A triclinic polymorph of cyclo-tetra - Thio-saccharinato- 8 S:S-tetra-kis[(triphenyl-phosphane-P)silver(I)]

Autores
Dennehy, Mariana; Freire Espeleta, Eleonora; Baggio, Ricardo Fortunato
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The triclinic structure of the title compound, cyclo-tetra-kis-(-1,1-dioxo- 1 6,2-benzothia-zole-3-thiol-ato- 2 S:S)tetra-kis- [(triphenyl-phosphane-P)silver(I)], [Ag4(C7H4NO2S2)4(C18H15P)4], is a polymorph of the previously reported monoclinic structure [Dennehy, Mandolesi, Quinzani & Jennings (2007). Z. Anorg. Allg. Chem. 633, 2746-2752]. In both polymorphs, the complex lies on a crystallographic inversion centre and the bond distances are closely comparable. Some differences can be found in the inter-atomic angles and torsion angles involving the inner Ag4S4 skeleton. The polymorphs contain essentially identical two-dimensional layers, but with different layer stacking arrangements. In the triclinic form, all layers are related by lattice translation, while in the monoclinic form they are arranged around glide planes so that adjacent layers are mirrored with respect to each other.
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur; Argentina
Fil: Freire Espeleta, Eleonora. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Unidad de Actividad de Materiales (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Unidad de Actividad de Materiales (CAC); Argentina
Materia
SILVER
THIOSACCHARINE
POLYMORPH
X RAY STRUCTURE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/189221
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/189221
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A triclinic polymorph of cyclo-tetra - Thio-saccharinato- 8 S:S-tetra-kis[(triphenyl-phosphane-P)silver(I)]Dennehy, MarianaFreire Espeleta, EleonoraBaggio, Ricardo FortunatoSILVERTHIOSACCHARINEPOLYMORPHX RAY STRUCTUREhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The triclinic structure of the title compound, cyclo-tetra-kis-(-1,1-dioxo- 1 6,2-benzothia-zole-3-thiol-ato- 2 S:S)tetra-kis- [(triphenyl-phosphane-P)silver(I)], [Ag4(C7H4NO2S2)4(C18H15P)4], is a polymorph of the previously reported monoclinic structure [Dennehy, Mandolesi, Quinzani & Jennings (2007). Z. Anorg. Allg. Chem. 633, 2746-2752]. In both polymorphs, the complex lies on a crystallographic inversion centre and the bond distances are closely comparable. Some differences can be found in the inter-atomic angles and torsion angles involving the inner Ag4S4 skeleton. The polymorphs contain essentially identical two-dimensional layers, but with different layer stacking arrangements. In the triclinic form, all layers are related by lattice translation, while in the monoclinic form they are arranged around glide planes so that adjacent layers are mirrored with respect to each other.Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur; ArgentinaFil: Freire Espeleta, Eleonora. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Unidad de Actividad de Materiales (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Unidad de Actividad de Materiales (CAC); ArgentinaWiley Blackwell Publishing, Inc2012-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/189221Dennehy, Mariana; Freire Espeleta, Eleonora; Baggio, Ricardo Fortunato; A triclinic polymorph of cyclo-tetra - Thio-saccharinato- 8 S:S-tetra-kis[(triphenyl-phosphane-P)silver(I)]; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 68; 1; 1-2012; 17-200108-2701CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1107/S0108270111053674/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1107/S0108270111053674info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:11:35Zoai:ri.conicet.gov.ar:11336/189221instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:11:36.296CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A triclinic polymorph of cyclo-tetra - Thio-saccharinato- 8 S:S-tetra-kis[(triphenyl-phosphane-P)silver(I)]
title A triclinic polymorph of cyclo-tetra - Thio-saccharinato- 8 S:S-tetra-kis[(triphenyl-phosphane-P)silver(I)]
spellingShingle A triclinic polymorph of cyclo-tetra - Thio-saccharinato- 8 S:S-tetra-kis[(triphenyl-phosphane-P)silver(I)]
Dennehy, Mariana
SILVER
THIOSACCHARINE
