Understanding the ion-induced elongation of silver nanoparticles embedded in silica

Autores
Peña Rodríguez, Ovidio; Prada, Alejandro; Olivares, José; Oliver, Alicia; Rodríguez Fernández, Luis; Silva Pereyra, Héctor G.; Bringa, Eduardo Marcial; Perlado, José Manuel; Rivera, Antonio
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work we have studied the elongation of silver nanoparticles irradiated with 40 MeV Bromine ions by means of in situ optical measurements, transmission electron microscopy and molecular dynamics simulations. The localized surface plasmon resonance of silver nanoparticles has a strong dependence on the particle shape and size, which allowed us to obtain the geometrical parameters with remarkable accuracy by means of a fit of the optical spectra. Optical results have been compared with transmission electron microscopy images and molecular dynamics simulations and the agreement is excellent in both cases. An important advantage of in situ measurements is that they yield an extremely detailed information of the full elongation kinetics. Final nanoparticle elongation depends on a complex competition between single-ion deformation, Ostwald ripening and dissolution. Building and validating theoretical models with the data reported in this work should be easier than with the information previously available, due to the unprecedented level of kinetic details obtained from the in situ measurements.
Fil: Peña Rodríguez, Ovidio. Universidad Politécnica de Madrid; España
Fil: Prada, Alejandro. Universidad Politécnica de Madrid; España
Fil: Olivares, José. Consejo Superior de Investigaciones Científicas; España. Universidad Politécnica de Madrid; España
Fil: Oliver, Alicia. Universidad Nacional Autónoma de México; México
Fil: Rodríguez Fernández, Luis. Universidad Nacional Autónoma de México; México
Fil: Silva Pereyra, Héctor G.. Instituto Potosino de Investigación Científica y Tecnológica; México
Fil: Bringa, Eduardo Marcial. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Perlado, José Manuel. Universidad Politécnica de Madrid; España
Fil: Rivera, Antonio. Universidad Politécnica de Madrid; España
Materia
NANOPARTICLES
RADIATION EFFECTS
SILICA
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/59713
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/59713
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Understanding the ion-induced elongation of silver nanoparticles embedded in silicaPeña Rodríguez, OvidioPrada, AlejandroOlivares, JoséOliver, AliciaRodríguez Fernández, LuisSilva Pereyra, Héctor G.Bringa, Eduardo MarcialPerlado, José ManuelRivera, AntonioNANOPARTICLESRADIATION EFFECTSSILICAhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1In this work we have studied the elongation of silver nanoparticles irradiated with 40 MeV Bromine ions by means of in situ optical measurements, transmission electron microscopy and molecular dynamics simulations. The localized surface plasmon resonance of silver nanoparticles has a strong dependence on the particle shape and size, which allowed us to obtain the geometrical parameters with remarkable accuracy by means of a fit of the optical spectra. Optical results have been compared with transmission electron microscopy images and molecular dynamics simulations and the agreement is excellent in both cases. An important advantage of in situ measurements is that they yield an extremely detailed information of the full elongation kinetics. Final nanoparticle elongation depends on a complex competition between single-ion deformation, Ostwald ripening and dissolution. Building and validating theoretical models with the data reported in this work should be easier than with the information previously available, due to the unprecedented level of kinetic details obtained from the in situ measurements.Fil: Peña Rodríguez, Ovidio. Universidad Politécnica de Madrid; EspañaFil: Prada, Alejandro. Universidad Politécnica de Madrid; EspañaFil: Olivares, José. Consejo Superior de Investigaciones Científicas; España. Universidad Politécnica de Madrid; EspañaFil: Oliver, Alicia. Universidad Nacional Autónoma de México; MéxicoFil: Rodríguez Fernández, Luis. Universidad Nacional Autónoma de México; MéxicoFil: Silva Pereyra, Héctor G.. Instituto Potosino de Investigación Científica y Tecnológica; MéxicoFil: Bringa, Eduardo Marcial. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; ArgentinaFil: Perlado, José Manuel. Universidad Politécnica de Madrid; EspañaFil: Rivera, Antonio. Universidad Politécnica de Madrid; EspañaNature Publishing Group2017-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/59713Peña Rodríguez, Ovidio; Prada, Alejandro; Olivares, José; Oliver, Alicia; Rodríguez Fernández, Luis; et al.; Understanding the ion-induced elongation of silver nanoparticles embedded in silica; Nature Publishing Group; Scientific Reports; 7; 1; 12-2017; 1-92045-2322CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1038/s41598-017-01145-0info:eu-repo/semantics/altIdentifier/url/https://www.nature.com/articles/s41598-017-01145-0info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:41:05Zoai:ri.conicet.gov.ar:11336/59713instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:41:06.079CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Understanding the ion-induced elongation of silver nanoparticles embedded in silica
title Understanding the ion-induced elongation of silver nanoparticles embedded in silica
spellingShingle Understanding the ion-induced elongation of silver nanoparticles embedded in silica
Peña Rodríguez, Ovidio
NANOPARTICLES
RADIATION EFFECTS
SILICA
title_short Understanding the ion-induced elongation of silver nanoparticles embedded in silica
title_full Understanding the ion-induced elongation of silver nanoparticles embedded in silica
title_fullStr Understanding the ion-induced elongation of silver nanoparticles embedded in silica
title_full_unstemmed Understanding the ion-induced elongation of silver nanoparticles embedded in silica
title_sort Understanding the ion-induced elongation of silver nanoparticles embedded in silica
dc.creator.none.fl_str_mv Peña Rodríguez, Ovidio
Prada, Alejandro
Olivares, José
Oliver, Alicia
Rodríguez Fernández, Luis
Silva Pereyra, Héctor G.
