Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases

Autores
Hojamberdiev, Mirabbos; Vargas Balda, Ronald Eduardo; Madriz Ruiz, Lorean Mercedes; Yubuta, Kunio; Kadirova, Zukhra C.; Shaislamov, Ulugbek; Sannegowda, Lokesh Koodlur; Jędruchniewicz, Katarzyna; Typek, Rafał; Teshima, Katsuya; Czech, Bożena
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Conventional wastewater treatment has been found to be ineffective at fully removing various antiviral drugs and emerging pollutants from wastewater. As an advanced oxidation process, heterogeneous photocatalysis is promising for detoxifying such water pollutants due to its mild operating conditions and efficiency. In this study, we explore the oxidative phase transition from bismuth iodide to bismuth oxyiodides by altering the temperature and time of thermal treatment. The influence of the temperature change from 350 °C to 450 °C on the phase transition from bismuth iodide to bismuth oxyiodides is more pronounced compared with the impact of time. This results in the formation of different bismuth oxyiodide crystalline phases with varying optoelectronic properties and photocatalytic activity. The effect of the bismuth iodide-to-bismuth oxyiodide phase transition on the efficiency of the photocatalytic removal of nitazoxanide is investigated in this study. The significant role of the BiOI/Bi4O5I2 heterostructure is established in facilitating the rapid photocatalytic degradation of nitazoxanide, with respective rate constants of k1 (0.051 min−1) and k2 (4.225 mg g−1 min−1) obtained for the photocatalyst sample thermally treated at 375 °C for 1 h. Trapping experiments provide evidence that photoexcited holes and hydroxyl radicals play a crucial role in the photocatalytic degradation of nitazoxanide. The photodegradation of nitazoxanide in aqueous solution over crystalline bismuth (oxy)iodide proceeds via hydrolysis into acetylsalicylic acid and the respective aminonitrothiazol, followed by the deacetylation and decarboxylation processes. Molecular dynamics simulation confirms that the high photocatalytic activity of BiOI/Bi4O5I2 is correlated to the higher adsorption energy due to the formation of a network of close contacts (<3.5 Å) between nitazoxanide molecules and iodine atoms.
Fil: Hojamberdiev, Mirabbos. Technishe Universitat Berlin; Alemania
Fil: Vargas Balda, Ronald Eduardo. Universidad Nacional de San Martín; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Biotecnológicas. Universidad Nacional de San Martín. Instituto de Investigaciones Biotecnológicas; Argentina
Fil: Madriz Ruiz, Lorean Mercedes. Universidad Nacional de San Martín; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Biotecnológicas. Universidad Nacional de San Martín. Instituto de Investigaciones Biotecnológicas; Argentina
Fil: Yubuta, Kunio. Kyushu University; Japón
Fil: Kadirova, Zukhra C.. National University of Uzbekistan; Uzbekistán. Tashkent State Technical University; Uzbekistán
Fil: Shaislamov, Ulugbek. National University Of Uzbekistan; Uzbekistán
Fil: Sannegowda, Lokesh Koodlur. Vijayanagara Sri Krishnadevaraya University; India
Fil: Jędruchniewicz, Katarzyna. Maria Curie-Skłodowska University in Lublin; Polonia
Fil: Typek, Rafał. Maria Curie-Skłodowska University in Lublin; Polonia
Fil: Teshima, Katsuya. Shinshu University; Japón
Fil: Czech, Bożena. Maria Curie-Skłodowska University in Lublin; Polonia
Materia
Nitazoxanide
Bismuth (oxy) iodide
Photocatalysis
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/230217
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/230217
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phasesHojamberdiev, MirabbosVargas Balda, Ronald EduardoMadriz Ruiz, Lorean MercedesYubuta, KunioKadirova, Zukhra C.Shaislamov, UlugbekSannegowda, Lokesh KoodlurJędruchniewicz, KatarzynaTypek, RafałTeshima, KatsuyaCzech, BożenaNitazoxanideBismuth (oxy) iodidePhotocatalysishttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Conventional wastewater treatment has been found to be ineffective at fully removing various antiviral drugs and emerging pollutants from wastewater. As an advanced oxidation process, heterogeneous photocatalysis is promising for detoxifying such water pollutants due to its mild operating conditions and efficiency. In this study, we explore the oxidative phase transition from bismuth iodide to bismuth oxyiodides by altering the temperature and time of thermal treatment. The influence of the temperature change from 350 °C to 450 °C on the phase transition from bismuth iodide to bismuth oxyiodides is more pronounced compared with the impact of time. This results in the formation of different bismuth oxyiodide crystalline phases with varying optoelectronic properties and photocatalytic activity. The effect of the bismuth iodide-to-bismuth oxyiodide phase transition on the efficiency of the photocatalytic removal of nitazoxanide is investigated in this study. The significant role of the BiOI/Bi4O5I2 heterostructure is established in facilitating the rapid photocatalytic degradation of nitazoxanide, with respective rate constants of k1 (0.051 min−1) and k2 (4.225 mg g−1 min−1) obtained for the photocatalyst sample thermally treated at 375 °C for 1 h. Trapping experiments provide evidence that photoexcited holes and hydroxyl radicals play a crucial role in the photocatalytic degradation of nitazoxanide. The photodegradation of nitazoxanide in aqueous solution over crystalline bismuth (oxy)iodide proceeds via hydrolysis into acetylsalicylic acid and the respective aminonitrothiazol, followed by the deacetylation and