Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases
- Autores
- Hojamberdiev, Mirabbos; Vargas Balda, Ronald Eduardo; Madriz Ruiz, Lorean Mercedes; Yubuta, Kunio; Kadirova, Zukhra C.; Shaislamov, Ulugbek; Sannegowda, Lokesh Koodlur; Jędruchniewicz, Katarzyna; Typek, Rafał; Teshima, Katsuya; Czech, Bożena
- Año de publicación
- 2023
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Conventional wastewater treatment has been found to be ineffective at fully removing various antiviral drugs and emerging pollutants from wastewater. As an advanced oxidation process, heterogeneous photocatalysis is promising for detoxifying such water pollutants due to its mild operating conditions and efficiency. In this study, we explore the oxidative phase transition from bismuth iodide to bismuth oxyiodides by altering the temperature and time of thermal treatment. The influence of the temperature change from 350 °C to 450 °C on the phase transition from bismuth iodide to bismuth oxyiodides is more pronounced compared with the impact of time. This results in the formation of different bismuth oxyiodide crystalline phases with varying optoelectronic properties and photocatalytic activity. The effect of the bismuth iodide-to-bismuth oxyiodide phase transition on the efficiency of the photocatalytic removal of nitazoxanide is investigated in this study. The significant role of the BiOI/Bi4O5I2 heterostructure is established in facilitating the rapid photocatalytic degradation of nitazoxanide, with respective rate constants of k1 (0.051 min−1) and k2 (4.225 mg g−1 min−1) obtained for the photocatalyst sample thermally treated at 375 °C for 1 h. Trapping experiments provide evidence that photoexcited holes and hydroxyl radicals play a crucial role in the photocatalytic degradation of nitazoxanide. The photodegradation of nitazoxanide in aqueous solution over crystalline bismuth (oxy)iodide proceeds via hydrolysis into acetylsalicylic acid and the respective aminonitrothiazol, followed by the deacetylation and decarboxylation processes. Molecular dynamics simulation confirms that the high photocatalytic activity of BiOI/Bi4O5I2 is correlated to the higher adsorption energy due to the formation of a network of close contacts (<3.5 Å) between nitazoxanide molecules and iodine atoms.
Fil: Hojamberdiev, Mirabbos. Technishe Universitat Berlin; Alemania
Fil: Vargas Balda, Ronald Eduardo. Universidad Nacional de San Martín; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Biotecnológicas. Universidad Nacional de San Martín. Instituto de Investigaciones Biotecnológicas; Argentina
Fil: Madriz Ruiz, Lorean Mercedes. Universidad Nacional de San Martín; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Biotecnológicas. Universidad Nacional de San Martín. Instituto de Investigaciones Biotecnológicas; Argentina
Fil: Yubuta, Kunio. Kyushu University; Japón
Fil: Kadirova, Zukhra C.. National University of Uzbekistan; Uzbekistán. Tashkent State Technical University; Uzbekistán
Fil: Shaislamov, Ulugbek. National University Of Uzbekistan; Uzbekistán
Fil: Sannegowda, Lokesh Koodlur. Vijayanagara Sri Krishnadevaraya University; India
Fil: Jędruchniewicz, Katarzyna. Maria Curie-Skłodowska University in Lublin; Polonia
Fil: Typek, Rafał. Maria Curie-Skłodowska University in Lublin; Polonia
Fil: Teshima, Katsuya. Shinshu University; Japón
Fil: Czech, Bożena. Maria Curie-Skłodowska University in Lublin; Polonia - Materia
-
Nitazoxanide
Bismuth (oxy) iodide
Photocatalysis - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/230217
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Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phasesHojamberdiev, MirabbosVargas Balda, Ronald EduardoMadriz Ruiz, Lorean MercedesYubuta, KunioKadirova, Zukhra C.Shaislamov, UlugbekSannegowda, Lokesh KoodlurJędruchniewicz, KatarzynaTypek, RafałTeshima, KatsuyaCzech, BożenaNitazoxanideBismuth (oxy) iodidePhotocatalysishttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Conventional wastewater treatment has been found to be ineffective at fully removing various antiviral drugs and emerging pollutants from wastewater. As an advanced oxidation process, heterogeneous photocatalysis is promising for detoxifying such water pollutants due to its mild operating conditions and efficiency. In this study, we explore the oxidative phase transition from bismuth iodide to bismuth oxyiodides by altering the temperature and time of thermal treatment. The influence of the temperature change from 350 °C to 450 °C on the phase transition from bismuth iodide to bismuth oxyiodides is more pronounced compared with the impact of time. This results in the formation of different bismuth oxyiodide crystalline phases with varying optoelectronic properties and photocatalytic activity. The effect of the bismuth iodide-to-bismuth oxyiodide phase transition on the efficiency of the photocatalytic removal of nitazoxanide is investigated in this study. The significant role of the BiOI/Bi4O5I2 heterostructure is established in facilitating the rapid photocatalytic degradation of nitazoxanide, with respective rate constants of k1 (0.051 min−1) and k2 (4.225 mg g−1 min−1) obtained for the photocatalyst sample thermally