cubicphase of 50 nm surrounded by amorphous Ru-Sn.Conclusion: High interaction between Ru and Sn is preferred because segregated Ru speciesare not selective for the formation of oleyl alcohol. The electronic state of Ru° is veryimportant because small variations in the electron density leads to a decrease in the adsorption of the hydrogen, or because Ru°-H species do not have the adequate binding energy to produce the necessary ?hydride form?. Ru electronic state is modified by the chlorine that surrounds it, decreasing its ability to adsorb hydrogen.
publishDate 2019
dc.date.none.fl_str_mv 2019-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/88487
Sánchez, María Amparo; Mazzieri, Vanina Alejandra; Pronier, Stéphane; Vicerich, Maria Ana; Especel, Catherine; et al.; Ru-Sn-B/TiO 2 catalysts for methyl oleate selective hydrogenation. Influence of the preparation method and the chlorine content; John Wiley & Sons Ltd; Journal of Chemical Technology and Biotechnology; 94; 3; 3-2019; 982-991
0268-2575
CONICET Digital
CONICET
url http://hdl.handle.net/11336/88487
identifier_str_mv Sánchez, María Amparo; Mazzieri, Vanina Alejandra; Pronier, Stéphane; Vicerich, Maria Ana; Especel, Catherine; et al.; Ru-Sn-B/TiO 2 catalysts for methyl oleate selective hydrogenation. Influence of the preparation method and the chlorine content; John Wiley & Sons Ltd; Journal of Chemical Technology and Biotechnology; 94; 3; 3-2019; 982-991
0268-2575
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://doi.wiley.com/10.1002/jctb.5849
info:eu-repo/semantics/altIdentifier/doi/10.1002/jctb.5849
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Ltd
publisher.none.fl_str_mv John Wiley & Sons Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.891075

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