decarboxylation processes. Molecular dynamics simulation confirms that the high photocatalytic activity of BiOI/Bi4O5I2 is correlated to the higher adsorption energy due to the formation of a network of close contacts (<3.5 Å) between nitazoxanide molecules and iodine atoms.Fil: Hojamberdiev, Mirabbos. Technishe Universitat Berlin; AlemaniaFil: Vargas Balda, Ronald Eduardo. Universidad Nacional de San Martín; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Biotecnológicas. Universidad Nacional de San Martín. Instituto de Investigaciones Biotecnológicas; ArgentinaFil: Madriz Ruiz, Lorean Mercedes. Universidad Nacional de San Martín; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Biotecnológicas. Universidad Nacional de San Martín. Instituto de Investigaciones Biotecnológicas; ArgentinaFil: Yubuta, Kunio. Kyushu University; JapónFil: Kadirova, Zukhra C.. National University of Uzbekistan; Uzbekistán. Tashkent State Technical University; UzbekistánFil: Shaislamov, Ulugbek. National University Of Uzbekistan; UzbekistánFil: Sannegowda, Lokesh Koodlur. Vijayanagara Sri Krishnadevaraya University; IndiaFil: Jędruchniewicz, Katarzyna. Maria Curie-Skłodowska University in Lublin; PoloniaFil: Typek, Rafał. Maria Curie-Skłodowska University in Lublin; PoloniaFil: Teshima, Katsuya. Shinshu University; JapónFil: Czech, Bożena. Maria Curie-Skłodowska University in Lublin; PoloniaRoyal Society of Chemistry2023-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/230217Hojamberdiev, Mirabbos; Vargas Balda, Ronald Eduardo; Madriz Ruiz, Lorean Mercedes; Yubuta, Kunio; Kadirova, Zukhra C.; et al.; Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases; Royal Society of Chemistry; Environmental Science: Nano; 11; 1; 12-2023; 336-3502051-81532051-8161CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/d3en00548hinfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2024/en/d3en00548hinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:41:58Zoai:ri.conicet.gov.ar:11336/230217instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:41:58.677CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases
title Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases
spellingShingle Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases
Hojamberdiev, Mirabbos
Nitazoxanide
Bismuth (oxy) iodide
Photocatalysis
title_short Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases
title_full Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases
title_fullStr Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases
title_full_unstemmed Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases
title_sort Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases
dc.creator.none.fl_str_mv Hojamberdiev, Mirabbos
Vargas Balda, Ronald Eduardo
Madriz Ruiz, Lorean Mercedes
Yubuta, Kunio
Kadirova, Zukhra C.
Shaislamov, Ulugbek
Sannegowda, Lokesh Koodlur
Jędruchniewicz, Katarzyna
Typek, Rafał
Teshima, Katsuya
Czech, Bożena
author Hojamberdiev, Mirabbos
author_facet Hojamberdiev, Mirabbos
Vargas Balda, Ronald Eduardo
Madriz Ruiz, Lorean Mercedes
Yubuta, Kunio
Kadirova, Zukhra C.
Shaislamov, Ulugbek
Sannegowda, Lokesh Koodlur
Jędruchniewicz, Katarzyna
Typek, Rafał
Teshima, Katsuya
Czech, Bożena
author_role author
author2 Vargas Balda, Ronald Eduardo
Madriz Ruiz, Lorean Mercedes
Yubuta, Kunio
Kadirova, Zukhra C.
Shaislamov, Ulugbek
Sannegowda, Lokesh Koodlur
Jędruchniewicz, Katarzyna
Typek, Rafał
Teshima, Katsuya
Czech, Bożena
author2_role author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Nitazoxanide
Bismuth (oxy) iodide
Photocatalysis
topic Nitazoxanide
Bismuth (oxy) iodide
Photocatalysis
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Conventional wastewater treatment has been found to be ineffective at fully removing various antiviral drugs and emerging pollutants from wastewater. As an advanced oxidation process, heterogeneous photocatalysis is promising for detoxifying such water pollutants due to its mild operating conditions and efficiency. In this study, we explore the oxidative phase transition from bismuth iodide to bismuth oxyiodides by altering the temperature and time of thermal treatment. The influence of the temperature change from 350 °C to 450 °C on the phase transition from bismuth iodide to bismuth oxyiodides is more pronounced compared with the impact of time. This results in the formation of different bismuth oxyiodide crystalline phases with varying optoelectronic properties and photocatalytic activity. The effect of the bismuth iodide-to-bismuth oxyiodide phase transition on the efficiency of the photocatalytic removal of nitazoxanide is investigated in this study. The significant role of the BiOI/Bi4O5I2 heterostructure is established in facilitating the rapid photocatalytic degradation of nitazoxanide, with respective rate constants of k1 (0.051 min−1) and k2 (4.225 mg g−1 min−1) obtained for the photocatalyst sample thermally treated at 375 °C for 1 h. Trapping experiments provide evidence that photoexcited holes and hydroxyl radicals play a crucial role in the photocatalytic degradation of nitazoxanide. The photodegradation of nitazoxanide in aqueous solution over crystalline bismuth (oxy)iodide proceeds via hydrolysis into acetylsalicylic acid and the respective aminonitrothiazol, followed by the deacetylation and decarboxylation processes. Molecular dynamics simulation confirms that the high photocatalytic activity of BiOI/Bi4O5I2 is correlated to the higher adsorption energy due to the formation of a network of close contacts (<3.5 Å) between nitazoxanide molecules and iodine atoms.
