The role of efflorescent salts associated with sulfide-rich mine wastes in the short-term cycling of arsenic: Insights from XRD, XAS, and µ-XRF studies

Autores
Nieva, Nancy Eugenia; Garcia, Maria Gabriela; Borgnino Bianchi, Laura Carolina; Borda, Laura Gabriela
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The evaporation of As-rich leachates generated by the weathering of sulfide-rich mine wastes accumulated in abandoned tailing dams of the La Concordia mine, triggers the widespread precipitation of saline crusts and efflorescences. Because these salts are highly soluble, they may release high concentrations of arsenic after rainfall events. Thus, the goal of this work is to assess the solid speciation of As in these efflorescences, which may help to understand the short-term cycling of As in the site. The results reveal that As is present only as As(V), while its capacity to be retained in the salts highly depends on their mineralogical composition. Hydrous sulfates, such as gypsum and epsomite show a very low capacity to scavenge As, while copiapite retains the highest concentrations of this element. The spectroscopic evidences suggest that in this mineral, As(V) is included within the lattice, substituting sulfate in the tetrahedral sites. Because copiapite is highly soluble, it may be considered as one of the most important transient reservoirs of As in the site that can release high concentrations of this hazardous pollutant during the occasional rainfall events produced during the wet season.
Fil: Nieva, Nancy Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina. Universidad Nacional de Catamarca; Argentina
Fil: Garcia, Maria Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Borgnino Bianchi, Laura Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Borda, Laura Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Materia
AMD
COPIAPITE
SALT EFFLORESCENCES
XAS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/173875
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling The role of efflorescent salts associated with sulfide-rich mine wastes in the short-term cycling of arsenic: Insights from XRD, XAS, and µ-XRF studiesNieva, Nancy EugeniaGarcia, Maria GabrielaBorgnino Bianchi, Laura CarolinaBorda, Laura GabrielaAMDCOPIAPITESALT EFFLORESCENCESXAShttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1The evaporation of As-rich leachates generated by the weathering of sulfide-rich mine wastes accumulated in abandoned tailing dams of the La Concordia mine, triggers the widespread precipitation of saline crusts and efflorescences. Because these salts are highly soluble, they may release high concentrations of arsenic after rainfall events. Thus, the goal of this work is to assess the solid speciation of As in these efflorescences, which may help to understand the short-term cycling of As in the site. The results reveal that As is present only as As(V), while its capacity to be retained in the salts highly depends on their mineralogical composition. Hydrous sulfates, such as gypsum and epsomite show a very low capacity to scavenge As, while copiapite retains the highest concentrations of this element. The spectroscopic evidences suggest that in this mineral, As(V) is included within the lattice, substituting sulfate in the tetrahedral sites. Because copiapite is highly soluble, it may be considered as one of the most important transient reservoirs of As in the site that can release high concentrations of this hazardous pollutant during the occasional rainfall events produced during the wet season.Fil: Nieva, Nancy Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina. Universidad Nacional de Catamarca; ArgentinaFil: Garcia, Maria Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Borgnino Bianchi, Laura Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Borda, Laura Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaElsevier Science2021-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/173875Nieva, Nancy Eugenia; Garcia, Maria Gabriela; Borgnino Bianchi, Laura Carolina; Borda, Laura Gabriela; The role of efflorescent salts associated with sulfide-rich mine wastes in the short-term cycling of arsenic: Insights from XRD, XAS, and µ-XRF studies; Elsevier Science; Journal of Hazardous Materials; 404; 124158; 2-2021; 1-410304-3894CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0304389420321488info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jhazmat.2020.124158info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:37:54Zoai:ri.conicet.gov.ar:11336/173875instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:37:54.725CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv The role of efflorescent salts associated with sulfide-rich mine wastes in the short-term cycling of arsenic: Insights from XRD, XAS, and µ-XRF studies
title The role of efflorescent salts associated with sulfide-rich mine wastes in the short-term cycling of arsenic: Insights from XRD, XAS, and µ-XRF studies
spellingShingle The role of efflorescent salts associated with sulfide-rich mine wastes in the short-term cycling of arsenic: Insights from XRD, XAS, and µ-XRF studies
Nieva, Nancy Eugenia
AMD
COPIAPITE
SALT EFFLORESCENCES
XAS
