Ethane as an alternative solvent for supercritical extraction of orange peel oils

Autores
Raeissi, S.; Díaz, María Soledad; Espinosa, Susana Noemi; Peters, C.J.; Brignole, Esteban Alberto
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The objective of this study was to investigate the superiority of ethane in comparison to CO2 as a supercritical extraction solvent for deterpenating citrus oils. A rigorous computer code was developed that optimized extraction column operating conditions to minimize solvent recirculation. The SRK equation of state was used as the thermodynamic model after globally optimizing its adjustable binary interaction parameters to a combination of different literature data sets consisting of binary isothermal P–x, y, ternary constant composition P–T, and ternary isothermal isobaric x–y data. An investigation of the effects of different process variables on the degree of extraction revealed complicated and interconnected relations among the variables and extraction efficiencies. However, since the process of deterpenation, in particular, benefits from higher solubility more than from higher selectivity, increases in temperature, pressure, solvent-to-feed ratio, and reflux rate all seem to favor the separation. To compare the performance of ethane and carbon dioxide for orange oil deterpenation, selectivities of separation between the terpene and aroma fractions were calculated and compared for the two solvents. Compared to CO2, ethane is the better solvent for citrus constituents. This results in decreased solvent/feed mass ratio for ethane when the processes are compared at the same reduced pressure. However, these are not the only benefits of ethane over CO2. As the critical pressure of ethane is lower, the absolute operating pressures of ethane columns can be lower.
Fil: Raeissi, S.. Shiraz University; Irán
Fil: Díaz, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina
Fil: Espinosa, Susana Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina
Fil: Peters, C.J.. Delft University of Technology; Países Bajos
Fil: Brignole, Esteban Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina
Materia
Citrus Oil
Essential Oil
Deterpenation
Folding
Fractionation
Optimization
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/41969
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/41969
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Ethane as an alternative solvent for supercritical extraction of orange peel oilsRaeissi, S.Díaz, María SoledadEspinosa, Susana NoemiPeters, C.J.Brignole, Esteban AlbertoCitrus OilEssential OilDeterpenationFoldingFractionationOptimizationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The objective of this study was to investigate the superiority of ethane in comparison to CO2 as a supercritical extraction solvent for deterpenating citrus oils. A rigorous computer code was developed that optimized extraction column operating conditions to minimize solvent recirculation. The SRK equation of state was used as the thermodynamic model after globally optimizing its adjustable binary interaction parameters to a combination of different literature data sets consisting of binary isothermal P–x, y, ternary constant composition P–T, and ternary isothermal isobaric x–y data. An investigation of the effects of different process variables on the degree of extraction revealed complicated and interconnected relations among the variables and extraction efficiencies. However, since the process of deterpenation, in particular, benefits from higher solubility more than from higher selectivity, increases in temperature, pressure, solvent-to-feed ratio, and reflux rate all seem to favor the separation. To compare the performance of ethane and carbon dioxide for orange oil deterpenation, selectivities of separation between the terpene and aroma fractions were calculated and compared for the two solvents. Compared to CO2, ethane is the better solvent for citrus constituents. This results in decreased solvent/feed mass ratio for ethane when the processes are compared at the same reduced pressure. However, these are not the only benefits of ethane over CO2. As the critical pressure of ethane is lower, the absolute operating pressures of ethane columns can be lower.Fil: Raeissi, S.. Shiraz University; IránFil: Díaz, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; ArgentinaFil: Espinosa, Susana Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; ArgentinaFil: Peters, C.J.. Delft University of Technology; Países BajosFil: Brignole, Esteban Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; ArgentinaElsevier Science2008-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/41969Raeissi, S.; Díaz, María Soledad; Espinosa, Susana Noemi; Peters, C.J.; Brignole, Esteban Alberto; Ethane as an alternative solvent for supercritical extraction of orange peel oils; Elsevier Science; Journal of Supercritical Fluids; 45; 3; 12-2008; 306-3130896-8446CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.supflu.2008.01.008info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0896844608000119info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:01:18Zoai:ri.conicet.gov.ar:11336/41969instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:01:18.804CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ethane as an alternative solvent for supercritical extraction of orange peel oils
title Ethane as an alternative solvent for supercritical extraction of orange peel oils
spellingShingle Ethane as an alternative solvent for supercritical extraction of orange peel oils
Raeissi, S.
