Thermo-compression of biodegradable thermoplastic corn starch films containing chitin and chitosan

Autores
Lopez, Olivia Valeria; Garcia, Maria Alejandra; Villar, Marcelo Armando; Gentili, A.; Rodríguez, M. S.; Albertengo, L.
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Films based on thermoplastic corn starch (TPS) and chitosan/chitin were obtained by melt-mixing and thermo-compression. Chitosan and chitin incorporation to TPS matrix induced some structural modifications due mainly to the interactions between starch hydroxyl and chitosan/chitin amino groups. Crystallinity degree of TPS films was increased with biopolymers incorporation. Enthalpy melting values for TPSechitosan/chitin films resulted lower than those corresponding to TPS control ones. Films had homogeneous and smooth surfaces, without pores and cracks and no glycerol migration was evidenced by Scanning Electronic Microscopy. Films fracture surfaces were uniform without the presence of unmelting starch granules neither chitosan/chitin agglomerates. Films with chitosan/chitin presented higher color, UV absorption capacity and opacity than TPS films. Addition of 10 g chitosan or chitin/100 g starch decreased 35 and 56% water vapor permeability, respectively. Biopolymers addition to TPS increased tensile strength and elastic modulus, and decreased elongation at break. Starch and glycerol rich domains where evidenced in TPS matrixes by Dynamic Mechanical Analysis. Finally, TPS-chitosan films reduced Staphylococcus aureus and Escherichia coli growth in the contact zone.
Fil: Lopez, Olivia Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigaciones En Criotecnología de Alimentos (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas; Argentina
Fil: Garcia, Maria Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigaciones En Criotecnología de Alimentos (i); Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas; Argentina
Fil: Villar, Marcelo Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; Argentina
Fil: Gentili, A.. Universidad Nacional del Sur. Departamento de Biología, Bioquímica y Farmacia; Argentina
Fil: Rodríguez, M. S.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Albertengo, L.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur. Departamento de Química; Argentina
Materia
Thermoplastic Corn Starch Films with Chitosan And Chitin
Thermo-Compression
Structural Characterization
Barrier And Mechanical Properties
Antimicrobial Capacity
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/13541
Acceder
id CONICETDig_e9321476bb2871d7ea831cfa2e964cbf
oai_identifier_str oai:ri.conicet.gov.ar:11336/13541
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Thermo-compression of biodegradable thermoplastic corn starch films containing chitin and chitosanLopez, Olivia ValeriaGarcia, Maria AlejandraVillar, Marcelo ArmandoGentili, A.Rodríguez, M. S.Albertengo, L.Thermoplastic Corn Starch Films with Chitosan And ChitinThermo-CompressionStructural CharacterizationBarrier And Mechanical PropertiesAntimicrobial Capacityhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Films based on thermoplastic corn starch (TPS) and chitosan/chitin were obtained by melt-mixing and thermo-compression. Chitosan and chitin incorporation to TPS matrix induced some structural modifications due mainly to the interactions between starch hydroxyl and chitosan/chitin amino groups. Crystallinity degree of TPS films was increased with biopolymers incorporation. Enthalpy melting values for TPSechitosan/chitin films resulted lower than those corresponding to TPS control ones. Films had homogeneous and smooth surfaces, without pores and cracks and no glycerol migration was evidenced by Scanning Electronic Microscopy. Films fracture surfaces were uniform without the presence of unmelting starch granules neither chitosan/chitin agglomerates. Films with chitosan/chitin presented higher color, UV absorption capacity and opacity than TPS films. Addition of 10 g chitosan or chitin/100 g starch decreased 35 and 56% water vapor permeability, respectively. Biopolymers addition to TPS increased tensile strength and elastic modulus, and decreased elongation at break. Starch and glycerol rich domains where evidenced in TPS matrixes by Dynamic Mechanical Analysis. Finally, TPS-chitosan films reduced Staphylococcus aureus and Escherichia coli growth in the contact zone.Fil: Lopez, Olivia Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigaciones En Criotecnología de Alimentos (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas; ArgentinaFil: Garcia, Maria Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigaciones En Criotecnología de Alimentos (i); Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas; ArgentinaFil: Villar, Marcelo Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; ArgentinaFil: Gentili, A.. Universidad Nacional del Sur. Departamento de Biología, Bioquímica y Farmacia; ArgentinaFil: Rodríguez, M. S.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur. Departamento de Química; ArgentinaFil: Albertengo, L.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur. Departamento de Química; ArgentinaElsevier2014-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/13541Lopez, Olivia Valeria; Garcia, Maria Alejandra; Villar, Marcelo Armando; Gentili, A.; Rodríguez, M. S.; et al.; Thermo-compression of biodegradable thermoplastic corn starch films containing chitin and chitosan; Elsevier; LWT - Food Science and Technology; 57; 1; 6-2014; 106-1150023-6438enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0023643814000413info:eu-repo/semantics/altIdentifier/doi/10.1016/j.lwt.2014.01.024info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:44:25Zoai:ri.conicet.gov.ar:11336/13541instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:44:25.879CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Thermo-compression of biodegradable thermoplastic corn starch films containing chitin and chitosan
title Thermo-compression of biodegradable thermoplastic corn starch films containing chitin and chitosan
spellingShingle Thermo-compression of biodegradable thermoplastic corn starch films containing chitin and chitosan
Lopez, Olivia Valeria
Thermoplastic Corn Starch Films with Chitosan And Chitin
Thermo-Compression
Structural Characterization
Barrier And Mechanical Properties
Antimicrobial Capacity
title_short Thermo-compression of biodegradable thermoplastic corn starch films containing chitin and chitosan
title_full Thermo-compression of biodegradable thermoplastic corn starch films containing chitin and chitosan
title_fullStr Thermo-compression of biodegradable thermoplastic corn starch films containing chitin and chitosan
title_full_unstemmed Thermo-compression of biodegradable thermoplastic corn starch films containing chitin and chitosan
title_sort Thermo-compression of biodegradable thermoplastic corn starch films containing chitin and chitosan
dc.creator.none.fl_str_mv Lopez, Olivia Valeria
Garcia, Maria Alejandra
Villar, Marcelo Armando
Gentili, A.
