Triplet state of 4-methoxybenzyl alcohol chemisorbed on silica nanoparticles

Autores
Arce, Valeria Beatriz; Bertolotti, Sonia Graciela; Oliveira, Fernando J. V. E.; Airoldi, Claudio; Arques, Antonio; Santos Juanes, Lucas; Gonzalez, Monica Cristina; Cobos, Carlos Jorge; Allegretti, Patricia Ercilia; Martire, Daniel Osvaldo
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The knowledge of photochemical kinetics in colloidal systems is important in understanding environmental photochemistry on dispersed solid surfaces. As model materials for the chemically sorbed organic compounds present in natural environments, modified silica nanoparticles (NPs) were obtained here by condensation of the silanol groups of fumed silica nanoparticles with 4-methoxybenzyl alcohol. These particles were characterized by different techniques. To evaluate their toxicity, the inhibition of the natural luminescence emission of the marine bacterium Vibrio fischeri in suspensions of the particles was measured. Laser flash-photolysis experiments (λexc = 266 nm) performed with NP suspensions in acetonitrile-aqueous phosphate buffer mixtures showed the formation of the lowest triplet excited state of the chemisorbed organic groups (λmax = 390 nm). DFT calculations of the absorption spectrum of this radical support the assignment. From the calculated triplet energy, a thermodynamically favorable energy transfer from these triplet states to oxygen to yield singlet molecular oxygen is predicted. Avalue of 0.09 was measured for the quantum yield of singlet molecular oxygen generation by air-saturated suspensions of the nanoparticles in the mixture of solvents acetonitrile-aqueous phosphate buffer. The quantum yield of singlet molecular oxygen generation by the free 4-methoxybenzyl alcohol in the same solvent is 0.31.
Fil: Arce, Valeria Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina
Fil: Bertolotti, Sonia Graciela. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Oliveira, Fernando J. V. E.. Universidade Federal da Paraíba; Brasil
Fil: Airoldi, Claudio. Universidade Estadual de Campinas; Brasil
Fil: Arques, Antonio. Universidad Politécnica de Valencia; España
Fil: Santos Juanes, Lucas. Universidad Politécnica de Valencia; España
Fil: Gonzalez, Monica Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Cobos, Carlos Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Allegretti, Patricia Ercilia. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina
Fil: Martire, Daniel Osvaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Materia
Triplet State
Chemisorbed
Silica Nanoparticles
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/81737
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Triplet state of 4-methoxybenzyl alcohol chemisorbed on silica nanoparticlesArce, Valeria BeatrizBertolotti, Sonia GracielaOliveira, Fernando J. V. E.Airoldi, ClaudioArques, AntonioSantos Juanes, LucasGonzalez, Monica CristinaCobos, Carlos JorgeAllegretti, Patricia ErciliaMartire, Daniel OsvaldoTriplet StateChemisorbedSilica Nanoparticleshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The knowledge of photochemical kinetics in colloidal systems is important in understanding environmental photochemistry on dispersed solid surfaces. As model materials for the chemically sorbed organic compounds present in natural environments, modified silica nanoparticles (NPs) were obtained here by condensation of the silanol groups of fumed silica nanoparticles with 4-methoxybenzyl alcohol. These particles were characterized by different techniques. To evaluate their toxicity, the inhibition of the natural luminescence emission of the marine bacterium Vibrio fischeri in suspensions of the particles