Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment

Autores
Gamba, Martina; Flores, Federico Manuel; Madejová, Jana; Torres Sanchez, Rosa Maria
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
To remove fungicide Imazalil (IMZ) (commercial formulation) from agricultural wastewater, adsorption was performed and compared among montmorillonite (Mt) and four organo-Mts (OMts), with different octadecyltrimethylammonium (ODTMA) loadings. The agglomerates size increase of OMts with respect to Mt found encourages the use of the former in agricultural wastewater treatment. Characterization of the OMts adsorbents by powder X-ray diffraction, infrared spectroscopy, and thermogravimetric analyses, indicated that ODTMA was present in the interlayer with diff erent molecular arrangements, a diminution of the thermal stability of the OMts and an increase of ODTMA loading being observed at the same time. Zeta potential measurements showed electric surface charge reversion from negative to positive when the surfactant loading exceeded 100% of the clay cation exchange capacity (CEC). The IMZ adsorption on the raw Mt showed high pH dependence and affinity toward the fungicide, while OMts showed best IMZ adsorption capacity at high IMZ concentrations inversely related with the ODTMA loading. The characterization of IMZ-adsorbed samples indicated that for IMZ-Mt the interaction between IMZH+ and the siloxane surface was electrostatic. For IMZ-OMt samples the presence of new XRD and FTIR peaks suggested different IMZ interlayer arrangements and direct interaction with the surface, respectively. Analysis of zeta potential measurements indicated synergetic effects between the ODTMA and IMZ molecules at the external surface.
Fil: Gamba, Martina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Flores, Federico Manuel. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Madejová, Jana. Slovak Academy of Sciences; Eslovaquia
Fil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Materia
Imazalil
Montmorillonita
Nano-Montmorillonita
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/37767
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/37767
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatmentGamba, MartinaFlores, Federico ManuelMadejová, JanaTorres Sanchez, Rosa MariaImazalilMontmorillonitaNano-Montmorillonitahttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1To remove fungicide Imazalil (IMZ) (commercial formulation) from agricultural wastewater, adsorption was performed and compared among montmorillonite (Mt) and four organo-Mts (OMts), with different octadecyltrimethylammonium (ODTMA) loadings. The agglomerates size increase of OMts with respect to Mt found encourages the use of the former in agricultural wastewater treatment. Characterization of the OMts adsorbents by powder X-ray diffraction, infrared spectroscopy, and thermogravimetric analyses, indicated that ODTMA was present in the interlayer with diff erent molecular arrangements, a diminution of the thermal stability of the OMts and an increase of ODTMA loading being observed at the same time. Zeta potential measurements showed electric surface charge reversion from negative to positive when the surfactant loading exceeded 100% of the clay cation exchange capacity (CEC). The IMZ adsorption on the raw Mt showed high pH dependence and affinity toward the fungicide, while OMts showed best IMZ adsorption capacity at high IMZ concentrations inversely related with the ODTMA loading. The characterization of IMZ-adsorbed samples indicated that for IMZ-Mt the interaction between IMZH+ and the siloxane surface was electrostatic. For IMZ-OMt samples the presence of new XRD and FTIR peaks suggested different IMZ interlayer arrangements and direct interaction with the surface, respectively. Analysis of zeta potential measurements indicated synergetic effects between the ODTMA and IMZ molecules at the external surface.Fil: Gamba, Martina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Flores, Federico Manuel. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Madejová, Jana. Slovak Academy of Sciences; EslovaquiaFil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaAmerican Chemical Society2015-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/37767Gamba, Martina; Flores, Federico Manuel; Madejová, Jana; Torres Sanchez, Rosa Maria; Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment; American Chemical Society; Industrial & Engineering Chemical Research; 54; 5; 2-2015; 1529-15380888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie5035804info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/ie5035804info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:52:18Zoai:ri.conicet.gov.ar:11336/37767instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:52:19.197CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment
title Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment
spellingShingle Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment
Gamba, Martina
Imazalil
Montmorillonita
Nano-Montmorillonita