Rodríguez, M. S.
Albertengo, L.
author Lopez, Olivia Valeria
author_facet Lopez, Olivia Valeria
Garcia, Maria Alejandra
Villar, Marcelo Armando
Gentili, A.
Rodríguez, M. S.
Albertengo, L.
author_role author
author2 Garcia, Maria Alejandra
Villar, Marcelo Armando
Gentili, A.
Rodríguez, M. S.
Albertengo, L.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Thermoplastic Corn Starch Films with Chitosan And Chitin
Thermo-Compression
Structural Characterization
Barrier And Mechanical Properties
Antimicrobial Capacity
topic Thermoplastic Corn Starch Films with Chitosan And Chitin
Thermo-Compression
Structural Characterization
Barrier And Mechanical Properties
Antimicrobial Capacity
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Films based on thermoplastic corn starch (TPS) and chitosan/chitin were obtained by melt-mixing and thermo-compression. Chitosan and chitin incorporation to TPS matrix induced some structural modifications due mainly to the interactions between starch hydroxyl and chitosan/chitin amino groups. Crystallinity degree of TPS films was increased with biopolymers incorporation. Enthalpy melting values for TPSechitosan/chitin films resulted lower than those corresponding to TPS control ones. Films had homogeneous and smooth surfaces, without pores and cracks and no glycerol migration was evidenced by Scanning Electronic Microscopy. Films fracture surfaces were uniform without the presence of unmelting starch granules neither chitosan/chitin agglomerates. Films with chitosan/chitin presented higher color, UV absorption capacity and opacity than TPS films. Addition of 10 g chitosan or chitin/100 g starch decreased 35 and 56% water vapor permeability, respectively. Biopolymers addition to TPS increased tensile strength and elastic modulus, and decreased elongation at break. Starch and glycerol rich domains where evidenced in TPS matrixes by Dynamic Mechanical Analysis. Finally, TPS-chitosan films reduced Staphylococcus aureus and Escherichia coli growth in the contact zone.
Fil: Lopez, Olivia Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigaciones En Criotecnología de Alimentos (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas; Argentina
Fil: Garcia, Maria Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigaciones En Criotecnología de Alimentos (i); Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas; Argentina
Fil: Villar, Marcelo Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur. Departamento de Ingenieria Quimica; Argentina
Fil: Gentili, A.. Universidad Nacional del Sur. Departamento de Biología, Bioquímica y Farmacia; Argentina
Fil: Rodríguez, M. S.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Albertengo, L.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur. Departamento de Química; Argentina
description Films based on thermoplastic corn starch (TPS) and chitosan/chitin were obtained by melt-mixing and thermo-compression. Chitosan and chitin incorporation to TPS matrix induced some structural modifications due mainly to the interactions between starch hydroxyl and chitosan/chitin amino groups. Crystallinity degree of TPS films was increased with biopolymers incorporation. Enthalpy melting values for TPSechitosan/chitin films resulted lower than those corresponding to TPS control ones. Films had homogeneous and smooth surfaces, without pores and cracks and no glycerol migration was evidenced by Scanning Electronic Microscopy. Films fracture surfaces were uniform without the presence of unmelting starch granules neither chitosan/chitin agglomerates. Films with chitosan/chitin presented higher color, UV absorption capacity and opacity than TPS films. Addition of 10 g chitosan or chitin/100 g starch decreased 35 and 56% water vapor permeability, respectively. Biopolymers addition to TPS increased tensile strength and elastic modulus, and decreased elongation at break. Starch and glycerol rich domains where evidenced in TPS matrixes by Dynamic Mechanical Analysis. Finally, TPS-chitosan films reduced Staphylococcus aureus and Escherichia coli growth in the contact zone.
publishDate 2014
dc.date.none.fl_str_mv 2014-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/13541
Lopez, Olivia Valeria; Garcia, Maria Alejandra; Villar, Marcelo Armando; Gentili, A.; Rodríguez, M. S.; et al.; Thermo-compression of biodegradable thermoplastic corn starch films containing chitin and chitosan; Elsevier; LWT - Food Science and Technology; 57; 1; 6-2014; 106-115
0023-6438
url http://hdl.handle.net/11336/13541
identifier_str_mv Lopez, Olivia Valeria; Garcia, Maria Alejandra; Villar, Marcelo Armando; Gentili, A.; Rodríguez, M. S.; et al.; Thermo-compression of biodegradable thermoplastic corn starch films containing chitin and chitosan; Elsevier; LWT - Food Science and Technology; 57; 1; 6-2014; 106-115
0023-6438
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0023643814000413
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.lwt.2014.01.024
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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