title_short The role of efflorescent salts associated with sulfide-rich mine wastes in the short-term cycling of arsenic: Insights from XRD, XAS, and µ-XRF studies
title_full The role of efflorescent salts associated with sulfide-rich mine wastes in the short-term cycling of arsenic: Insights from XRD, XAS, and µ-XRF studies
title_fullStr The role of efflorescent salts associated with sulfide-rich mine wastes in the short-term cycling of arsenic: Insights from XRD, XAS, and µ-XRF studies
title_full_unstemmed The role of efflorescent salts associated with sulfide-rich mine wastes in the short-term cycling of arsenic: Insights from XRD, XAS, and µ-XRF studies
title_sort The role of efflorescent salts associated with sulfide-rich mine wastes in the short-term cycling of arsenic: Insights from XRD, XAS, and µ-XRF studies
dc.creator.none.fl_str_mv Nieva, Nancy Eugenia
Garcia, Maria Gabriela
Borgnino Bianchi, Laura Carolina
Borda, Laura Gabriela
author Nieva, Nancy Eugenia
author_facet Nieva, Nancy Eugenia
Garcia, Maria Gabriela
Borgnino Bianchi, Laura Carolina
Borda, Laura Gabriela
author_role author
author2 Garcia, Maria Gabriela
Borgnino Bianchi, Laura Carolina
Borda, Laura Gabriela
author2_role author
author
author
dc.subject.none.fl_str_mv AMD
COPIAPITE
SALT EFFLORESCENCES
XAS
topic AMD
COPIAPITE
SALT EFFLORESCENCES
XAS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The evaporation of As-rich leachates generated by the weathering of sulfide-rich mine wastes accumulated in abandoned tailing dams of the La Concordia mine, triggers the widespread precipitation of saline crusts and efflorescences. Because these salts are highly soluble, they may release high concentrations of arsenic after rainfall events. Thus, the goal of this work is to assess the solid speciation of As in these efflorescences, which may help to understand the short-term cycling of As in the site. The results reveal that As is present only as As(V), while its capacity to be retained in the salts highly depends on their mineralogical composition. Hydrous sulfates, such as gypsum and epsomite show a very low capacity to scavenge As, while copiapite retains the highest concentrations of this element. The spectroscopic evidences suggest that in this mineral, As(V) is included within the lattice, substituting sulfate in the tetrahedral sites. Because copiapite is highly soluble, it may be considered as one of the most important transient reservoirs of As in the site that can release high concentrations of this hazardous pollutant during the occasional rainfall events produced during the wet season.
Fil: Nieva, Nancy Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina. Universidad Nacional de Catamarca; Argentina
Fil: Garcia, Maria Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Borgnino Bianchi, Laura Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Borda, Laura Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
description The evaporation of As-rich leachates generated by the weathering of sulfide-rich mine wastes accumulated in abandoned tailing dams of the La Concordia mine, triggers the widespread precipitation of saline crusts and efflorescences. Because these salts are highly soluble, they may release high concentrations of arsenic after rainfall events. Thus, the goal of this work is to assess the solid speciation of As in these efflorescences, which may help to understand the short-term cycling of As in the site. The results reveal that As is present only as As(V), while its capacity to be retained in the salts highly depends on their mineralogical composition. Hydrous sulfates, such as gypsum and epsomite show a very low capacity to scavenge As, while copiapite retains the highest concentrations of this element. The spectroscopic evidences suggest that in this mineral, As(V) is included within the lattice, substituting sulfate in the tetrahedral sites. Because copiapite is highly soluble, it may be considered as one of the most important transient reservoirs of As in the site that can release high concentrations of this hazardous pollutant during the occasional rainfall events produced during the wet season.
publishDate 2021
dc.date.none.fl_str_mv 2021-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/173875
Nieva, Nancy Eugenia; Garcia, Maria Gabriela; Borgnino Bianchi, Laura Carolina; Borda, Laura Gabriela; The role of efflorescent salts associated with sulfide-rich mine wastes in the short-term cycling of arsenic: Insights from XRD, XAS, and µ-XRF studies; Elsevier Science; Journal of Hazardous Materials; 404; 124158; 2-2021; 1-41
0304-3894
CONICET Digital
CONICET
url http://hdl.handle.net/11336/173875
identifier_str_mv Nieva, Nancy Eugenia; Garcia, Maria Gabriela; Borgnino Bianchi, Laura Carolina; Borda, Laura Gabriela; The role of efflorescent salts associated with sulfide-rich mine wastes in the short-term cycling of arsenic: Insights from XRD, XAS, and µ-XRF studies; Elsevier Science; Journal of Hazardous Materials; 404; 124158; 2-2021; 1-41
0304-3894
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0304389420321488
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jhazmat.2020.124158
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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