Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment
- Autores
- Gamba, Martina; Flores, Federico Manuel; Madejová, Jana; Torres Sanchez, Rosa Maria
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- To remove fungicide Imazalil (IMZ) (commercial formulation) from agricultural wastewater, adsorption was performed and compared among montmorillonite (Mt) and four organo-Mts (OMts), with different octadecyltrimethylammonium (ODTMA) loadings. The agglomerates size increase of OMts with respect to Mt found encourages the use of the former in agricultural wastewater treatment. Characterization of the OMts adsorbents by powder X-ray diffraction, infrared spectroscopy, and thermogravimetric analyses, indicated that ODTMA was present in the interlayer with diff erent molecular arrangements, a diminution of the thermal stability of the OMts and an increase of ODTMA loading being observed at the same time. Zeta potential measurements showed electric surface charge reversion from negative to positive when the surfactant loading exceeded 100% of the clay cation exchange capacity (CEC). The IMZ adsorption on the raw Mt showed high pH dependence and affinity toward the fungicide, while OMts showed best IMZ adsorption capacity at high IMZ concentrations inversely related with the ODTMA loading. The characterization of IMZ-adsorbed samples indicated that for IMZ-Mt the interaction between IMZH+ and the siloxane surface was electrostatic. For IMZ-OMt samples the presence of new XRD and FTIR peaks suggested different IMZ interlayer arrangements and direct interaction with the surface, respectively. Analysis of zeta potential measurements indicated synergetic effects between the ODTMA and IMZ molecules at the external surface.
Fil: Gamba, Martina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Flores, Federico Manuel. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Madejová, Jana. Slovak Academy of Sciences; Eslovaquia
Fil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina - Materia
-
Imazalil
Montmorillonita
Nano-Montmorillonita - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/37767
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CONICET Digital (CONICET) |
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Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatmentGamba, MartinaFlores, Federico ManuelMadejová, JanaTorres Sanchez, Rosa MariaImazalilMontmorillonitaNano-Montmorillonitahttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1To remove fungicide Imazalil (IMZ) (commercial formulation) from agricultural wastewater, adsorption was performed and compared among montmorillonite (Mt) and four organo-Mts (OMts), with different octadecyltrimethylammonium (ODTMA) loadings. The agglomerates size increase of OMts with respect to Mt found encourages the use of the former in agricultural wastewater treatment. Characterization of the OMts adsorbents by powder X-ray diffraction, infrared spectroscopy, and thermogravimetric analyses, indicated that ODTMA was present in the interlayer with diff erent molecular arrangements, a diminution of the thermal stability of the OMts and an increase of ODTMA loading being observed at the same time. Zeta potential measurements showed electric surface charge reversion from negative to positive when the surfactant loading exceeded 100% of the clay cation exchange capacity (CEC). The IMZ adsorption on the raw Mt showed high pH dependence and affinity toward the fungicide, while OMts showed best IMZ adsorption capacity at high IMZ concentrations inversely related with the ODTMA loading. The characterization of IMZ-adsorbed samples indicated that for IMZ-Mt the interaction between IMZH+ and the siloxane surface was electrostatic. For IMZ-OMt samples the presence of new XRD and FTIR peaks suggested different IMZ interlayer arrangements and direct interaction with the surface, respectively. Analysis of zeta potential measurements indicated synergetic effects between the ODTMA and IMZ molecules at the external surface.Fil: Gamba, Martina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Flores, Federico Manuel. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Madejová, Jana. Slovak Academy of Sciences; EslovaquiaFil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaAmerican Chemical Society2015-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/37767Gamba, Martina; Flores, Federico Manuel; Madejová, Jana; Torres Sanchez, Rosa Maria; Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment; American Chemical Society; Industrial & Engineering Chemical Research; 54; 5; 2-2015; 1529-15380888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie5035804info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/ie5035804info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:53:19Zoai:ri.conicet.gov.ar:11336/37767instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:53:19.341CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment |
title |
Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment |
spellingShingle |
Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment Gamba, Martina Imazalil Montmorillonita Nano-Montmorillonita |
title_short |
Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment |
title_full |
Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment |
title_fullStr |
Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment |
title_full_unstemmed |
Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment |
title_sort |
Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment |
dc.creator.none.fl_str_mv |
Gamba, Martina Flores, Federico Manuel Madejová, Jana Torres Sanchez, Rosa Maria |
author |
Gamba, Martina |
author_facet |
Gamba, Martina Flores, Federico Manuel Madejová, Jana Torres Sanchez, Rosa Maria |
author_role |
author |
author2 |
Flores, Federico Manuel Madejová, Jana Torres Sanchez, Rosa Maria |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Imazalil Montmorillonita Nano-Montmorillonita |
topic |
Imazalil Montmorillonita Nano-Montmorillonita |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.5 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
To remove fungicide Imazalil (IMZ) (commercial formulation) from agricultural wastewater, adsorption was performed and compared among montmorillonite (Mt) and four organo-Mts (OMts), with different octadecyltrimethylammonium (ODTMA) loadings. The agglomerates size increase of OMts with respect to Mt found encourages the use of the former in agricultural wastewater treatment. Characterization of the OMts adsorbents by powder X-ray diffraction, infrared spectroscopy, and thermogravimetric analyses, indicated that ODTMA was present in the interlayer with diff erent molecular arrangements, a diminution of the thermal stability of the OMts and an increase of ODTMA loading being observed at the same time. Zeta potential measurements showed electric surface charge reversion from negative to positive when the surfactant loading exceeded 100% of the clay cation exchange capacity (CEC). The IMZ adsorption on the raw Mt showed high pH dependence and affinity toward the fungicide, while OMts showed best IMZ adsorption capacity at high IMZ concentrations inversely related with the ODTMA loading. The characterization of IMZ-adsorbed samples indicated that for IMZ-Mt the interaction between IMZH+ and the siloxane surface was electrostatic. For IMZ-OMt samples the presence of new XRD and FTIR peaks suggested different IMZ interlayer arrangements and direct interaction with the surface, respectively. Analysis of zeta potential measurements indicated synergetic effects between the ODTMA and IMZ molecules at the external surface. Fil: Gamba, Martina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina Fil: Flores, Federico Manuel. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina Fil: Madejová, Jana. Slovak Academy of Sciences; Eslovaquia Fil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina |
description |
To remove fungicide Imazalil (IMZ) (commercial formulation) from agricultural wastewater, adsorption was performed and compared among montmorillonite (Mt) and four organo-Mts (OMts), with different octadecyltrimethylammonium (ODTMA) loadings. The agglomerates size increase of OMts with respect to Mt found encourages the use of the former in agricultural wastewater treatment. Characterization of the OMts adsorbents by powder X-ray diffraction, infrared spectroscopy, and thermogravimetric analyses, indicated that ODTMA was present in the interlayer with diff erent molecular arrangements, a diminution of the thermal stability of the OMts and an increase of ODTMA loading being observed at the same time. Zeta potential measurements showed electric surface charge reversion from negative to positive when the surfactant loading exceeded 100% of the clay cation exchange capacity (CEC). The IMZ adsorption on the raw Mt showed high pH dependence and affinity toward the fungicide, while OMts showed best IMZ adsorption capacity at high IMZ concentrations inversely related with the ODTMA loading. The characterization of IMZ-adsorbed samples indicated that for IMZ-Mt the interaction between IMZH+ and the siloxane surface was electrostatic. For IMZ-OMt samples the presence of new XRD and FTIR peaks suggested different IMZ interlayer arrangements and direct interaction with the surface, respectively. Analysis of zeta potential measurements indicated synergetic effects between the ODTMA and IMZ molecules at the external surface. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-02 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/37767 Gamba, Martina; Flores, Federico Manuel; Madejová, Jana; Torres Sanchez, Rosa Maria; Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment; American Chemical Society; Industrial & Engineering Chemical Research; 54; 5; 2-2015; 1529-1538 0888-5885 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/37767 |
identifier_str_mv |
Gamba, Martina; Flores, Federico Manuel; Madejová, Jana; Torres Sanchez, Rosa Maria; Comparison of imazalil removal onto montmorillonite and nanomontmorillonite and adsorption surface sites involved: An approach for agricultural wastewater treatment; American Chemical Society; Industrial & Engineering Chemical Research; 54; 5; 2-2015; 1529-1538 0888-5885 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1021/ie5035804 info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/ie5035804 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842269215585730560 |
score |
13.13397 |