Citrus Oil
Essential Oil
Deterpenation
Folding
Fractionation
Optimization
title_short Ethane as an alternative solvent for supercritical extraction of orange peel oils
title_full Ethane as an alternative solvent for supercritical extraction of orange peel oils
title_fullStr Ethane as an alternative solvent for supercritical extraction of orange peel oils
title_full_unstemmed Ethane as an alternative solvent for supercritical extraction of orange peel oils
title_sort Ethane as an alternative solvent for supercritical extraction of orange peel oils
dc.creator.none.fl_str_mv Raeissi, S.
Díaz, María Soledad
Espinosa, Susana Noemi
Peters, C.J.
Brignole, Esteban Alberto
author Raeissi, S.
author_facet Raeissi, S.
Díaz, María Soledad
Espinosa, Susana Noemi
Peters, C.J.
Brignole, Esteban Alberto
author_role author
author2 Díaz, María Soledad
Espinosa, Susana Noemi
Peters, C.J.
Brignole, Esteban Alberto
author2_role author
author
author
author
dc.subject.none.fl_str_mv Citrus Oil
Essential Oil
Deterpenation
Folding
Fractionation
Optimization
topic Citrus Oil
Essential Oil
Deterpenation
Folding
Fractionation
Optimization
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The objective of this study was to investigate the superiority of ethane in comparison to CO2 as a supercritical extraction solvent for deterpenating citrus oils. A rigorous computer code was developed that optimized extraction column operating conditions to minimize solvent recirculation. The SRK equation of state was used as the thermodynamic model after globally optimizing its adjustable binary interaction parameters to a combination of different literature data sets consisting of binary isothermal P–x, y, ternary constant composition P–T, and ternary isothermal isobaric x–y data. An investigation of the effects of different process variables on the degree of extraction revealed complicated and interconnected relations among the variables and extraction efficiencies. However, since the process of deterpenation, in particular, benefits from higher solubility more than from higher selectivity, increases in temperature, pressure, solvent-to-feed ratio, and reflux rate all seem to favor the separation. To compare the performance of ethane and carbon dioxide for orange oil deterpenation, selectivities of separation between the terpene and aroma fractions were calculated and compared for the two solvents. Compared to CO2, ethane is the better solvent for citrus constituents. This results in decreased solvent/feed mass ratio for ethane when the processes are compared at the same reduced pressure. However, these are not the only benefits of ethane over CO2. As the critical pressure of ethane is lower, the absolute operating pressures of ethane columns can be lower.
Fil: Raeissi, S.. Shiraz University; Irán
Fil: Díaz, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina
Fil: Espinosa, Susana Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina
Fil: Peters, C.J.. Delft University of Technology; Países Bajos
Fil: Brignole, Esteban Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina
description The objective of this study was to investigate the superiority of ethane in comparison to CO2 as a supercritical extraction solvent for deterpenating citrus oils. A rigorous computer code was developed that optimized extraction column operating conditions to minimize solvent recirculation. The SRK equation of state was used as the thermodynamic model after globally optimizing its adjustable binary interaction parameters to a combination of different literature data sets consisting of binary isothermal P–x, y, ternary constant composition P–T, and ternary isothermal isobaric x–y data. An investigation of the effects of different process variables on the degree of extraction revealed complicated and interconnected relations among the variables and extraction efficiencies. However, since the process of deterpenation, in particular, benefits from higher solubility more than from higher selectivity, increases in temperature, pressure, solvent-to-feed ratio, and reflux rate all seem to favor the separation. To compare the performance of ethane and carbon dioxide for orange oil deterpenation, selectivities of separation between the terpene and aroma fractions were calculated and compared for the two solvents. Compared to CO2, ethane is the better solvent for citrus constituents. This results in decreased solvent/feed mass ratio for ethane when the processes are compared at the same reduced pressure. However, these are not the only benefits of ethane over CO2. As the critical pressure of ethane is lower, the absolute operating pressures of ethane columns can be lower.
publishDate 2008
dc.date.none.fl_str_mv 2008-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/41969
Raeissi, S.; Díaz, María Soledad; Espinosa, Susana Noemi; Peters, C.J.; Brignole, Esteban Alberto; Ethane as an alternative solvent for supercritical extraction of orange peel oils; Elsevier Science; Journal of Supercritical Fluids; 45; 3; 12-2008; 306-313
0896-8446
CONICET Digital
CONICET
url http://hdl.handle.net/11336/41969
identifier_str_mv Raeissi, S.; Díaz, María Soledad; Espinosa, Susana Noemi; Peters, C.J.; Brignole, Esteban Alberto; Ethane as an alternative solvent for supercritical extraction of orange peel oils; Elsevier Science; Journal of Supercritical Fluids; 45; 3; 12-2008; 306-313
0896-8446
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.supflu.2008.01.008
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0896844608000119
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269688696930304
score 13.13397

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