Different coordination modes of the thiosaccharinate anion in dinuclear and one dimensional polymeric silver–azine complexes

Autores
Dennehy, Mariana; Quinzani, Oscar Valentín; Granados, Alejandro Manuel; Burrow, Robert Alan
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The effect of substituted pyridines bases upon the coordination of thiosaccharinate (tsac, C7H4NO2S2 in ternary silver complexes is analyzed. Four crystalline silver-substituted pyridine complexes with tsac as a coordinating counter anion, [Ag(tsac)(3-methylpyridine)2]n, [Ag2(tsac)2(4-methylpyridine)]n, [Ag2(tsac)2 (quinoline)2] and [Ag(tsac)(4-methyloxypyridine)]n were synthesized and characterized by means of spectroscopic (IR and Raman, UV–Vis, and 1 H and 13C NMR) and X-ray diffraction techniques. The thiosaccharinate anion showed its versatility coordinating to the metal in each complex by a different way. In the 3-Mepy complex it was coordinated in a l2-S mode and in the 4-MeOpy complex it was bound in a l3-S form both resulting in polymeric chains. In the 4-Mepy complex the anion was bound in a l2-S,N head to head mode and in the quinoline complex in a l2-S,N head to tail mode, both showing dinuclear arrangements.
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Quinzani, Oscar Valentín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Granados, Alejandro Manuel. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Burrow, Robert Alan. Universidade Federal de Santa Maria; Brasil
Materia
THIONATES
SILVER
PYRIDINE
X-RAY STRUCTURE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/281017
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/281017
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Different coordination modes of the thiosaccharinate anion in dinuclear and one dimensional polymeric silver–azine complexesDennehy, MarianaQuinzani, Oscar ValentínGranados, Alejandro ManuelBurrow, Robert AlanTHIONATESSILVERPYRIDINEX-RAY STRUCTUREhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The effect of substituted pyridines bases upon the coordination of thiosaccharinate (tsac, C7H4NO2S2 in ternary silver complexes is analyzed. Four crystalline silver-substituted pyridine complexes with tsac as a coordinating counter anion, [Ag(tsac)(3-methylpyridine)2]n, [Ag2(tsac)2(4-methylpyridine)]n, [Ag2(tsac)2 (quinoline)2] and [Ag(tsac)(4-methyloxypyridine)]n were synthesized and characterized by means of spectroscopic (IR and Raman, UV–Vis, and 1 H and 13C NMR) and X-ray diffraction techniques. The thiosaccharinate anion showed its versatility coordinating to the metal in each complex by a different way. In the 3-Mepy complex it was coordinated in a l2-S mode and in the 4-MeOpy complex it was bound in a l3-S form both resulting in polymeric chains. In the 4-Mepy complex the anion was bound in a l2-S,N head to head mode and in the quinoline complex in a l2-S,N head to tail mode, both showing dinuclear arrangements.Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Quinzani, Oscar Valentín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Granados, Alejandro Manuel. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Burrow, Robert Alan. Universidade Federal de Santa Maria; BrasilPergamon-Elsevier Science Ltd2010-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/281017Dennehy, Mariana; Quinzani, Oscar Valentín; Granados, Alejandro Manuel; Burrow, Robert Alan; Different coordination modes of the thiosaccharinate anion in dinuclear and one dimensional polymeric silver–azine complexes; Pergamon-Elsevier Science Ltd; Polyhedron; 29; 4; 3-2010; 1344-13520277-5387CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0277538709007748info:eu-repo/semantics/altIdentifier/doi/10.1016/j.poly.2009.12.025info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2026-02-26T10:26:48Zoai:ri.conicet.gov.ar:11336/281017instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982026-02-26 10:26:48.563CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Different coordination modes of the thiosaccharinate anion in dinuclear and one dimensional polymeric silver–azine complexes
title Different coordination modes of the thiosaccharinate anion in dinuclear and one dimensional polymeric silver–azine complexes
spellingShingle Different coordination modes of the thiosaccharinate anion in dinuclear and one dimensional polymeric silver–azine complexes
Dennehy, Mariana
THIONATES
SILVER
PYRIDINE