was measured. Laser flash-photolysis experiments (λexc = 266 nm) performed with NP suspensions in acetonitrile-aqueous phosphate buffer mixtures showed the formation of the lowest triplet excited state of the chemisorbed organic groups (λmax = 390 nm). DFT calculations of the absorption spectrum of this radical support the assignment. From the calculated triplet energy, a thermodynamically favorable energy transfer from these triplet states to oxygen to yield singlet molecular oxygen is predicted. Avalue of 0.09 was measured for the quantum yield of singlet molecular oxygen generation by air-saturated suspensions of the nanoparticles in the mixture of solvents acetonitrile-aqueous phosphate buffer. The quantum yield of singlet molecular oxygen generation by the free 4-methoxybenzyl alcohol in the same solvent is 0.31.Fil: Arce, Valeria Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; ArgentinaFil: Bertolotti, Sonia Graciela. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaFil: Oliveira, Fernando J. V. E.. Universidade Federal da Paraíba; BrasilFil: Airoldi, Claudio. Universidade Estadual de Campinas; BrasilFil: Arques, Antonio. Universidad Politécnica de Valencia; EspañaFil: Santos Juanes, Lucas. Universidad Politécnica de Valencia; EspañaFil: Gonzalez, Monica Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Cobos, Carlos Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Allegretti, Patricia Ercilia. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; ArgentinaFil: Martire, Daniel Osvaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaRoyal Society of Chemistry2012-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/81737Arce, Valeria Beatriz; Bertolotti, Sonia Graciela; Oliveira, Fernando J. V. E.; Airoldi, Claudio; Arques, Antonio; et al.; Triplet state of 4-methoxybenzyl alcohol chemisorbed on silica nanoparticles; Royal Society of Chemistry; Photochemical and Photobiological Sciences; 11; 6; 6-2012; 1032-10401474-905XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2012/PP/c2pp05370e#!divAbstractinfo:eu-repo/semantics/altIdentifier/doi/10.1039/c2pp05370einfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:07:07Zoai:ri.conicet.gov.ar:11336/81737instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:07:07.389CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Triplet state of 4-methoxybenzyl alcohol chemisorbed on silica nanoparticles
title Triplet state of 4-methoxybenzyl alcohol chemisorbed on silica nanoparticles
spellingShingle Triplet state of 4-methoxybenzyl alcohol chemisorbed on silica nanoparticles
Arce, Valeria Beatriz
Triplet State
Chemisorbed
Silica Nanoparticles
title_short Triplet state of 4-methoxybenzyl alcohol chemisorbed on silica nanoparticles
title_full Triplet state of 4-methoxybenzyl alcohol chemisorbed on silica nanoparticles
title_fullStr Triplet state of 4-methoxybenzyl alcohol chemisorbed on silica nanoparticles
title_full_unstemmed Triplet state of 4-methoxybenzyl alcohol chemisorbed on silica nanoparticles
title_sort Triplet state of 4-methoxybenzyl alcohol chemisorbed on silica nanoparticles
dc.creator.none.fl_str_mv Arce, Valeria Beatriz
Bertolotti, Sonia Graciela
Oliveira, Fernando J. V. E.
Airoldi, Claudio
Arques, Antonio
Santos Juanes, Lucas
Gonzalez, Monica Cristina
Cobos, Carlos Jorge
Allegretti, Patricia Ercilia
Martire, Daniel Osvaldo
author Arce, Valeria Beatriz
author_facet Arce, Valeria Beatriz
Bertolotti, Sonia Graciela
Oliveira, Fernando J. V. E.
Airoldi, Claudio
Arques, Antonio
Santos Juanes, Lucas
Gonzalez, Monica Cristina
Cobos, Carlos Jorge
Allegretti, Patricia Ercilia
Martire, Daniel Osvaldo
author_role author
author2 Bertolotti, Sonia Graciela
Oliveira, Fernando J. V. E.