title_short Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment
title_full Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment
title_fullStr Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment
title_full_unstemmed Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment
title_sort Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment
dc.creator.none.fl_str_mv Gamba, Martina
Flores, Federico Manuel
Madejová, Jana
Torres Sanchez, Rosa Maria
author Gamba, Martina
author_facet Gamba, Martina
Flores, Federico Manuel
Madejová, Jana
Torres Sanchez, Rosa Maria
author_role author
author2 Flores, Federico Manuel
Madejová, Jana
Torres Sanchez, Rosa Maria
author2_role author
author
author
dc.subject.none.fl_str_mv Imazalil
Montmorillonita
Nano-Montmorillonita
topic Imazalil
Montmorillonita
Nano-Montmorillonita
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv To remove fungicide Imazalil (IMZ) (commercial formulation) from agricultural wastewater, adsorption was performed and compared among montmorillonite (Mt) and four organo-Mts (OMts), with different octadecyltrimethylammonium (ODTMA) loadings. The agglomerates size increase of OMts with respect to Mt found encourages the use of the former in agricultural wastewater treatment. Characterization of the OMts adsorbents by powder X-ray diffraction, infrared spectroscopy, and thermogravimetric analyses, indicated that ODTMA was present in the interlayer with diff erent molecular arrangements, a diminution of the thermal stability of the OMts and an increase of ODTMA loading being observed at the same time. Zeta potential measurements showed electric surface charge reversion from negative to positive when the surfactant loading exceeded 100% of the clay cation exchange capacity (CEC). The IMZ adsorption on the raw Mt showed high pH dependence and affinity toward the fungicide, while OMts showed best IMZ adsorption capacity at high IMZ concentrations inversely related with the ODTMA loading. The characterization of IMZ-adsorbed samples indicated that for IMZ-Mt the interaction between IMZH+ and the siloxane surface was electrostatic. For IMZ-OMt samples the presence of new XRD and FTIR peaks suggested different IMZ interlayer arrangements and direct interaction with the surface, respectively. Analysis of zeta potential measurements indicated synergetic effects between the ODTMA and IMZ molecules at the external surface.
Fil: Gamba, Martina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Flores, Federico Manuel. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Madejová, Jana. Slovak Academy of Sciences; Eslovaquia
Fil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
description To remove fungicide Imazalil (IMZ) (commercial formulation) from agricultural wastewater, adsorption was performed and compared among montmorillonite (Mt) and four organo-Mts (OMts), with different octadecyltrimethylammonium (ODTMA) loadings. The agglomerates size increase of OMts with respect to Mt found encourages the use of the former in agricultural wastewater treatment. Characterization of the OMts adsorbents by powder X-ray diffraction, infrared spectroscopy, and thermogravimetric analyses, indicated that ODTMA was present in the interlayer with diff erent molecular arrangements, a diminution of the thermal stability of the OMts and an increase of ODTMA loading being observed at the same time. Zeta potential measurements showed electric surface charge reversion from negative to positive when the surfactant loading exceeded 100% of the clay cation exchange capacity (CEC). The IMZ adsorption on the raw Mt showed high pH dependence and affinity toward the fungicide, while OMts showed best IMZ adsorption capacity at high IMZ concentrations inversely related with the ODTMA loading. The characterization of IMZ-adsorbed samples indicated that for IMZ-Mt the interaction between IMZH+ and the siloxane surface was electrostatic. For IMZ-OMt samples the presence of new XRD and FTIR peaks suggested different IMZ interlayer arrangements and direct interaction with the surface, respectively. Analysis of zeta potential measurements indicated synergetic effects between the ODTMA and IMZ molecules at the external surface.
publishDate 2015
dc.date.none.fl_str_mv 2015-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/37767
Gamba, Martina; Flores, Federico Manuel; Madejová, Jana; Torres Sanchez, Rosa Maria; Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment; American Chemical Society; Industrial & Engineering Chemical Research; 54; 5; 2-2015; 1529-1538
0888-5885
CONICET Digital
CONICET
url http://hdl.handle.net/11336/37767
identifier_str_mv Gamba, Martina; Flores, Federico Manuel; Madejová, Jana; Torres Sanchez, Rosa Maria; Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment; American Chemical Society; Industrial & Engineering Chemical Research; 54; 5; 2-2015; 1529-1538
0888-5885
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ie5035804
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/ie5035804
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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