Dielectric dispersion in aqueous colloidal systems

Autores
Grosse, Constantino; Delgado, Alejandra Verónica
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work we describe the fundamentals of the phenomenon of dielectric dispersion in aqueous colloidal suspensions, as well as the most recent advances on the subject. We begin by establishing the admitted definitions of the permittivity of a heterogeneous system consisting of a certain volume of a material dispersed in the form of identical spheres (the particles) in a liquid medium (an electrolyte solution). Attention is also paid to the relationship between the electric permittivity of the suspension and the strength and frequency dependence of the dipole moment induced by the external field. A thorough historical revision is provided, describing the key contributions, both experimental and theoretical, to the development of this field of electrokinetics and interface physics. In fact, elucidation of the mechanisms responsible for the values of the permittivity of disperse systems over a wide enough frequency range is a rich exercise in electromagnetism, fluid mechanics and electrochemistry of interfaces. Three mechanisms are typically responsible for the dielectric dispersion of the suspension. The gamma dispersion is a manifestation of the frequency dependence of the permittivity of the aqueous electrolyte solution where the particles are suspended. It is mainly determined by the polar nature of the water molecules and its characteristic frequency is in the GHz range. The delta dispersion (typically in the MHz range) is determined by the Maxwell-Wagner-O'Konski relaxation mechanism: it occurs because of the different permittivities and conductivities of the particle and the surrounding medium. Finally, the alpha- or Low Frequency Dielectric Dispersion (LFDD) is a phenomenon characterized by a huge increase of the permittivity at very low frequencies (kHz range). Its relationship with the phenomenon of concentration polarization is carefully discussed, as it is an essential feature of the electric permittivity of suspensions. The mathematical treatment of the problem is rather complex, and analytical solutions are only available in a limited number of cases. Attention is hence also devoted to describing and comparing the numerical approaches that can be used. Experimental determination of the (particularly low frequency) dielectric dispersion is complicated mainly because of the phenomenon of the polarization of the electrode-solution interface. In this contribution we describe the solutions reported to this problem, both in the frequency and in the time domains. An interesting aspect of dielectric dispersion determinations, not shared by other techniques, is their applicability to concentrated suspensions. The modifications of the theory of the permittivity of suspensions, required to account for the hydrodynamic and electrical interactions are also described, stressing the fact that suspensions often considered as dilute are actually far from being so. The review is finished with a description of the most recent advances, namely the consideration of suspensions of soft particles and extensions of the standard electrokinetic model in order to reach a better agreement between theory and experiments. The conclusion of the work refers to the expected developments, particularly in the field of experimental determinations (mainly in the high frequency side of the dispersion), and of descriptions of the solid/liquid interface with corresponding extensions of the standard electrokinetic model.
Fil: Grosse, Constantino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; Argentina
Fil: Delgado, Alejandra Verónica. Universidad de Granada. Facultad de Ciencias. Departamento de Física Aplicada; España
Materia
Alpha Dispersion
Colloidal Suspensions
Concentrated Suspensions
Concentration Polarization
Dielectric Dispersion
Ion Size
Low Frequency Dielectric Dispersion
Maxwell-Wagner-O'Konski Relaxation
Soft Particles
Surface Conductivity
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/72436

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oai_identifier_str oai:ri.conicet.gov.ar:11336/72436
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network_name_str CONICET Digital (CONICET)
spelling Dielectric dispersion in aqueous colloidal systemsGrosse, ConstantinoDelgado, Alejandra VerónicaAlpha DispersionColloidal SuspensionsConcentrated SuspensionsConcentration PolarizationDielectric DispersionIon SizeLow Frequency Dielectric DispersionMaxwell-Wagner-O'Konski RelaxationSoft ParticlesSurface Conductivityhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1In this work we describe the fundamentals of the phenomenon of dielectric dispersion in aqueous colloidal suspensions, as well as the most recent advances on the subject. We begin by establishing the admitted definitions of the permittivity of a heterogeneous system consisting of a certain volume of a material dispersed in the form of identical spheres (the particles) in a liquid medium (an electrolyte solution). Attention is also paid to the relationship between the electric permittivity of the suspension and the strength and frequency dependence of the dipole moment induced by the external field. A thorough historical revision is provided, describing the key contributions, both experimental and theoretical, to the development of this field of electrokinetics and interface physics. In fact, elucidation of the mechanisms responsible for the values of the permittivity of disperse systems over a wide enough frequency range is a rich exercise in electromagnetism, fluid mechanics and electrochemistry of interfaces. Three mechanisms are typically responsible for the dielectric dispersion of the suspension. The gamma dispersion is a manifestation of the frequency dependence of the permittivity of the aqueous electrolyte solution where the particles are suspended. It is mainly determined by the polar nature of the water molecules and its characteristic frequency is in the GHz range. The delta dispersion (typically in the MHz range) is determined by the Maxwell-Wagner-O'Konski relaxation mechanism: it occurs because of the different permittivities and conductivities of the particle and the surrounding medium. Finally, the alpha- or Low Frequency Dielectric Dispersion (LFDD) is a phenomenon characterized by a huge increase of the permittivity at very low frequencies (kHz range). Its relationship with the phenomenon of concentration polarization is carefully discussed, as it is an essential feature of the electric permittivity of suspensions. The mathematical treatment of the problem is rather complex, and analytical solutions are only available in a limited number of cases. Attention is hence also devoted to describing and comparing the numerical approaches that can be used. Experimental determination of the (particularly low frequency) dielectric dispersion is complicated