Airoldi, Claudio
Arques, Antonio
Santos Juanes, Lucas
Gonzalez, Monica Cristina
Cobos, Carlos Jorge
Allegretti, Patricia Ercilia
Martire, Daniel Osvaldo
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Triplet State
Chemisorbed
Silica Nanoparticles
topic Triplet State
Chemisorbed
Silica Nanoparticles
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The knowledge of photochemical kinetics in colloidal systems is important in understanding environmental photochemistry on dispersed solid surfaces. As model materials for the chemically sorbed organic compounds present in natural environments, modified silica nanoparticles (NPs) were obtained here by condensation of the silanol groups of fumed silica nanoparticles with 4-methoxybenzyl alcohol. These particles were characterized by different techniques. To evaluate their toxicity, the inhibition of the natural luminescence emission of the marine bacterium Vibrio fischeri in suspensions of the particles was measured. Laser flash-photolysis experiments (λexc = 266 nm) performed with NP suspensions in acetonitrile-aqueous phosphate buffer mixtures showed the formation of the lowest triplet excited state of the chemisorbed organic groups (λmax = 390 nm). DFT calculations of the absorption spectrum of this radical support the assignment. From the calculated triplet energy, a thermodynamically favorable energy transfer from these triplet states to oxygen to yield singlet molecular oxygen is predicted. Avalue of 0.09 was measured for the quantum yield of singlet molecular oxygen generation by air-saturated suspensions of the nanoparticles in the mixture of solvents acetonitrile-aqueous phosphate buffer. The quantum yield of singlet molecular oxygen generation by the free 4-methoxybenzyl alcohol in the same solvent is 0.31.
Fil: Arce, Valeria Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina
Fil: Bertolotti, Sonia Graciela. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Oliveira, Fernando J. V. E.. Universidade Federal da Paraíba; Brasil
Fil: Airoldi, Claudio. Universidade Estadual de Campinas; Brasil
Fil: Arques, Antonio. Universidad Politécnica de Valencia; España
Fil: Santos Juanes, Lucas. Universidad Politécnica de Valencia; España
Fil: Gonzalez, Monica Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Cobos, Carlos Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Allegretti, Patricia Ercilia. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina
Fil: Martire, Daniel Osvaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
description The knowledge of photochemical kinetics in colloidal systems is important in understanding environmental photochemistry on dispersed solid surfaces. As model materials for the chemically sorbed organic compounds present in natural environments, modified silica nanoparticles (NPs) were obtained here by condensation of the silanol groups of fumed silica nanoparticles with 4-methoxybenzyl alcohol. These particles were characterized by different techniques. To evaluate their toxicity, the inhibition of the natural luminescence emission of the marine bacterium Vibrio fischeri in suspensions of the particles was measured. Laser flash-photolysis experiments (λexc = 266 nm) performed with NP suspensions in acetonitrile-aqueous phosphate buffer mixtures showed the formation of the lowest triplet excited state of the chemisorbed organic groups (λmax = 390 nm). DFT calculations of the absorption spectrum of this radical support the assignment. From the calculated triplet energy, a thermodynamically favorable energy transfer from these triplet states to oxygen to yield singlet molecular oxygen is predicted. Avalue of 0.09 was measured for the quantum yield of singlet molecular oxygen generation by air-saturated suspensions of the nanoparticles in the mixture of solvents acetonitrile-aqueous phosphate buffer. The quantum yield of singlet molecular oxygen generation by the free 4-methoxybenzyl alcohol in the same solvent is 0.31.
publishDate 2012
dc.date.none.fl_str_mv 2012-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/81737
Arce, Valeria Beatriz; Bertolotti, Sonia Graciela; Oliveira, Fernando J. V. E.; Airoldi, Claudio; Arques, Antonio; et al.; Triplet state of 4-methoxybenzyl alcohol chemisorbed on silica nanoparticles; Royal Society of Chemistry; Photochemical and Photobiological Sciences; 11; 6; 6-2012; 1032-1040
1474-905X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/81737
identifier_str_mv Arce, Valeria Beatriz; Bertolotti, Sonia Graciela; Oliveira, Fernando J. V. E.; Airoldi, Claudio; Arques, Antonio; et al.; Triplet state of 4-methoxybenzyl alcohol chemisorbed on silica nanoparticles; Royal Society of Chemistry; Photochemical and Photobiological Sciences; 11; 6; 6-2012; 1032-1040
1474-905X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2012/PP/c2pp05370e#!divAbstract
info:eu-repo/semantics/altIdentifier/doi/10.1039/c2pp05370e
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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