treated at 375 °C for 1 h. Trapping experiments provide evidence that photoexcited holes and hydroxyl radicals play a crucial role in the photocatalytic degradation of nitazoxanide. The photodegradation of nitazoxanide in aqueous solution over crystalline bismuth (oxy)iodide proceeds via hydrolysis into acetylsalicylic acid and the respective aminonitrothiazol, followed by the deacetylation and decarboxylation processes. Molecular dynamics simulation confirms that the high photocatalytic activity of BiOI/Bi4O5I2 is correlated to the higher adsorption energy due to the formation of a network of close contacts (<3.5 Å) between nitazoxanide molecules and iodine atoms.Fil: Hojamberdiev, Mirabbos. Technishe Universitat Berlin; AlemaniaFil: Vargas Balda, Ronald Eduardo. Universidad Nacional de San Martín; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Biotecnológicas. Universidad Nacional de San Martín. Instituto de Investigaciones Biotecnológicas; ArgentinaFil: Madriz Ruiz, Lorean Mercedes. Universidad Nacional de San Martín; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Biotecnológicas. Universidad Nacional de San Martín. Instituto de Investigaciones Biotecnológicas; ArgentinaFil: Yubuta, Kunio. Kyushu University; JapónFil: Kadirova, Zukhra C.. National University of Uzbekistan; Uzbekistán. Tashkent State Technical University; UzbekistánFil: Shaislamov, Ulugbek. National University Of Uzbekistan; UzbekistánFil: Sannegowda, Lokesh Koodlur. Vijayanagara Sri Krishnadevaraya University; IndiaFil: Jędruchniewicz, Katarzyna. Maria Curie-Skłodowska University in Lublin; PoloniaFil: Typek, Rafał. Maria Curie-Skłodowska University in Lublin; PoloniaFil: Teshima, Katsuya. Shinshu University; JapónFil: Czech, Bożena. Maria Curie-Skłodowska University in Lublin; PoloniaRoyal Society of Chemistry2023-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/230217Hojamberdiev, Mirabbos; Vargas Balda, Ronald Eduardo; Madriz Ruiz, Lorean Mercedes; Yubuta, Kunio; Kadirova, Zukhra C.; et al.; Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases; Royal Society of Chemistry; Environmental Science: Nano; 11; 1; 12-2023; 336-3502051-81532051-8161CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/d3en00548hinfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2024/en/d3en00548hinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:43:44Zoai:ri.conicet.gov.ar:11336/230217instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:43:45.17CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases |
title |
Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases |
spellingShingle |
Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases Hojamberdiev, Mirabbos Nitazoxanide Bismuth (oxy) iodide Photocatalysis |
title_short |
Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases |
title_full |
Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases |
title_fullStr |
Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases |
title_full_unstemmed |
Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases |
title_sort |
Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases |
dc.creator.none.fl_str_mv |
Hojamberdiev, Mirabbos Vargas Balda, Ronald Eduardo Madriz Ruiz, Lorean Mercedes Yubuta, Kunio Kadirova, Zukhra C. Shaislamov, Ulugbek Sannegowda, Lokesh Koodlur Jędruchniewicz, Katarzyna Typek, Rafał Teshima, Katsuya Czech, Bożena |
author |
Hojamberdiev, Mirabbos |
author_facet |
Hojamberdiev, Mirabbos Vargas Balda, Ronald Eduardo Madriz Ruiz, Lorean Mercedes Yubuta, Kunio Kadirova, Zukhra C. Shaislamov, Ulugbek Sannegowda, Lokesh Koodlur Jędruchniewicz, Katarzyna Typek, Rafał Teshima, Katsuya Czech, Bożena |
author_role |
author |
author2 |
Vargas Balda, Ronald Eduardo Madriz Ruiz, Lorean Mercedes Yubuta, Kunio Kadirova, Zukhra C. Shaislamov, Ulugbek Sannegowda, Lokesh Koodlur Jędruchniewicz, Katarzyna Typek, Rafał Teshima, Katsuya Czech, Bożena |
author2_role |
author author author author author author author author author author |
dc.subject.none.fl_str_mv |
Nitazoxanide Bismuth (oxy) iodide Photocatalysis |
topic |
Nitazoxanide Bismuth (oxy) iodide Photocatalysis |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Conventional wastewater treatment has been found to be ineffective at fully removing various antiviral drugs and emerging pollutants from wastewater. As an advanced oxidation process, heterogeneous photocatalysis is promising for detoxifying such water pollutants due to its mild operating conditions and efficiency. In this study, we explore the oxidative phase transition from bismuth iodide to bismuth oxyiodides by altering the temperature and time of thermal treatment. The influence of the temperature change from 350 °C to 450 °C on the phase transition from bismuth iodide to bismuth oxyiodides is more pronounced compared with the impact of time. This results in the formation of different bismuth oxyiodide crystalline phases with varying optoelectronic properties and photocatalytic activity. The effect of the bismuth iodide-to-bismuth oxyiodide phase transition on the efficiency of the photocatalytic removal of nitazoxanide is investigated in this study. The significant role of the BiOI/Bi4O5I2 heterostructure is established