POLYMORPH
X RAY STRUCTURE
title_short A triclinic polymorph of cyclo-tetra - Thio-saccharinato- 8 S:S-tetra-kis[(triphenyl-phosphane-P)silver(I)]
title_full A triclinic polymorph of cyclo-tetra - Thio-saccharinato- 8 S:S-tetra-kis[(triphenyl-phosphane-P)silver(I)]
title_fullStr A triclinic polymorph of cyclo-tetra - Thio-saccharinato- 8 S:S-tetra-kis[(triphenyl-phosphane-P)silver(I)]
title_full_unstemmed A triclinic polymorph of cyclo-tetra - Thio-saccharinato- 8 S:S-tetra-kis[(triphenyl-phosphane-P)silver(I)]
title_sort A triclinic polymorph of cyclo-tetra - Thio-saccharinato- 8 S:S-tetra-kis[(triphenyl-phosphane-P)silver(I)]
dc.creator.none.fl_str_mv Dennehy, Mariana
Freire Espeleta, Eleonora
Baggio, Ricardo Fortunato
author Dennehy, Mariana
author_facet Dennehy, Mariana
Freire Espeleta, Eleonora
Baggio, Ricardo Fortunato
author_role author
author2 Freire Espeleta, Eleonora
Baggio, Ricardo Fortunato
author2_role author
author
dc.subject.none.fl_str_mv SILVER
THIOSACCHARINE
POLYMORPH
X RAY STRUCTURE
topic SILVER
THIOSACCHARINE
POLYMORPH
X RAY STRUCTURE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The triclinic structure of the title compound, cyclo-tetra-kis-(-1,1-dioxo- 1 6,2-benzothia-zole-3-thiol-ato- 2 S:S)tetra-kis- [(triphenyl-phosphane-P)silver(I)], [Ag4(C7H4NO2S2)4(C18H15P)4], is a polymorph of the previously reported monoclinic structure [Dennehy, Mandolesi, Quinzani & Jennings (2007). Z. Anorg. Allg. Chem. 633, 2746-2752]. In both polymorphs, the complex lies on a crystallographic inversion centre and the bond distances are closely comparable. Some differences can be found in the inter-atomic angles and torsion angles involving the inner Ag4S4 skeleton. The polymorphs contain essentially identical two-dimensional layers, but with different layer stacking arrangements. In the triclinic form, all layers are related by lattice translation, while in the monoclinic form they are arranged around glide planes so that adjacent layers are mirrored with respect to each other.
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur; Argentina
Fil: Freire Espeleta, Eleonora. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Unidad de Actividad de Materiales (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Unidad de Actividad de Materiales (CAC); Argentina
description The triclinic structure of the title compound, cyclo-tetra-kis-(-1,1-dioxo- 1 6,2-benzothia-zole-3-thiol-ato- 2 S:S)tetra-kis- [(triphenyl-phosphane-P)silver(I)], [Ag4(C7H4NO2S2)4(C18H15P)4], is a polymorph of the previously reported monoclinic structure [Dennehy, Mandolesi, Quinzani & Jennings (2007). Z. Anorg. Allg. Chem. 633, 2746-2752]. In both polymorphs, the complex lies on a crystallographic inversion centre and the bond distances are closely comparable. Some differences can be found in the inter-atomic angles and torsion angles involving the inner Ag4S4 skeleton. The polymorphs contain essentially identical two-dimensional layers, but with different layer stacking arrangements. In the triclinic form, all layers are related by lattice translation, while in the monoclinic form they are arranged around glide planes so that adjacent layers are mirrored with respect to each other.
publishDate 2012
dc.date.none.fl_str_mv 2012-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/189221
Dennehy, Mariana; Freire Espeleta, Eleonora; Baggio, Ricardo Fortunato; A triclinic polymorph of cyclo-tetra - Thio-saccharinato- 8 S:S-tetra-kis[(triphenyl-phosphane-P)silver(I)]; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 68; 1; 1-2012; 17-20
0108-2701
CONICET Digital
CONICET
url http://hdl.handle.net/11336/189221
identifier_str_mv Dennehy, Mariana; Freire Espeleta, Eleonora; Baggio, Ricardo Fortunato; A triclinic polymorph of cyclo-tetra - Thio-saccharinato- 8 S:S-tetra-kis[(triphenyl-phosphane-P)silver(I)]; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 68; 1; 1-2012; 17-20
0108-2701
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1107/S0108270111053674/abstract
info:eu-repo/semantics/altIdentifier/doi/10.1107/S0108270111053674
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846781496490196992
score 12.982451

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