mainly because of the phenomenon of the polarization of the electrode-solution interface. In this contribution we describe the solutions reported to this problem, both in the frequency and in the time domains. An interesting aspect of dielectric dispersion determinations, not shared by other techniques, is their applicability to concentrated suspensions. The modifications of the theory of the permittivity of suspensions, required to account for the hydrodynamic and electrical interactions are also described, stressing the fact that suspensions often considered as dilute are actually far from being so. The review is finished with a description of the most recent advances, namely the consideration of suspensions of soft particles and extensions of the standard electrokinetic model in order to reach a better agreement between theory and experiments. The conclusion of the work refers to the expected developments, particularly in the field of experimental determinations (mainly in the high frequency side of the dispersion), and of descriptions of the solid/liquid interface with corresponding extensions of the standard electrokinetic model.Fil: Grosse, Constantino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; ArgentinaFil: Delgado, Alejandra Verónica. Universidad de Granada. Facultad de Ciencias. Departamento de Física Aplicada; EspañaElsevier Science London2010-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/72436Grosse, Constantino; Delgado, Alejandra Verónica; Dielectric dispersion in aqueous colloidal systems; Elsevier Science London; Current Opinion In Colloid & Interface Science; 15; 3; 6-2010; 145-1591359-0294CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cocis.2009.11.004info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1359029409001046?via%3Dihubinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:30:03Zoai:ri.conicet.gov.ar:11336/72436instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:30:04.286CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Dielectric dispersion in aqueous colloidal systems
title Dielectric dispersion in aqueous colloidal systems
spellingShingle Dielectric dispersion in aqueous colloidal systems
Grosse, Constantino
Alpha Dispersion
Colloidal Suspensions
Concentrated Suspensions
Concentration Polarization
Dielectric Dispersion
Ion Size
Low Frequency Dielectric Dispersion
Maxwell-Wagner-O'Konski Relaxation
Soft Particles
Surface Conductivity
title_short Dielectric dispersion in aqueous colloidal systems
title_full Dielectric dispersion in aqueous colloidal systems
title_fullStr Dielectric dispersion in aqueous colloidal systems
title_full_unstemmed Dielectric dispersion in aqueous colloidal systems
title_sort Dielectric dispersion in aqueous colloidal systems
dc.creator.none.fl_str_mv Grosse, Constantino
Delgado, Alejandra Verónica
author Grosse, Constantino
author_facet Grosse, Constantino
Delgado, Alejandra Verónica
author_role author
author2 Delgado, Alejandra Verónica
author2_role author
dc.subject.none.fl_str_mv Alpha Dispersion
Colloidal Suspensions
Concentrated Suspensions
Concentration Polarization
Dielectric Dispersion
Ion Size
Low Frequency Dielectric Dispersion
Maxwell-Wagner-O'Konski Relaxation
Soft Particles
Surface Conductivity
topic Alpha Dispersion
Colloidal Suspensions
Concentrated Suspensions
Concentration Polarization
Dielectric Dispersion
Ion Size
Low Frequency Dielectric Dispersion
Maxwell-Wagner-O'Konski Relaxation
Soft Particles
Surface Conductivity
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this work we describe the fundamentals of the phenomenon of dielectric dispersion in aqueous colloidal suspensions, as well as the most recent advances on the subject. We begin by establishing the admitted definitions of the permittivity of a heterogeneous system consisting of a certain volume of a material dispersed in the form of identical spheres (the particles) in a liquid medium (an electrolyte solution). Attention is also paid to the relationship between the electric permittivity of the suspension and the strength and frequency dependence of the dipole moment induced by the external field. A thorough historical revision is provided, describing the key contributions, both experimental and theoretical, to the development of this field of electrokinetics and interface physics. In fact, elucidation of the mechanisms responsible for the values of the permittivity of disperse systems over a wide enough frequency range is a rich exercise in electromagnetism, fluid mechanics and electrochemistry of interfaces. Three mechanisms are typically responsible for the dielectric dispersion of the suspension. The gamma dispersion is a manifestation of the frequency dependence of the permittivity of the aqueous electrolyte solution where the particles are suspended. It is mainly determined by the polar nature of the water molecules and its characteristic frequency is in the GHz range. The delta dispersion (typically in the MHz range) is determined by the Maxwell-Wagner-O'Konski relaxation mechanism: it occurs because of the different permittivities and conductivities of the particle and the surrounding medium. Finally, the alpha- or Low Frequency Dielectric Dispersion (LFDD) is a phenomenon characterized by a huge increase of the permittivity at very low frequencies (kHz range). Its relationship with the phenomenon of concentration polarization is carefully discussed, as it is an essential feature of the electric permittivity of suspensions. The mathematical treatment of the problem is rather complex, and analytical solutions are only available in a limited number of cases. Attention is hence also devoted to describing and comparing the numerical approaches that can be used. Experimental determination of the (particularly low frequency) dielectric dispersion is complicated mainly because of the phenomenon of the polarization of the electrode-solution interface. In this contribution we describe the solutions reported to this problem, both in the frequency and in the time domains. An interesting aspect of dielectric dispersion determinations, not shared by other techniques, is their applicability to concentrated suspensions. The modifications of the theory of the permittivity of suspensions, required to account for the hydrodynamic and electrical interactions are also described, stressing the fact that suspensions often considered as dilute are actually far from being so. The review is finished with a description of the most recent advances, namely the consideration of suspensions of soft particles and extensions of the standard electrokinetic model in order to reach a better agreement between theory and experiments. The conclusion of the work refers to the expected developments, particularly in the field of experimental determinations (mainly in the high frequency side of the dispersion), and of descriptions of the solid/liquid interface with corresponding extensions of the standard electrokinetic model.