in facilitating the rapid photocatalytic degradation of nitazoxanide, with respective rate constants of k1 (0.051 min−1) and k2 (4.225 mg g−1 min−1) obtained for the photocatalyst sample thermally treated at 375 °C for 1 h. Trapping experiments provide evidence that photoexcited holes and hydroxyl radicals play a crucial role in the photocatalytic degradation of nitazoxanide. The photodegradation of nitazoxanide in aqueous solution over crystalline bismuth (oxy)iodide proceeds via hydrolysis into acetylsalicylic acid and the respective aminonitrothiazol, followed by the deacetylation and decarboxylation processes. Molecular dynamics simulation confirms that the high photocatalytic activity of BiOI/Bi4O5I2 is correlated to the higher adsorption energy due to the formation of a network of close contacts (<3.5 Å) between nitazoxanide molecules and iodine atoms. Fil: Hojamberdiev, Mirabbos. Technishe Universitat Berlin; Alemania Fil: Vargas Balda, Ronald Eduardo. Universidad Nacional de San Martín; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Biotecnológicas. Universidad Nacional de San Martín. Instituto de Investigaciones Biotecnológicas; Argentina Fil: Madriz Ruiz, Lorean Mercedes. Universidad Nacional de San Martín; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Biotecnológicas. Universidad Nacional de San Martín. Instituto de Investigaciones Biotecnológicas; Argentina Fil: Yubuta, Kunio. Kyushu University; Japón Fil: Kadirova, Zukhra C.. National University of Uzbekistan; Uzbekistán. Tashkent State Technical University; Uzbekistán Fil: Shaislamov, Ulugbek. National University Of Uzbekistan; Uzbekistán Fil: Sannegowda, Lokesh Koodlur. Vijayanagara Sri Krishnadevaraya University; India Fil: Jędruchniewicz, Katarzyna. Maria Curie-Skłodowska University in Lublin; Polonia Fil: Typek, Rafał. Maria Curie-Skłodowska University in Lublin; Polonia Fil: Teshima, Katsuya. Shinshu University; Japón Fil: Czech, Bożena. Maria Curie-Skłodowska University in Lublin; Polonia |
description |
Conventional wastewater treatment has been found to be ineffective at fully removing various antiviral drugs and emerging pollutants from wastewater. As an advanced oxidation process, heterogeneous photocatalysis is promising for detoxifying such water pollutants due to its mild operating conditions and efficiency. In this study, we explore the oxidative phase transition from bismuth iodide to bismuth oxyiodides by altering the temperature and time of thermal treatment. The influence of the temperature change from 350 °C to 450 °C on the phase transition from bismuth iodide to bismuth oxyiodides is more pronounced compared with the impact of time. This results in the formation of different bismuth oxyiodide crystalline phases with varying optoelectronic properties and photocatalytic activity. The effect of the bismuth iodide-to-bismuth oxyiodide phase transition on the efficiency of the photocatalytic removal of nitazoxanide is investigated in this study. The significant role of the BiOI/Bi4O5I2 heterostructure is established in facilitating the rapid photocatalytic degradation of nitazoxanide, with respective rate constants of k1 (0.051 min−1) and k2 (4.225 mg g−1 min−1) obtained for the photocatalyst sample thermally treated at 375 °C for 1 h. Trapping experiments provide evidence that photoexcited holes and hydroxyl radicals play a crucial role in the photocatalytic degradation of nitazoxanide. The photodegradation of nitazoxanide in aqueous solution over crystalline bismuth (oxy)iodide proceeds via hydrolysis into acetylsalicylic acid and the respective aminonitrothiazol, followed by the deacetylation and decarboxylation processes. Molecular dynamics simulation confirms that the high photocatalytic activity of BiOI/Bi4O5I2 is correlated to the higher adsorption energy due to the formation of a network of close contacts (<3.5 Å) between nitazoxanide molecules and iodine atoms. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/230217 Hojamberdiev, Mirabbos; Vargas Balda, Ronald Eduardo; Madriz Ruiz, Lorean Mercedes; Yubuta, Kunio; Kadirova, Zukhra C.; et al.; Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases; Royal Society of Chemistry; Environmental Science: Nano; 11; 1; 12-2023; 336-350 2051-8153 2051-8161 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/230217 |
identifier_str_mv |
Hojamberdiev, Mirabbos; Vargas Balda, Ronald Eduardo; Madriz Ruiz, Lorean Mercedes; Yubuta, Kunio; Kadirova, Zukhra C.; et al.; Unveiling the origin of the efficient photocatalytic degradation of nitazoxanide over bismuth (oxy)iodide crystalline phases; Royal Society of Chemistry; Environmental Science: Nano; 11; 1; 12-2023; 336-350 2051-8153 2051-8161 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1039/d3en00548h info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2024/en/d3en00548h |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Royal Society of Chemistry |
publisher.none.fl_str_mv |
Royal Society of Chemistry |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
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CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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score |
13.070432 |