X-RAY STRUCTURE
title_short Different coordination modes of the thiosaccharinate anion in dinuclear and one dimensional polymeric silver–azine complexes
title_full Different coordination modes of the thiosaccharinate anion in dinuclear and one dimensional polymeric silver–azine complexes
title_fullStr Different coordination modes of the thiosaccharinate anion in dinuclear and one dimensional polymeric silver–azine complexes
title_full_unstemmed Different coordination modes of the thiosaccharinate anion in dinuclear and one dimensional polymeric silver–azine complexes
title_sort Different coordination modes of the thiosaccharinate anion in dinuclear and one dimensional polymeric silver–azine complexes
dc.creator.none.fl_str_mv Dennehy, Mariana
Quinzani, Oscar Valentín
Granados, Alejandro Manuel
Burrow, Robert Alan
author Dennehy, Mariana
author_facet Dennehy, Mariana
Quinzani, Oscar Valentín
Granados, Alejandro Manuel
Burrow, Robert Alan
author_role author
author2 Quinzani, Oscar Valentín
Granados, Alejandro Manuel
Burrow, Robert Alan
author2_role author
author
author
dc.subject.none.fl_str_mv THIONATES
SILVER
PYRIDINE
X-RAY STRUCTURE
topic THIONATES
SILVER
PYRIDINE
X-RAY STRUCTURE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The effect of substituted pyridines bases upon the coordination of thiosaccharinate (tsac, C7H4NO2S2 in ternary silver complexes is analyzed. Four crystalline silver-substituted pyridine complexes with tsac as a coordinating counter anion, [Ag(tsac)(3-methylpyridine)2]n, [Ag2(tsac)2(4-methylpyridine)]n, [Ag2(tsac)2 (quinoline)2] and [Ag(tsac)(4-methyloxypyridine)]n were synthesized and characterized by means of spectroscopic (IR and Raman, UV–Vis, and 1 H and 13C NMR) and X-ray diffraction techniques. The thiosaccharinate anion showed its versatility coordinating to the metal in each complex by a different way. In the 3-Mepy complex it was coordinated in a l2-S mode and in the 4-MeOpy complex it was bound in a l3-S form both resulting in polymeric chains. In the 4-Mepy complex the anion was bound in a l2-S,N head to head mode and in the quinoline complex in a l2-S,N head to tail mode, both showing dinuclear arrangements.
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Quinzani, Oscar Valentín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Granados, Alejandro Manuel. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Burrow, Robert Alan. Universidade Federal de Santa Maria; Brasil
description The effect of substituted pyridines bases upon the coordination of thiosaccharinate (tsac, C7H4NO2S2 in ternary silver complexes is analyzed. Four crystalline silver-substituted pyridine complexes with tsac as a coordinating counter anion, [Ag(tsac)(3-methylpyridine)2]n, [Ag2(tsac)2(4-methylpyridine)]n, [Ag2(tsac)2 (quinoline)2] and [Ag(tsac)(4-methyloxypyridine)]n were synthesized and characterized by means of spectroscopic (IR and Raman, UV–Vis, and 1 H and 13C NMR) and X-ray diffraction techniques. The thiosaccharinate anion showed its versatility coordinating to the metal in each complex by a different way. In the 3-Mepy complex it was coordinated in a l2-S mode and in the 4-MeOpy complex it was bound in a l3-S form both resulting in polymeric chains. In the 4-Mepy complex the anion was bound in a l2-S,N head to head mode and in the quinoline complex in a l2-S,N head to tail mode, both showing dinuclear arrangements.
publishDate 2010
dc.date.none.fl_str_mv 2010-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/281017
Dennehy, Mariana; Quinzani, Oscar Valentín; Granados, Alejandro Manuel; Burrow, Robert Alan; Different coordination modes of the thiosaccharinate anion in dinuclear and one dimensional polymeric silver–azine complexes; Pergamon-Elsevier Science Ltd; Polyhedron; 29; 4; 3-2010; 1344-1352
0277-5387
CONICET Digital
CONICET
url http://hdl.handle.net/11336/281017
identifier_str_mv Dennehy, Mariana; Quinzani, Oscar Valentín; Granados, Alejandro Manuel; Burrow, Robert Alan; Different coordination modes of the thiosaccharinate anion in dinuclear and one dimensional polymeric silver–azine complexes; Pergamon-Elsevier Science Ltd; Polyhedron; 29; 4; 3-2010; 1344-1352
0277-5387
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0277538709007748
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.poly.2009.12.025
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.176822

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