Thermodynamic modeling and process optimization of supercritical fluid fractionation of fish oil fatty acid ethyl esters

Autores
Espinosa, Susana Noemi; Díaz, María Soledad; Brignole, Esteban Alberto
Año de publicación
2002
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Rigorous thermodynamic modeling, simulation, and optimization of the supercritical fractionation of EPA and DHA esters is presented. These valuable products are obtained from complex mixtures of fish oil fatty acid alkyl esters by high-pressure fractionation with supercritical carbon dioxide. A group contribution equation of state (GC-EOS) that provides reliable phase equilibrium and solubility predictions is used to support the process simulation. A correlation has been developed for the estimation of a thermodynamic model parameter: the fish oil esters hard-sphere diameter. The capability of the group contribution equation of state is confirmed by a detailed comparison of predictions with experimental data. Rigorous simulation models for process units have been formulated within a nonlinear optimization model to maximize EPA and DHA esters recovery and purity from several natural fish oil mixtures with supercritical extraction.
Fil: Espinosa, Susana Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Díaz, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Brignole, Esteban Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Fish Oil
Supercritical Fractionation
Optimization
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/37986

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spelling Thermodynamic modeling and process optimization of supercritical fluid fractionation of fish oil fatty acid ethyl estersEspinosa, Susana NoemiDíaz, María SoledadBrignole, Esteban AlbertoFish OilSupercritical FractionationOptimizationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Rigorous thermodynamic modeling, simulation, and optimization of the supercritical fractionation of EPA and DHA esters is presented. These valuable products are obtained from complex mixtures of fish oil fatty acid alkyl esters by high-pressure fractionation with supercritical carbon dioxide. A group contribution equation of state (GC-EOS) that provides reliable phase equilibrium and solubility predictions is used to support the process simulation. A correlation has been developed for the estimation of a thermodynamic model parameter: the fish oil esters hard-sphere diameter. The capability of the group contribution equation of state is confirmed by a detailed comparison of predictions with experimental data. Rigorous simulation models for process units have been formulated within a nonlinear optimization model to maximize EPA and DHA esters recovery and purity from several natural fish oil mixtures with supercritical extraction.Fil: Espinosa, Susana Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Díaz, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Brignole, Esteban Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaAmerican Chemical Society2002-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/37986Espinosa, Susana Noemi; Díaz, María Soledad; Brignole, Esteban Alberto; Thermodynamic modeling and process optimization of supercritical fluid fractionation of fish oil fatty acid ethyl esters; American Chemical Society; Industrial & Engineering Chemical Research; 41; 6; 3-2002; 1516-15270888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ie010470hinfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie010470hinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:09:20Zoai:ri.conicet.gov.ar:11336/37986instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:09:20.855CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Thermodynamic modeling and process optimization of supercritical fluid fractionation of fish oil fatty acid ethyl esters
title Thermodynamic modeling and process optimization of supercritical fluid fractionation of fish oil fatty acid ethyl esters
spellingShingle Thermodynamic modeling and process optimization of supercritical fluid fractionation of fish oil fatty acid ethyl esters
Espinosa, Susana Noemi
Fish Oil
Supercritical Fractionation
Optimization
title_short Thermodynamic modeling and process optimization of supercritical fluid fractionation of fish oil fatty acid ethyl esters
title_full Thermodynamic modeling and process optimization of supercritical fluid fractionation of fish oil fatty acid ethyl esters
title_fullStr Thermodynamic modeling and process optimization of supercritical fluid fractionation of fish oil fatty acid ethyl esters
title_full_unstemmed Thermodynamic modeling and process optimization of supercritical fluid fractionation of fish oil fatty acid ethyl esters
title_sort Thermodynamic modeling and process optimization of supercritical fluid fractionation of fish oil fatty acid ethyl esters
dc.creator.none.fl_str_mv Espinosa, Susana Noemi
Díaz, María Soledad
Brignole, Esteban Alberto
author Espinosa, Susana Noemi
author_facet Espinosa, Susana Noemi
Díaz, María Soledad
Brignole, Esteban Alberto
author_role author
author2 Díaz, María Soledad
Brignole, Esteban Alberto
author2_role author
author
dc.subject.none.fl_str_mv Fish Oil
Supercritical Fractionation
Optimization
topic Fish Oil
Supercritical Fractionation
Optimization
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Rigorous thermodynamic modeling, simulation, and optimization of the supercritical fractionation of EPA and DHA esters is presented. These valuable products are obtained from complex mixtures of fish oil fatty acid alkyl esters by high-pressure fractionation with supercritical carbon dioxide. A group contribution equation of state (GC-EOS) that provides reliable phase equilibrium and solubility predictions is used to support the process simulation. A correlation has been developed for the estimation of a thermodynamic model parameter: the fish oil esters hard-sphere diameter. The capability of the group contribution equation of state is confirmed by a detailed comparison of predictions with experimental data. Rigorous simulation models for process units have been formulated within a nonlinear optimization model to maximize EPA and DHA esters recovery and purity from several natural fish oil mixtures with supercritical extraction.
Fil: Espinosa, Susana Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Díaz, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Brignole, Esteban Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description Rigorous thermodynamic modeling, simulation, and optimization of the supercritical fractionation of EPA and DHA esters is presented. These valuable products are obtained from complex mixtures of fish oil fatty acid alkyl esters by high-pressure fractionation with supercritical carbon dioxide. A group contribution equation of state (GC-EOS) that provides reliable phase equilibrium and solubility predictions is used to support the process simulation. A correlation has been developed for the estimation of a thermodynamic model parameter: the fish oil esters hard-sphere diameter. The capability of the group contribution equation of state is confirmed by a detailed comparison of predictions with experimental data. Rigorous simulation models for process units have been formulated within a nonlinear optimization model to maximize EPA and DHA esters recovery and purity from several natural fish oil mixtures with supercritical extraction.
publishDate 2002
dc.date.none.fl_str_mv 2002-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/37986
Espinosa, Susana Noemi; Díaz, María Soledad; Brignole, Esteban Alberto; Thermodynamic modeling and process optimization of supercritical fluid fractionation of fish oil fatty acid ethyl esters; American Chemical Society; Industrial & Engineering Chemical Research; 41; 6; 3-2002; 1516-1527
0888-5885
CONICET Digital
CONICET
url http://hdl.handle.net/11336/37986
identifier_str_mv Espinosa, Susana Noemi; Díaz, María Soledad; Brignole, Esteban Alberto; Thermodynamic modeling and process optimization of supercritical fluid fractionation of fish oil fatty acid ethyl esters; American Chemical Society; Industrial & Engineering Chemical Research; 41; 6; 3-2002; 1516-1527
0888-5885
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ie010470h
info:eu-repo/semantics/altIdentifier/doi/10.1021/ie010470h
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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