Synthesis and characterization of magnetic-montmorillonite and magnetic-organo-montmorillonite: Surface sites involved on cobalt sorption

Autores
Barraqué, Facundo; Montes, María Luciana; Fernandez, Mariela Alejandra; Mercader, Roberto Carlos; Candal, Roberto Jorge; Torres Sanchez, Rosa Maria
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Montmorillonite magnetic-clay nanoparticles (MtMag) and its exchanged product with hexadecyltrimethylammonium (O100MtMag) were synthetized by alkaline oxidation of ferrous sulfate, characterized by diverse techniques (XRD, Mössbauer spectroscopy, VSM, SEM, Zeta Potential, total specific surface area, TOC) and used as Co2+ sorbents. The magnetic characteristic of these materials allows them to be used in cases of decontamination of water polluted with dangerous materials, such as radioactive ones, reducing the risk to health due to indirect manipulation by means of external magnetic fields. For comparison, samples without magnetic material (O100Mt) and in absence of clay (Mag) were also synthetized. The synthesis of magnetic materials disclosed the presence of magnetite and goethite nanoparticles, while the saturation magnetization displayed by O100MtMag was higher than that obtained for MtMag, indicating the existence of a higher amount of magnetite particles in the first one. This suggests that O100MtMag could be manipulated easier than MtMag through external magnetic fields. Moreover, the surface electric charge of MtMag sample can be described as a mixture of Magnetite and montmorillonite, with ratios related to the surface of both components. Co2+ sorption percentages, using an initial Co2+ concentration of 85 mg/L, resulted similar for the different materials while the Co2+ sorption was ascribed to interactions with the montmorillonite interlayer and external surface. The current results indicate that O100MtMag is a more appropriate material than MtMag for Co2+ removal by external magnets.
Fil: Barraqué, Facundo. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Montes, María Luciana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Fernandez, Mariela Alejandra. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Mercader, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Candal, Roberto Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Instituto de Investigación en Ingeniería Ambiental; Argentina
Fil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Materia
MAGNETIC COMPOSITE SYNTHESIS
MAGNETITE
MONTMORILLONITE
ORGANO-MONTMORILLONITE COBALT SORPTION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/95324
Acceder
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spelling Synthesis and characterization of magnetic-montmorillonite and magnetic-organo-montmorillonite: Surface sites involved on cobalt sorptionBarraqué, FacundoMontes, María LucianaFernandez, Mariela AlejandraMercader, Roberto CarlosCandal, Roberto JorgeTorres Sanchez, Rosa MariaMAGNETIC COMPOSITE SYNTHESISMAGNETITEMONTMORILLONITEORGANO-MONTMORILLONITE COBALT SORPTIONhttps://purl.org/becyt/ford/2.7https://purl.org/becyt/ford/2Montmorillonite magnetic-clay nanoparticles (MtMag) and its exchanged product with hexadecyltrimethylammonium (O100MtMag) were synthetized by alkaline oxidation of ferrous sulfate, characterized by diverse techniques (XRD, Mössbauer spectroscopy, VSM, SEM, Zeta Potential, total specific surface area, TOC) and used as Co2+ sorbents. The magnetic characteristic of these materials allows them to be used in cases of decontamination of water polluted with dangerous materials, such as radioactive ones, reducing the risk to health due to indirect manipulation by means of external magnetic fields. For comparison, samples without magnetic material (O100Mt) and in absence of clay (Mag) were also synthetized. The synthesis of magnetic materials disclosed the presence of magnetite and goethite nanoparticles, while the saturation magnetization displayed by O100MtMag was higher than that obtained for MtMag, indicating the existence of a higher amount of magnetite particles in the first one. This suggests that O100MtMag could be manipulated easier than MtMag through external magnetic fields. Moreover, the surface electric charge of MtMag sample can be described as a mixture of Magnetite and montmorillonite, with ratios related to the surface of both components. Co2+ sorption percentages, using an initial Co2+ concentration of 85 mg/L, resulted similar for the different materials while the Co2+ sorption was ascribed to interactions with the montmorillonite interlayer and external surface. The current results indicate that O100MtMag is a more appropriate material than MtMag for Co2+ removal by external magnets.Fil: Barraqué, Facundo. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Montes, María Luciana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Fernandez, Mariela Alejandra. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Mercader, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Candal, Roberto Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Instituto de Investigación en Ingeniería Ambiental; ArgentinaFil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaElsevier Science2018-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/95324Barraqué, Facundo; Montes, María Luciana; Fernandez, Mariela Alejandra; Mercader, Roberto Carlos; Candal, Roberto Jorge; et al.; Synthesis and characterization of magnetic-montmorillonite and magnetic-organo-montmorillonite: Surface sites involved on cobalt sorption; Elsevier Science; Journal of Magnetism and Magnetic Materials; 466; 11-2018; 376-3840304-8853CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0304885318306954?via%3Dihubinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jmmm.2018.07.052info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:47:22Zoai:ri.conicet.gov.ar:11336/95324instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:47:22.473CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and characterization of magnetic-montmorillonite and magnetic-organo-montmorillonite: Surface sites involved on cobalt sorption
title Synthesis and characterization of magnetic-montmorillonite and magnetic-organo-montmorillonite: Surface sites involved on cobalt sorption
spellingShingle Synthesis and characterization of magnetic-montmorillonite and magnetic-organo-montmorillonite: Surface sites involved on cobalt sorption
Barraqué, Facundo
MAGNETIC COMPOSITE SYNTHESIS
MAGNETITE
MONTMORILLONITE
ORGANO-MONTMORILLONITE COBALT SORPTION