Bringa, Eduardo Marcial
Perlado, José Manuel
Rivera, Antonio
author Peña Rodríguez, Ovidio
author_facet Peña Rodríguez, Ovidio
Prada, Alejandro
Olivares, José
Oliver, Alicia
Rodríguez Fernández, Luis
Silva Pereyra, Héctor G.
Bringa, Eduardo Marcial
Perlado, José Manuel
Rivera, Antonio
author_role author
author2 Prada, Alejandro
Olivares, José
Oliver, Alicia
Rodríguez Fernández, Luis
Silva Pereyra, Héctor G.
Bringa, Eduardo Marcial
Perlado, José Manuel
Rivera, Antonio
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv NANOPARTICLES
RADIATION EFFECTS
SILICA
topic NANOPARTICLES
RADIATION EFFECTS
SILICA
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this work we have studied the elongation of silver nanoparticles irradiated with 40 MeV Bromine ions by means of in situ optical measurements, transmission electron microscopy and molecular dynamics simulations. The localized surface plasmon resonance of silver nanoparticles has a strong dependence on the particle shape and size, which allowed us to obtain the geometrical parameters with remarkable accuracy by means of a fit of the optical spectra. Optical results have been compared with transmission electron microscopy images and molecular dynamics simulations and the agreement is excellent in both cases. An important advantage of in situ measurements is that they yield an extremely detailed information of the full elongation kinetics. Final nanoparticle elongation depends on a complex competition between single-ion deformation, Ostwald ripening and dissolution. Building and validating theoretical models with the data reported in this work should be easier than with the information previously available, due to the unprecedented level of kinetic details obtained from the in situ measurements.
Fil: Peña Rodríguez, Ovidio. Universidad Politécnica de Madrid; España
Fil: Prada, Alejandro. Universidad Politécnica de Madrid; España
Fil: Olivares, José. Consejo Superior de Investigaciones Científicas; España. Universidad Politécnica de Madrid; España
Fil: Oliver, Alicia. Universidad Nacional Autónoma de México; México
Fil: Rodríguez Fernández, Luis. Universidad Nacional Autónoma de México; México
Fil: Silva Pereyra, Héctor G.. Instituto Potosino de Investigación Científica y Tecnológica; México
Fil: Bringa, Eduardo Marcial. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Perlado, José Manuel. Universidad Politécnica de Madrid; España
Fil: Rivera, Antonio. Universidad Politécnica de Madrid; España
description In this work we have studied the elongation of silver nanoparticles irradiated with 40 MeV Bromine ions by means of in situ optical measurements, transmission electron microscopy and molecular dynamics simulations. The localized surface plasmon resonance of silver nanoparticles has a strong dependence on the particle shape and size, which allowed us to obtain the geometrical parameters with remarkable accuracy by means of a fit of the optical spectra. Optical results have been compared with transmission electron microscopy images and molecular dynamics simulations and the agreement is excellent in both cases. An important advantage of in situ measurements is that they yield an extremely detailed information of the full elongation kinetics. Final nanoparticle elongation depends on a complex competition between single-ion deformation, Ostwald ripening and dissolution. Building and validating theoretical models with the data reported in this work should be easier than with the information previously available, due to the unprecedented level of kinetic details obtained from the in situ measurements.
publishDate 2017
dc.date.none.fl_str_mv 2017-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/59713
Peña Rodríguez, Ovidio; Prada, Alejandro; Olivares, José; Oliver, Alicia; Rodríguez Fernández, Luis; et al.; Understanding the ion-induced elongation of silver nanoparticles embedded in silica; Nature Publishing Group; Scientific Reports; 7; 1; 12-2017; 1-9
2045-2322
CONICET Digital
CONICET
url http://hdl.handle.net/11336/59713
identifier_str_mv Peña Rodríguez, Ovidio; Prada, Alejandro; Olivares, José; Oliver, Alicia; Rodríguez Fernández, Luis; et al.; Understanding the ion-induced elongation of silver nanoparticles embedded in silica; Nature Publishing Group; Scientific Reports; 7; 1; 12-2017; 1-9
2045-2322
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1038/s41598-017-01145-0
info:eu-repo/semantics/altIdentifier/url/https://www.nature.com/articles/s41598-017-01145-0
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Nature Publishing Group
publisher.none.fl_str_mv Nature Publishing Group
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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