Fil: Hojamberdiev, Mirabbos. Technishe Universitat Berlin; Alemania
Fil: Vargas Balda, Ronald Eduardo. Universidad Nacional de San Martín; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Biotecnológicas. Universidad Nacional de San Martín. Instituto de Investigaciones Biotecnológicas; Argentina
Fil: Madriz Ruiz, Lorean Mercedes. Universidad Nacional de San Martín; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Biotecnológicas. Universidad Nacional de San Martín. Instituto de Investigaciones Biotecnológicas; Argentina
Fil: Yubuta, Kunio. Kyushu University; Japón
Fil: Kadirova, Zukhra C.. National University of Uzbekistan; Uzbekistán. Tashkent State Technical University; Uzbekistán
Fil: Shaislamov, Ulugbek. National University Of Uzbekistan; Uzbekistán
Fil: Sannegowda, Lokesh Koodlur. Vijayanagara Sri Krishnadevaraya University; India
Fil: Jędruchniewicz, Katarzyna. Maria Curie-Skłodowska University in Lublin; Polonia
Fil: Typek, Rafał. Maria Curie-Skłodowska University in Lublin; Polonia
Fil: Teshima, Katsuya. Shinshu University; Japón
Fil: Czech, Bożena. Maria Curie-Skłodowska University in Lublin; Polonia
description Conventional wastewater treatment has been found to be ineffective at fully removing various antiviral drugs and emerging pollutants from wastewater. As an advanced oxidation process, heterogeneous photocatalysis is promising for detoxifying such water pollutants due to its mild operating conditions and efficiency. In this study, we explore the oxidative phase transition from bismuth iodide to bismuth oxyiodides by altering the temperature and time of thermal treatment. The influence of the temperature change from 350 °C to 450 °C on the phase transition from bismuth iodide to bismuth oxyiodides is more pronounced compared with the impact of time. This results in the formation of different bismuth oxyiodide crystalline phases with varying optoelectronic properties and photocatalytic activity. The effect of the bismuth iodide-to-bismuth oxyiodide phase transition on the efficiency of the photocatalytic removal of nitazoxanide is investigated in this study. The significant role of the BiOI/Bi4O5I2 heterostructure is established in facilitating the rapid photocatalytic degradation of nitazoxanide, with respective rate constants of k1 (0.051 min−1) and k2 (4.225 mg g−1 min−1) obtained for the photocatalyst sample thermally treated at 375 °C for 1 h. Trapping experiments provide evidence that photoexcited holes and hydroxyl radicals play a crucial role in the photocatalytic degradation of nitazoxanide. The photodegradation of nitazoxanide in aqueous solution over crystalline bismuth (oxy)iodide proceeds via hydrolysis into acetylsalicylic acid and the respective aminonitrothiazol, followed by the deacetylation and decarboxylation processes. Molecular dynamics simulation confirms that the high photocatalytic activity of BiOI/Bi4O5I2 is correlated to the higher adsorption energy due to the formation of a network of close contacts (<3.5 Å) between nitazoxanide molecules and iodine atoms.
publishDate 2023
dc.date.none.fl_str_mv 2023-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/230217
Hojamberdiev, Mirabbos; Vargas Balda, Ronald Eduardo; Madriz Ruiz, Lorean Mercedes; Yubuta, Kunio; Kadirova, Zukhra C.; et al.; Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases; Royal Society of Chemistry; Environmental Science: Nano; 11; 1; 12-2023; 336-350
2051-8153
2051-8161
CONICET Digital
CONICET
url http://hdl.handle.net/11336/230217
identifier_str_mv Hojamberdiev, Mirabbos; Vargas Balda, Ronald Eduardo; Madriz Ruiz, Lorean Mercedes; Yubuta, Kunio; Kadirova, Zukhra C.; et al.; Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases; Royal Society of Chemistry; Environmental Science: Nano; 11; 1; 12-2023; 336-350
2051-8153
2051-8161
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/d3en00548h
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2024/en/d3en00548h
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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