title_short Synthesis and characterization of magnetic-montmorillonite and magnetic-organo-montmorillonite: Surface sites involved on cobalt sorption
title_full Synthesis and characterization of magnetic-montmorillonite and magnetic-organo-montmorillonite: Surface sites involved on cobalt sorption
title_fullStr Synthesis and characterization of magnetic-montmorillonite and magnetic-organo-montmorillonite: Surface sites involved on cobalt sorption
title_full_unstemmed Synthesis and characterization of magnetic-montmorillonite and magnetic-organo-montmorillonite: Surface sites involved on cobalt sorption
title_sort Synthesis and characterization of magnetic-montmorillonite and magnetic-organo-montmorillonite: Surface sites involved on cobalt sorption
dc.creator.none.fl_str_mv Barraqué, Facundo
Montes, María Luciana
Fernandez, Mariela Alejandra
Mercader, Roberto Carlos
Candal, Roberto Jorge
Torres Sanchez, Rosa Maria
author Barraqué, Facundo
author_facet Barraqué, Facundo
Montes, María Luciana
Fernandez, Mariela Alejandra
Mercader, Roberto Carlos
Candal, Roberto Jorge
Torres Sanchez, Rosa Maria
author_role author
author2 Montes, María Luciana
Fernandez, Mariela Alejandra
Mercader, Roberto Carlos
Candal, Roberto Jorge
Torres Sanchez, Rosa Maria
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv MAGNETIC COMPOSITE SYNTHESIS
MAGNETITE
MONTMORILLONITE
ORGANO-MONTMORILLONITE COBALT SORPTION
topic MAGNETIC COMPOSITE SYNTHESIS
MAGNETITE
MONTMORILLONITE
ORGANO-MONTMORILLONITE COBALT SORPTION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.7
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Montmorillonite magnetic-clay nanoparticles (MtMag) and its exchanged product with hexadecyltrimethylammonium (O100MtMag) were synthetized by alkaline oxidation of ferrous sulfate, characterized by diverse techniques (XRD, Mössbauer spectroscopy, VSM, SEM, Zeta Potential, total specific surface area, TOC) and used as Co2+ sorbents. The magnetic characteristic of these materials allows them to be used in cases of decontamination of water polluted with dangerous materials, such as radioactive ones, reducing the risk to health due to indirect manipulation by means of external magnetic fields. For comparison, samples without magnetic material (O100Mt) and in absence of clay (Mag) were also synthetized. The synthesis of magnetic materials disclosed the presence of magnetite and goethite nanoparticles, while the saturation magnetization displayed by O100MtMag was higher than that obtained for MtMag, indicating the existence of a higher amount of magnetite particles in the first one. This suggests that O100MtMag could be manipulated easier than MtMag through external magnetic fields. Moreover, the surface electric charge of MtMag sample can be described as a mixture of Magnetite and montmorillonite, with ratios related to the surface of both components. Co2+ sorption percentages, using an initial Co2+ concentration of 85 mg/L, resulted similar for the different materials while the Co2+ sorption was ascribed to interactions with the montmorillonite interlayer and external surface. The current results indicate that O100MtMag is a more appropriate material than MtMag for Co2+ removal by external magnets.
Fil: Barraqué, Facundo. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Montes, María Luciana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Fernandez, Mariela Alejandra. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Mercader, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Candal, Roberto Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Instituto de Investigación en Ingeniería Ambiental; Argentina
Fil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
description Montmorillonite magnetic-clay nanoparticles (MtMag) and its exchanged product with hexadecyltrimethylammonium (O100MtMag) were synthetized by alkaline oxidation of ferrous sulfate, characterized by diverse techniques (XRD, Mössbauer spectroscopy, VSM, SEM, Zeta Potential, total specific surface area, TOC) and used as Co2+ sorbents. The magnetic characteristic of these materials allows them to be used in cases of decontamination of water polluted with dangerous materials, such as radioactive ones, reducing the risk to health due to indirect manipulation by means of external magnetic fields. For comparison, samples without magnetic material (O100Mt) and in absence of clay (Mag) were also synthetized. The synthesis of magnetic materials disclosed the presence of magnetite and goethite nanoparticles, while the saturation magnetization displayed by O100MtMag was higher than that obtained for MtMag, indicating the existence of a higher amount of magnetite particles in the first one. This suggests that O100MtMag could be manipulated easier than MtMag through external magnetic fields. Moreover, the surface electric charge of MtMag sample can be described as a mixture of Magnetite and montmorillonite, with ratios related to the surface of both components. Co2+ sorption percentages, using an initial Co2+ concentration of 85 mg/L, resulted similar for the different materials while the Co2+ sorption was ascribed to interactions with the montmorillonite interlayer and external surface. The current results indicate that O100MtMag is a more appropriate material than MtMag for Co2+ removal by external magnets.
publishDate 2018
dc.date.none.fl_str_mv 2018-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/95324
Barraqué, Facundo; Montes, María Luciana; Fernandez, Mariela Alejandra; Mercader, Roberto Carlos; Candal, Roberto Jorge; et al.; Synthesis and characterization of magnetic-montmorillonite and magnetic-organo-montmorillonite: Surface sites involved on cobalt sorption; Elsevier Science; Journal of Magnetism and Magnetic Materials; 466; 11-2018; 376-384
0304-8853
CONICET Digital
CONICET
url http://hdl.handle.net/11336/95324
identifier_str_mv Barraqué, Facundo; Montes, María Luciana; Fernandez, Mariela Alejandra; Mercader, Roberto Carlos; Candal, Roberto Jorge; et al.; Synthesis and characterization of magnetic-montmorillonite and magnetic-organo-montmorillonite: Surface sites involved on cobalt sorption; Elsevier Science; Journal of Magnetism and Magnetic Materials; 466; 11-2018; 376-384
0304-8853
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0304885318306954?via%3Dihub
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jmmm.2018.07.052
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
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dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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