Fil: Grosse, Constantino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; Argentina
Fil: Delgado, Alejandra Verónica. Universidad de Granada. Facultad de Ciencias. Departamento de Física Aplicada; España
description In this work we describe the fundamentals of the phenomenon of dielectric dispersion in aqueous colloidal suspensions, as well as the most recent advances on the subject. We begin by establishing the admitted definitions of the permittivity of a heterogeneous system consisting of a certain volume of a material dispersed in the form of identical spheres (the particles) in a liquid medium (an electrolyte solution). Attention is also paid to the relationship between the electric permittivity of the suspension and the strength and frequency dependence of the dipole moment induced by the external field. A thorough historical revision is provided, describing the key contributions, both experimental and theoretical, to the development of this field of electrokinetics and interface physics. In fact, elucidation of the mechanisms responsible for the values of the permittivity of disperse systems over a wide enough frequency range is a rich exercise in electromagnetism, fluid mechanics and electrochemistry of interfaces. Three mechanisms are typically responsible for the dielectric dispersion of the suspension. The gamma dispersion is a manifestation of the frequency dependence of the permittivity of the aqueous electrolyte solution where the particles are suspended. It is mainly determined by the polar nature of the water molecules and its characteristic frequency is in the GHz range. The delta dispersion (typically in the MHz range) is determined by the Maxwell-Wagner-O'Konski relaxation mechanism: it occurs because of the different permittivities and conductivities of the particle and the surrounding medium. Finally, the alpha- or Low Frequency Dielectric Dispersion (LFDD) is a phenomenon characterized by a huge increase of the permittivity at very low frequencies (kHz range). Its relationship with the phenomenon of concentration polarization is carefully discussed, as it is an essential feature of the electric permittivity of suspensions. The mathematical treatment of the problem is rather complex, and analytical solutions are only available in a limited number of cases. Attention is hence also devoted to describing and comparing the numerical approaches that can be used. Experimental determination of the (particularly low frequency) dielectric dispersion is complicated mainly because of the phenomenon of the polarization of the electrode-solution interface. In this contribution we describe the solutions reported to this problem, both in the frequency and in the time domains. An interesting aspect of dielectric dispersion determinations, not shared by other techniques, is their applicability to concentrated suspensions. The modifications of the theory of the permittivity of suspensions, required to account for the hydrodynamic and electrical interactions are also described, stressing the fact that suspensions often considered as dilute are actually far from being so. The review is finished with a description of the most recent advances, namely the consideration of suspensions of soft particles and extensions of the standard electrokinetic model in order to reach a better agreement between theory and experiments. The conclusion of the work refers to the expected developments, particularly in the field of experimental determinations (mainly in the high frequency side of the dispersion), and of descriptions of the solid/liquid interface with corresponding extensions of the standard electrokinetic model.
publishDate 2010
dc.date.none.fl_str_mv 2010-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/72436
Grosse, Constantino; Delgado, Alejandra Verónica; Dielectric dispersion in aqueous colloidal systems; Elsevier Science London; Current Opinion In Colloid & Interface Science; 15; 3; 6-2010; 145-159
1359-0294
CONICET Digital
CONICET
url http://hdl.handle.net/11336/72436
identifier_str_mv Grosse, Constantino; Delgado, Alejandra Verónica; Dielectric dispersion in aqueous colloidal systems; Elsevier Science London; Current Opinion In Colloid & Interface Science; 15; 3; 6-2010; 145-159
1359-0294
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cocis.2009.11.004
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1359029409001046?via%3Dihub
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science London
publisher.none.fl_str_mv Elsevier Science London
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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